Platinum group metal-free Fe-based (Fe-N-C) oxygen reduction electrocatalysts for direct alcohol fuel cells

Berretti, Enrico; Longhi, Mariangela; Atanassov, Plamen; Sebastián, David; Lo Vecchio, Carmelo; Baglio, Vincenzo; Serov, Alexey; Marchionni, Andrea; Vizza, Francesco; Santoro, Carlo; Lavacchi, Alessandro

doi:10.1016/j.coelec.2021.100756

Title: Platinum group metal-free Fe-based (Fe-N-C) oxygen reduction electrocatalysts for direct alcohol fuel cells

Journal Article · Fri May 07 00:00:00 EDT 2021 · Current Opinion in Electrochemistry

DOI:https://doi.org/10.1016/j.coelec.2021.100756· OSTI ID:1976981

^[1]; Longhi, Mariangela ^[2]; Atanassov, Plamen ^[3]; Sebastián, David ^[4];

^[5];

^[5]; Serov, Alexey ^[6];

^[1]; Vizza, Francesco ^[1]; Santoro, Carlo ^[7]; Lavacchi, Alessandro ^[1]

Consiglio Nazionale delle Ricerche (CNR), Florence (Italy). Istituto di Chimica Dei Composti OrganoMetallici (ICCOM)
Univ. degli Studi di Milano (Italy)
Univ. of California, Irvine, CA (United States). National Fuel Cells Research Center
Consejo Superior de Investigaciones Cientificas (CSIC), Zaragoza (Spain). Instituto de Carboquímica
National Research Council (CNR), Messina (Italy). Istituto di Tecnologie Avanzate per l'Energia "Nicola Giordano" (ITAE)
Pajarito Powder, LLC, Albuquerque, NM (United States)
University of Milano-Bicocca, Milan (Italy)

In direct alcohol fuel cells (DAFCs), the oxidation of alcohols happens at the expenses of the oxygen reduction reaction at the cathode. DAFCs' cathodes use a significant amount of platinum that is an expensive critical raw material. Moreover, platinum oxidizes alcohols, a fact that combined with alcohol crossover, decreases significantly the performance of the cells. The use of Fe-based (Fe-N-C) platinum group metal–free (PGM-free) cathodes is a convenient strategy to overcome these limitations. This review analyzes the application of PGM-free cathodes to DAFCs. The discussion focuses on acidic systems and covers the following subjects: (i) the breakdown of DAFC potential in its components, (ii) the analysis of the advantages from the use of the PGM-free cathode, and (iii) a review of the performance and durability of DAFCs. Finally, the review closes with a view of the authors of the future perspective for the research.

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Research Organization:: Pajarito Powder, LLC, Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); Italian Ministry for University and Research

Grant/Contract Number:: EE0008419; 2017YH9MRK

OSTI ID:: 1976981

Journal Information:: Current Opinion in Electrochemistry, Vol. 29, Issue C; ISSN 2451-9103

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Platinum group metal-free Fe-based (Fe-N-C) oxygen reduction electrocatalysts for direct alcohol fuel cells

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