Novel Class of Rhenium Borides Based on Hexagonal Boron Networks Interconnected by Short B2 Dumbbells

Bykova, Elena; Johansson, Erik; Bykov, Maxim; Chariton, Stella; Fei, Hongzhan; Ovsyannikov, Sergey V.; Aslandukova, Alena; Gabel, Stefan; Holz, Hendrik; Merle, Benoit; Alling, Björn; Abrikosov, Igor A.; Smith, Jesse S.; Prakapenka, Vitali B.; Katsura, Tomoo; Dubrovinskaia, Natalia; Goncharov, Alexander F.; Dubrovinsky, Leonid

doi:10.1021/acs.chemmater.2c00520

Title: Novel Class of Rhenium Borides Based on Hexagonal Boron Networks Interconnected by Short B₂ Dumbbells

Journal Article · Tue Sep 06 00:00:00 EDT 2022 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.2c00520· OSTI ID:1970714

^[1]; Johansson, Erik ^[2];

^[3];

^[4]; Fei, Hongzhan ^[5];

^[6]; Aslandukova, Alena ^[5]; Gabel, Stefan ^[7]; Holz, Hendrik ^[8]; Merle, Benoit ^[8]; Alling, Björn ^[2]; Abrikosov, Igor A. ^[2]; Smith, Jesse S. ^[9];

^[4]; Katsura, Tomoo ^[5]; Dubrovinskaia, Natalia ^[10]; Goncharov, Alexander F. ^[11]; Dubrovinsky, Leonid ^[5]

Carnegie Institute of Science, Washington, DC (United States); University of Bayreuth (Germany)
Linkoping University (Sweden)
Carnegie Institute of Science, Washington, DC (United States); University of Cologne (Germany)
University of Chicago, IL (United States)
University of Bayreuth (Germany)
Bayerisches Geoinstitut, University of Bayreuth, Universitätstraβe 30, 95440 Bayreuth, Germany
Friedrich-Alexander-Universität, Erlangen (Germany)
Friedrich-Alexander-Universität, Erlangen (Germany); Universität Kassel (Germany)
Argonne National Laboratory (ANL), Lemont, IL (United States)
Linkoping University (Sweden); University of Bayreuth (Germany)
Carnegie Institute of Science, Washington, DC (United States)

Transition metal borides are known due to their attractive mechanical, electronic, refractive, and other properties. A new class of rhenium borides was identified by synchrotron single-crystal X-ray diffraction experiments in laser-heated diamond anvil cells between 26 and 75 GPa. Recoverable to ambient conditions, compounds rhenium triboride (ReB₃) and rhenium tetraboride (ReB₄) consist of close-packed single layers of rhenium atoms alternating with boron networks built from puckered hexagonal layers, which link short bonded (~ 1.7 angstrom) axially oriented B₂ dumbbells. The short and incompressible Re-B and B-B bonds oriented along the hexagonal c-axis contribute to low axial compressibility comparable with the linear compressibility of diamond. Sub-millimeter samples of ReB₃ and ReB₄ were synthesized in a large-volume press at pressures as low as 33 GPa and used for material characterization. Crystals of both compounds are metallic and hard (Vickers hardness, H_V= 34(3) GPa). Geometrical, crystal-chemical, and theoretical analysis considerations suggest that potential ReB_xcompounds with x > 4 can be based on the same principle of structural organization as in ReB₃ and ReB₄ and possess similar mechanical and electronic properties.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Swedish Research Council (SRC); European Union - Horizon 2020 Research and Innovation Programme; Carnegie Institution of Washington; German Research Foundation (DFG); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); Knut and Alice Wallenberg Foundation; European Research Council (ERC)

Grant/Contract Number:: AC02-06CH11357; EAR-1634415; FG02-94ER14466; 949626; KAW 2015.0043; 2014-6336; 2019-05403; 2019-05600; 2009 00971; KAW-2018.0194

OSTI ID:: 1970714

Journal Information:: Chemistry of Materials, Vol. 34, Issue 18; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Novel Class of Rhenium Borides Based on Hexagonal Boron Networks Interconnected by Short B2 Dumbbells

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Title: Novel Class of Rhenium Borides Based on Hexagonal Boron Networks Interconnected by Short B₂ Dumbbells