High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

Jin, Baitang; Li, Shiguang; Liang, Xinhua

doi:10.1021/acs.iecr.1c03705

Title: High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

Journal Article · Tue Dec 14 00:00:00 EST 2021 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.1c03705· OSTI ID:1968722

Jin, Baitang ^[1]; Li, Shiguang ^[2];

^[1]

Missouri Univ. of Science and Technology, Rolla, MO (United States)
Gas Technology Institute, Des Plaines, IL (United States)

In this study, highly dispersed nickel (Ni) nanoparticles (NPs) with an average particle size of 4.3 nm were uniformly deposited on the outer surface, the inner channel surface, and inside the pores of 20-cm long 4-channel α-Al₂O₃ hollow fibers (HFs) by atomic layer deposition (ALD) for dry reforming of methane (DRM). Cerium oxide (CeO₂) was added to promote the catalytic performance of Ni/Al₂O₃-HF catalysts. Rationally designed filling methods, by tuning the reactor size and inert fillings, can reduce the catalyst bed voidage in a fixed bed reactor for better reactant gas distribution, effectively utilize the Ni reactive sites, and achieve excellent catalytic performance. It was found that the CeO₂-promoted Ni/Al₂O₃-HF catalyst was highly active and highly stable without deactivation during an overall 400-hr DRM test at 850 ºC. CeO₂ with reversible valence states could participate in surface reactions; especially, the formation of CeAlO₃ provided sufficient surface Ce³⁺ for CO₂ activation and enhanced the stability and reusability of the HF catalysts.

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Research Organization:: Gas Technology Institute, Des Plaines, IL (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FE0029760

OSTI ID:: 1968722

Journal Information:: Industrial and Engineering Chemistry Research, Vol. 61, Issue 29; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: High-Performance Catalytic Four-Channel Hollow Fibers with Highly Dispersed Nickel Nanoparticles Prepared by Atomic Layer Deposition for Dry Reforming of Methane

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