Dyes, dye-sensitized solar cells, and methods of making and using the same

Patent · Tue Aug 23 00:00:00 EDT 2022

OSTI ID:1925013

Delcamp, Jared Heath; Rodrigues, Roberta Ramalho; Peddapuram, Adithya; Cheema, Hammad Arshad; Curiae, Christine

Provided herein are dyes, dye-sensitized solar cells, and sequential series multijunction dye-sensitized solar cell devices. The dyes include an electron deficient acceptor moiety, a medium electron density π-bridge moiety, and an electron rich donor moiety comprising a biaryl, a substituted biaryl, or an R¹, R², R³ substituted phenyl where each of R¹, R², and R³ independently comprises H, aryl, multiaryl, alkyl substituted aryl, alkoxy substituted aryl, alkyl substituted multiaryl, alkoxy substituted multiaryl, OR⁴, N(R⁵)₂, or a combination thereof; each R⁴ independently comprises H, alkyl, aryl, alkyl substituted aryl, alkoxy substituted aryl, or a combination thereof; and each R⁵ independently comprises aryl, multiaryl, alkyl substituted aryl, alkoxy substituted aryl, alkyl substituted multiaryl, alkoxy substituted multiaryl, or a combination thereof. The solar cells include a glass substrate, a dye-sensitized active layer, and a redox shuttle. The devices include at least two dye-sensitized solar cells connected in series.

• Research Organization: Univ. of Mississippi, University, MS (United States)
• Sponsoring Organization: USDOE; National Science Foundation (NSF)
• DOE Contract Number: 1455167; 1539035; SC0019131
• Assignee: University of Mississippi (University, MS)
• Patent Number(s): 11,421,110
• Application Number: 16/779,569
• OSTI ID: 1925013
• Resource Relation: Patent File Date: 01/31/2020
• Country of Publication: United States
• Language: English