Exploring natural aerosol formation from DMS oxidation and implications for aerosol forcing (Final Technical Report)
Because of their interactions with sunlight and with clouds, aerosol particles in the atmosphere can play an important role in the Earth’s climate. Understanding this role, and climate change in general, requires understanding the sources of these aerosol particles – not only anthropogenic sources (such as particles emitted from fossil fuel combustion) but also natural sources as well. One of the most important natural aerosol sources is the atmospheric oxidation of dimethyl sulfide (DMS). DMS, a gas emitted by oceanic phytoplankton, is the largest natural source of sulfur to the atmosphere. Once in the air it undergoes natural oxidation processes, converting the sulfur into sulfate, a major component of atmospheric aerosol. However, the chemical mechanism by which DMS oxidation forms sulfate particles is highly complex and uncertain. The goal of this project was therefore to better understand the chemistry of DMS oxidation, via laboratory and global-modeling studies. In the laboratory studies, DMS was oxidized in an environmental chamber (a large Teflon bag surrounded by UV lights to simulate sunlight), under a range of atmospheric conditions. A number of instruments were used to measure the reaction products (gases and particles) within the chamber. The total sulfur in the products equaled the sulfur in the reacted DMS, indicating that all major sulfur-containing species were measured. Yields of these products, and rates of important processes within the mechanism, were determined, providing improved parameters for use in chemical mechanisms. On the global modeling side, a detailed DMS oxidation scheme (that included chemistry occurring in both the gas phase and in cloud droplets) was incorporated into the Community Earth System Model (CESM), and the effects of this more complex mechanism on predicted sulfate levels and climate effects were explored. The expanded chemistry scheme was found to increase global sulfate levels under present-day conditions (~9%) and even more substantially (~30%) under preindustrial conditions. This additional predicted sulfate has implications for our understanding of the role of present-day aerosol pollution on climate, though because of in-cloud chemistry this effect is quite complex, highlighting the need for additional study.
- Research Organization:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Biological and Environmental Research (BER). Earth & Environmental Systems Science (EESS)
- DOE Contract Number:
- SC0018934
- OSTI ID:
- 1897725
- Report Number(s):
- DOE-MIT-18934
- Country of Publication:
- United States
- Language:
- English
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