Decreasing the Overpotential of Aprotic Li-CO2 Batteries with the In-Plane Alloy Structure in Ultrathin 2D Ru-Based Nanosheets

Wang, Yunhao; Zhou, Jingwen; Lin, Chao; Chen, Bo; Guan, Zhiqiang; Ebrahim, Amani M.; Qian, Guannan; Ye, Chenliang; Chen, Lin; Ge, Yiyao; Yun, Qinbai; Wang, Xixi; Zhou, Xichen; Wang, Gang; Li, Kedi; Lu, Pengyi; Ma, Yangbo; Xiong, Yuecheng; Wang, Tianshuai; Zheng, Long; Chu, Shengqi; Chen, Ye; Wang, Bin; Lee, Chun‐Sing; Liu, Yijin; Zhang, Qianfan; Fan, Zhanxi

doi:10.1002/adfm.202202737

Title: Decreasing the Overpotential of Aprotic Li-CO₂ Batteries with the In-Plane Alloy Structure in Ultrathin 2D Ru-Based Nanosheets

Journal Article · Wed May 04 00:00:00 EDT 2022 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202202737· OSTI ID:1889846

Wang, Yunhao ^[1]; Zhou, Jingwen ^[1]; Lin, Chao ^[2]; Chen, Bo ^[1]; Guan, Zhiqiang ^[1]; Ebrahim, Amani M. ^[3]; Qian, Guannan ^[3]; Ye, Chenliang ^[4]; Chen, Lin ^[5]; Ge, Yiyao ^[1]; Yun, Qinbai ^[1]; Wang, Xixi ^[1]; Zhou, Xichen ^[1]; Wang, Gang ^[6]; Li, Kedi ^[1]; Lu, Pengyi ^[1]; Ma, Yangbo ^[1]; Xiong, Yuecheng ^[1]; Wang, Tianshuai ^[2]; Zheng, Long ^[6] more »

City University of Hong Kong, Kowloon (Hong Kong)
Beihang University, Beijing (China)
SLAC National Accelerator Laboratory, Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Tsinghua University, Beijing (China)
University of Electronic Sciences and Technology of China Chengdu (China)
Chinese University of Hong Kong (Hong Kong)
Chinese Academy of Sciences (CAS), Beijing (China)
City University of Hong Kong, Kowloon (Hong Kong); City University of Hong Kong, Shenzhen (Hong Kong)

We report the aprotic Li-CO₂ battery is emerging as a promising energy storage technology with the capability of CO₂ fixation and conversion. However, its practical applications are still impeded by the large overpotential. Herein, the general synthesis of a series of ultrathin 2D Ru-M (M = Co, Ni, and Cu) nanosheets by a facile one-pot solvothermal method is reported. As a proof-of-concept application, the representative RuCo nanosheets are used as the cathode catalysts for Li-CO₂ batteries, which demonstrate a low charge voltage of 3.74 V, a small overpotential of 0.94 V, and hence a high energy efficiency of 75%. Ex/in situ studies and density functional theory calculations reveal that the excellent catalytic performance of RuCo nanosheets originates from the enhanced adsorption toward Li and CO₂ during discharge as well as the elevated electron interaction with Li₂CO₃ during charge by the in-plane RuCo alloy structure. This work indicates the feasibility of boosting the electrochemical performance of Li-CO₂ batteries by in-plane metal alloy sites of ultrathin 2D alloy nanomaterials.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC); National Precious Metals Material Engineering Research Center (NPMM); City University of Hong Kong; Chinese University of Hong Kong

Grant/Contract Number:: AC02-76SF00515; 22005258; 22175148; 52102320; 9610480; 7005512; 7005600; 9680301; 4930977

OSTI ID:: 1889846

Journal Information:: Advanced Functional Materials, Vol. 32, Issue 30; ISSN 1616-301X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
2D materials
alloy nanosheets
CO2 conversion
electrocatalysis
Li-CO2 electrochemistry

Title: Decreasing the Overpotential of Aprotic Li-CO2 Batteries with the In-Plane Alloy Structure in Ultrathin 2D Ru-Based Nanosheets

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Title: Decreasing the Overpotential of Aprotic Li-CO₂ Batteries with the In-Plane Alloy Structure in Ultrathin 2D Ru-Based Nanosheets