How Cerium and Lanthanum as Coproducts Promote Stable Rare Earth Production and New Alloys

Sims, Zachary C.; Kesler, Michael S.; Henderson, Hunter B.; Castillo, Emilio; Fishman, Tomer; Weiss, David; Singleton, Prentice; Eggert, Roderick; McCall, Scott K.; Rios, Orlando

doi:10.1007/s40831-022-00562-4

Title: How Cerium and Lanthanum as Coproducts Promote Stable Rare Earth Production and New Alloys

Journal Article · Tue Jul 05 00:00:00 EDT 2022 · Journal of Sustainable Metallurgy

DOI:https://doi.org/10.1007/s40831-022-00562-4· OSTI ID:1883885

Sims, Zachary C. ^[1];

^[2]; Henderson, Hunter B. ^[1]; Castillo, Emilio ^[3]; Fishman, Tomer ^[4]; Weiss, David ^[5]; Singleton, Prentice ^[6]; Eggert, Roderick ^[7]; McCall, Scott K. ^[1];

^[8]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Critical Materials Institute (CMI), Ames, IA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Critical Materials Institute (CMI), Ames, IA (United States);
University of Chile, Santiago (Chile)
IDC Herzliya (Israel)
Eck Industries, Manitowoc, WI (United States); Critical Materials Institute (CMI), Ames, IA (United States)
Borg Warner Turbo Systems, Ashville, NC (United States); Critical Materials Institute (CMI), Ames, IA (United States)
Colorado School of Mines, Golden, CO (United States); Critical Materials Institute (CMI), Ames, IA (United States)
Univ. of Tennessee, Knoxville, TN (United States); Critical Materials Institute (CMI), Ames, IA (United States)

The largest outputs of rare earth mining are the low-value byproducts cerium and lanthanum, which burden rare earth supply chains because they must be separated from more desirable rare earths used in magnet production. Promoting demand for cerium and lanthanum can potentially diversify the economics of rare earth mining and improve supply chain stability for all rare earth elements. A promising avenue for increasing byproduct rare earth element demand is their use in aluminum alloys; an application for cerium and lanthanum offering multiple benefits to manufacturing such as energy reduction and improved throughput. Experimental materials science and economic implications of Al-rare earth element alloys will be discussed. We show that Al–La/Ce alloys have elevated mechanical strength compared to more traditional aluminum alloys, in some formulations can be used without heat treatment, and possess a highly castable eutectic microstructure. This report presents the use of cerium and lanthanum in aluminum alloys as an example of how supply chain focused approaches to technological development can benefit stakeholders at every step in production.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office

Grant/Contract Number:: AC05-00OR22725; AC52-07NA27344

OSTI ID:: 1883885

Journal Information:: Journal of Sustainable Metallurgy, Vol. 8, Issue 3; ISSN 2199-3823

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

References (26)

Rare Earths and the Balance Problem Binnemans, Koen; Jones, Peter Tom Journal of Sustainable Metallurgy, Vol. 1, Issue 1 https://doi.org/10.1007/s40831-014-0005-1	journal	January 2015
Cerium-Based, Intermetallic-Strengthened Aluminum Casting Alloy: High-Volume Co-product Development Sims, Zachary C.; Weiss, D.; McCall, S. K. JOM, Vol. 68, Issue 7 https://doi.org/10.1007/s11837-016-1943-9	journal	May 2016
Characterization of Near Net-Shape Castable Rare Earth Modified Aluminum Alloys for High Temperature Application Sims, Zachary C.; Rios, Orlando; McCall, Scott K. Light Metals 2016 https://doi.org/10.1007/978-3-319-48251-4_19	book	January 2016
Life-Cycle and Energy Assessment of Automotive Component Manufacturing: The Dilemma Between Aluminum and Cast Iron Salonitis, Konstantinos; Jolly, Mark; Pagone, Emanuele Energies, Vol. 12, Issue 13 https://doi.org/10.3390/en12132557	journal	July 2019
Uncovering the end uses of the rare earth elements Du, Xiaoyue; Graedel, T. E. Science of The Total Environment, Vol. 461-462 https://doi.org/10.1016/j.scitotenv.2013.02.099	journal	September 2013
A critical review on solvent extraction of rare earths from aqueous solutions Xie, Feng; Zhang, Ting An; Dreisinger, David Minerals Engineering, Vol. 56 https://doi.org/10.1016/j.mineng.2013.10.021	journal	February 2014
Recycling rare earths: Perspectives and recent advances Fujita, Yoshiko; McCall, Scott K.; Ginosar, Daniel MRS Bulletin, Vol. 47, Issue 3 https://doi.org/10.1557/s43577-022-00301-w	journal	March 2022
Separating Rare Earth Elements Fray, Derek J. Science, Vol. 289, Issue 5488 https://doi.org/10.1126/science.289.5488.2295	journal	September 2000
Ageless Aluminum-Cerium-Based Alloys in High-Volume Die Casting for Improved Energy Efficiency Stromme, Eric T.; Henderson, Hunter B.; Sims, Zachary C. JOM, Vol. 70, Issue 6 https://doi.org/10.1007/s11837-018-2861-9	journal	April 2018
Evaluation of an Al-Ce alloy for laser additive manufacturing Plotkowski, A.; Rios, O.; Sridharan, N. Acta Materialia, Vol. 126 https://doi.org/10.1016/j.actamat.2016.12.065	journal	March 2017
Additively Manufactured Single-Use Molds and Reusable Patterns for Large Automotive and Hydroelectric Components Henderson, Hunter B.; Stromme, Eric T.; Kesler, Michael S. International Journal of Metalcasting, Vol. 14, Issue 2 https://doi.org/10.1007/s40962-019-00379-0	journal	October 2019
New Plant-Technologies for Reducing Carbon Emissions and Costs in Heat Treatment Processes of Aluminium Castings Scharf, Stefan; Dischinger, Norbert; Ates, Baris Procedia CIRP, Vol. 69 https://doi.org/10.1016/j.procir.2017.11.140	journal	January 2018
Liquid direct reactive interface printing of structural aluminum alloys Kesler, Michael S.; Neveau, Max L.; Carter, William G. Applied Materials Today, Vol. 13 https://doi.org/10.1016/j.apmt.2018.10.005	journal	December 2018
Enhanced mechanical performance via laser induced nanostructure formation in an additively manufactured lightweight aluminum alloy Martin, Aiden A.; Hammons, Joshua A.; Henderson, Hunter B. Applied Materials Today, Vol. 22 https://doi.org/10.1016/j.apmt.2021.100972	journal	March 2021
Al-Ce-Mg (Aluminum-Cerium-Magnesium) Raghavan, V. Journal of Phase Equilibria and Diffusion, Vol. 28, Issue 5 https://doi.org/10.1007/s11669-007-9136-4	journal	August 2007
Improved High-Temperature Aluminum Alloys Containing Cerium Weiss, David Journal of Materials Engineering and Performance, Vol. 28, Issue 4 https://doi.org/10.1007/s11665-019-3884-2	journal	February 2019
SANS study of the precipitates microstructural evolution in Al 4032 car engine pistons Rogante, M.; Lebedev, V. T.; Nicolaie, F. Physica B: Condensed Matter, Vol. 358, Issue 1-4 https://doi.org/10.1016/j.physb.2005.01.240	journal	April 2005
A study on the re-solution heat treatment of AA 2618 aluminum alloy Özbek, İbrahim Materials Characterization, Vol. 58, Issue 3 https://doi.org/10.1016/j.matchar.2006.07.002	journal	March 2007
Estimation of local fatigue behaviour in A356–T6 gravity die cast engine head based on solidification defects content Ceschini, L.; Morri, Al.; Morri, An. International Journal of Cast Metals Research, Vol. 27, Issue 1 https://doi.org/10.1179/1743133613Y.0000000081	journal	December 2013
Microstructural design of high-strength aluminum alloys Nie, J. F.; Muddle, B. C. Journal of Phase Equilibria, Vol. 19, Issue 6 https://doi.org/10.1361/105497198770341734	journal	December 1998
Fundamental aspects of hot isostatic pressing: An overview Atkinson, H. V.; Davies, S. Metallurgical and Materials Transactions A, Vol. 31, Issue 12 https://doi.org/10.1007/s11661-000-0078-2	journal	December 2000
Mechanisms of hot-isostatic pressing Swinkels, F. B.; Wilkinson, D. S.; Arzt, E. Acta Metallurgica, Vol. 31, Issue 11 https://doi.org/10.1016/0001-6160(83)90129-3	journal	November 1983
Porosity regrowth during heat treatment of hot isostatically pressed additively manufactured titanium components Tammas-Williams, S.; Withers, P. J.; Todd, I. Scripta Materialia, Vol. 122 https://doi.org/10.1016/j.scriptamat.2016.05.002	journal	September 2016
Anticipating impacts of introducing aluminum-cerium alloys into the United States automotive market Nguyen, Ruby T.; Imholte, D. Devin; Rios, Orlando R. Resources, Conservation and Recycling, Vol. 144 https://doi.org/10.1016/j.resconrec.2019.02.009	journal	May 2019
Rare Earths and the Balance Problem: How to Deal with Changing Markets? Binnemans, Koen; Jones, Peter Tom; Müller, Torsten Journal of Sustainable Metallurgy, Vol. 4, Issue 1 https://doi.org/10.1007/s40831-018-0162-8	journal	February 2018
Application of Ce for scavenging Cu impurities in A356 Al alloys Sims, Zachary C.; Henderson, Hunter B.; Thompson, Michael J. European Journal of Materials, Vol. 1, Issue 1 https://doi.org/10.1080/26889277.2021.1974801	journal	January 2021

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