Mutual Diffusion Coefficients and Refractive Index Increments of K2SO4(aq) at 298.15 K from Rayleigh Interferometry

Rard, Joseph A.; Miller, Donald G.; Albright, John G.; Zeidler, Manfred E.; Annunziata, Onofrio

doi:10.1007/s10953-021-01118-y

Title: Mutual Diffusion Coefficients and Refractive Index Increments of K₂SO₄(aq) at 298.15 K from Rayleigh Interferometry

Journal Article · Sat Oct 09 00:00:00 EDT 2021 · Journal of Solution Chemistry

DOI:https://doi.org/10.1007/s10953-021-01118-y· OSTI ID:1860789

Rard, Joseph A. ^[1]; Miller, Donald G. ^[1]; Albright, John G. ^[2]; Zeidler, Manfred E. ^[1];

^[2]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Texas Christian Univ., Fort Worth, TX (United States)

Here, isothermal mutual diffusion coefficients (interdiffusion coefficients) were measured for K₂SO₄(aq) at 298.15 ± 0.005 K, at numerous concentrations ranging from dilute solutions to near saturation (0.59648 mol∙dm^-3; 0.61349 mol∙kg^-1) under free diffusion boundary conditions, using high precision Rayleigh interferometry. Under the experimental conditions these diffusion coefficients are on the volume-fixed reference frame D_v. Two series of experiments were performed, the first using the traditional experimental approach with a mercury lamp source and with the interference patterns being recorded on glass photographic plates, and the second with a He-Ne laser light source and computerized data acquisition using a photodiode array. The results from both series of experiments are in excellent agreement, and generally yield diffusion coefficients precise to at least 0.002 x 10^-9 m²∙s¹ (0.15% to 0.19%) and in most cases to 0.001 x 10^-9 m²∙s^-1 (0.07% to 0.1%). These experiments also yield accurate values of the refractive index differences for the solution pairs used in the diffusion experiments. The new diffusion coefficients are compared to two sets of published values of diffusion coefficients for K₂SO₄(aq) which are somewhat discrepant from each other. This study extends and complements our earlier work on the diffusion coefficients of the most common brine salts: NaCl(aq), KCl(aq), MgCl₂(aq), CaCl₂(aq), Na₂SO₄(aq),^]MgSO₄(aq), NaHCO₃(aq), and KHCO₃(aq) at 298.15 K.

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Research Organization:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC52-07NA27344; W-7405-Eng-48

OSTI ID:: 1860789

Report Number(s):: LLNL-JRNL-824363; 1037813

Journal Information:: Journal of Solution Chemistry, Vol. 50, Issue 11-12; ISSN 0095-9782

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
diffusion coefficients
Rayleigh interferometry
aqueous K2SO4
refractive index increments

Title: Mutual Diffusion Coefficients and Refractive Index Increments of K2SO4(aq) at 298.15 K from Rayleigh Interferometry

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References (48)

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Title: Mutual Diffusion Coefficients and Refractive Index Increments of K₂SO₄(aq) at 298.15 K from Rayleigh Interferometry