Comparison of the dielectric and magnetocaloric properties of bulk and film of GdFe0.5Cr0.5O3

Shi, Jianhang; Seehra, Mohindar S.; Dang, Yanliu; Suib, Steven L.; Jain, Menka

doi:10.1063/5.0048828

Title: Comparison of the dielectric and magnetocaloric properties of bulk and film of GdFe_0.5Cr_0.5O₃

Journal Article · Mon Jun 28 00:00:00 EDT 2021 · Journal of Applied Physics

DOI:https://doi.org/10.1063/5.0048828· OSTI ID:1838052

^[1];

^[2]; Dang, Yanliu ^[1]; Suib, Steven L. ^[1];

^[1]

Univ. of Connecticut, Storrs, CT (United States)
West Virginia Univ., Morgantown, WV (United States)

Here, we report a comparison of the magnetic, magnetocaloric, and dielectric properties of 50% iron substituted GdCrO₃ (GdFe_0.5Cr_0.5O₃) bulk pellet and 960 nm thick film of GdFe_0.5Cr_0.5O₃ (GFCO). The 960 nm film was synthesized on a platinized-silicon substrate by chem. soln. deposition and spin-coating methods. The X-ray diffraction scans of the bulk sample and the film as well as the morphology of the film as examined by the field-emission scanning electron microscope indicate phase-pure and polycrystalline nature of these samples. XPS was used to deermine the valence states of Gd, Fe, and Cr. The temp. dependence of the dielectric const. from 225 to 700 K shows peaks at T_C = 525 K for the bulk and ≈450 K for the film due to ferroelectric to paraelectric transitions, since elec. polarization vs elec. field hysteresis loops are observed. at room temp. The dielectric studies in the bulk GFCO for T > T_C indicate a relaxor-like behavior. The measurements of the magnetization (M) of the samples as a function of temp. (5-350 K) and magnetic field (H) up to 7 T (=70 kOe) depict hysteresis behavior at low temps. due to the canted antiferromagnetic order of Fe³⁺/Cr³⁺ below the Néel temp. of ≈275 K. The M vs H isotherms at various temps. are used to det. and compare the magnetic entropy change (-ΔS) and relative cooling power (RCP) of the two samples, yielding (-ΔS) = 30.7 J/kg K (18.8 J/kg K) and RCP = 566.5 J/kg (375 J/kg) for the bulk (960 nm film) samples of GFCO at 7 K and 7 T, resp. The plot of RCP vs T shows that magnetic cooling for this system is most effective for T < 30 K. Comparatively smaller magnitudes of (-ΔS) and RCP for the film vis-a-vis the bulk sample of GFCO scale with its reduced magnetization. This suggests that further improvements in the quality of the films are needed to improve their magnetization and hence their magnetocaloric properties, possibly making them useful for on-chip cooling in miniaturized devices.

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Research Organization:: Univ. of Connecticut, Storrs, CT (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE

Grant/Contract Number:: FG02-86ER13622

OSTI ID:: 1838052

Alternate ID(s):: OSTI ID: 1798932

Journal Information:: Journal of Applied Physics, Vol. 129, Issue 24; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Thin films
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Title: Comparison of the dielectric and magnetocaloric properties of bulk and film of GdFe0.5Cr0.5O3

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Title: Comparison of the dielectric and magnetocaloric properties of bulk and film of GdFe_0.5Cr_0.5O₃