Kinetics of Ion Exchange of Zr/Sn(IV) Phosphonate–Phosphate Hybrid Materials for Separation of Lanthanides from Oxidized Actinides

Burns, Jonathan D.; Clearfield, Abraham

doi:10.1080/07366299.2018.1542971

Title: Kinetics of Ion Exchange of Zr/Sn(IV) Phosphonate–Phosphate Hybrid Materials for Separation of Lanthanides from Oxidized Actinides

Journal Article · Wed Nov 14 00:00:00 EST 2018 · Solvent Extraction and Ion Exchange

DOI:https://doi.org/10.1080/07366299.2018.1542971· OSTI ID:1832760

^[1]; Clearfield, Abraham ^[1]

Texas A & M Univ., College Station, TX (United States)

The kinetics of ion exchange of Zr/Sn(IV) phosphonate-phosphate hybrid ion exchange materials have been studied with several types of ions of specific interest to nuclear fuel recycling including Nd³⁺ at 4.5 and 43 mM and NpO₂+ at 2.9 mM spanning multiple HNO₃ concentrations. In most cases the equilibrium was reached in less than 12 h. The ion exchange behavior followed that of pseudo first-order adsorption with rates ranging from 0.430–4.10 h^-1 and 0.290–0.435 h^-1 for Nd³⁺ and NpO₂⁺, respectively. A separation with both Nd³⁺ and NpO₂⁺ present was performed, resulting in separation factors of 1.9–12, 1.7–6.6, and 2.0–5.7 at 1×10^-1, 1×10^-2, and 1×10^-3 M HNO₃, respectively.

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Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE), Nuclear Energy University Program (NEUP)

Grant/Contract Number:: NE0000746

OSTI ID:: 1832760

Journal Information:: Solvent Extraction and Ion Exchange, Vol. 36, Issue 7; ISSN 0736-6299

Publisher:: Taylor and FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 1 work

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Title: Kinetics of Ion Exchange of Zr/Sn(IV) Phosphonate–Phosphate Hybrid Materials for Separation of Lanthanides from Oxidized Actinides

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