Sustainable and Inexpensive Polydimethylsiloxane Sponges for Daytime Radiative Cooling

Zhou, Lyu; Rada, Jacob; Zhang, Huafan; Song, Haomin; Mirniaharikandi, Seyededriss; Ooi, Boon S.; Gan, Qiaoqiang

doi:10.1002/advs.202102502

Title: Sustainable and Inexpensive Polydimethylsiloxane Sponges for Daytime Radiative Cooling

Journal Article · Wed Oct 20 00:00:00 EDT 2021 · Advanced Science

DOI:https://doi.org/10.1002/advs.202102502· OSTI ID:1831812

^[1]; Rada, Jacob ^[1]; Zhang, Huafan ^[2]; Song, Haomin ^[1]; Mirniaharikandi, Seyededriss ^[1]; Ooi, Boon S. ^[2];

^[1]

State Univ. of New York at Buffalo, NY (United States)
King Abdullah University of Science and Technology (KAUST), Thuwal (Saudi Arabia)

Radiative cooling is an emerging cooling technology that can passively release heat to the environment. To obtain a subambient cooling effect during the daytime, chemically engineered structural materials are widely explored to simultaneously reject sunlight and preserve strong thermal emission. However, many previously reported fabrication processes involve hazardous chemicals, which can hinder a material’s ability to be mass produced. In order to eliminate the hazardous chemicals used in the fabrication of previous works, this article reports a white polydimethylsiloxane (PDMS) sponge fabricated by a sustainable process using microsugar templates. By substituting the chemicals for sugar, the manufacturing procedure produces zero toxic waste and can also be endlessly recycled via methods widely used in the sugar industry. The obtained porous PDMS exhibits strong visible scattering and thermal emission, resulting in an efficient temperature reduction of 4.6 °C and cooling power of 43 W m^–2 under direct solar irradiation. In addition, due to the air-filled voids within the PDMS sponge, its thermal conductivity remains low at 0.06 W (m K)^–1. This unique combination of radiative cooling and thermal insulation properties can efficiently suppress the heat exchange with the solar-heated rooftop or the environment, representing a promising future for new energy-efficient building envelope material.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: State Univ. of New York at Buffalo, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF)

Grant/Contract Number:: FE0031960; CBET-1932968

OSTI ID:: 1831812

Journal Information:: Advanced Science, Vol. 8, Issue 23; ISSN 2198-3844

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (42)

Radiative Cooling: Principles, Progress, and Potentials Hossain, Md. Muntasir; Gu, Min Advanced Science, Vol. 3, Issue 7 https://doi.org/10.1002/advs.201500360	journal	February 2016
Keeping cool: Enhanced optical reflection and radiative heat dissipation in Saharan silver ants Shi, N. N.; Tsai, C. -C.; Camino, F. Science, Vol. 349, Issue 6245 https://doi.org/10.1126/science.aab3564	journal	June 2015
3D Printing by Multiphase Silicone/Water Capillary Inks Roh, Sangchul; Parekh, Dishit P.; Bharti, Bhuvnesh Advanced Materials, Vol. 29, Issue 30 https://doi.org/10.1002/adma.201701554	journal	June 2017
Superhydrophobic and Recyclable Cellulose-Fiber-Based Composites for High-Efficiency Passive Radiative Cooling Tian, Yanpei; Shao, Hong; Liu, Xiaojie ACS Applied Materials & Interfaces, Vol. 13, Issue 19 https://doi.org/10.1021/acsami.1c04046	journal	May 2021
Scalable and hierarchically designed polymer film as a selective thermal emitter for high-performance all-day radiative cooling Li, Duo; Liu, Xin; Li, Wei Nature Nanotechnology, Vol. 16, Issue 2 https://doi.org/10.1038/s41565-020-00800-4	journal	November 2020
Terrestrial radiative cooling: Using the cold universe as a renewable and sustainable energy source Yin, Xiaobo; Yang, Ronggui; Tan, Gang Science, Vol. 370, Issue 6518 https://doi.org/10.1126/science.abb0971	journal	November 2020
Cellulose-Based Hybrid Structural Material for Radiative Cooling Chen, Yipeng; Dang, Baokang; Fu, Jinzhou Nano Letters, Vol. 21, Issue 1 https://doi.org/10.1021/acs.nanolett.0c03738	journal	December 2020
Creating an Eco‐Friendly Building Coating with Smart Subambient Radiative Cooling Xue, Xiao; Qiu, Meng; Li, Yanwen Advanced Materials, Vol. 32, Issue 42 https://doi.org/10.1002/adma.201906751	journal	September 2020
A radiative cooling structural material Li, Tian; Zhai, Yao; He, Shuaiming Science, Vol. 364, Issue 6442 https://doi.org/10.1126/science.aau9101	journal	May 2019
Passive radiative cooling below ambient air temperature under direct sunlight Raman, Aaswath P.; Anoma, Marc Abou; Zhu, Linxiao Nature, Vol. 515, Issue 7528, p. 540-544 https://doi.org/10.1038/nature13883	journal	November 2014
Recent progress in fabrication and application of polydimethylsiloxane sponges Zhu, Deyong; Handschuh-Wang, Stephan; Zhou, Xuechang Journal of Materials Chemistry A, Vol. 5, Issue 32 https://doi.org/10.1039/C7TA04577H	journal	January 2017
Passive directional sub-ambient daytime radiative cooling Bhatia, Bikram; Leroy, Arny; Shen, Yichen Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07293-9	journal	November 2018
Outdoor‐Useable, Wireless/Battery‐Free Patch‐Type Tissue Oximeter with Radiative Cooling Kang, Min Hyung; Lee, Gil Ju; Lee, Joong Hoon Advanced Science, Vol. 8, Issue 10 https://doi.org/10.1002/advs.202004885	journal	March 2021
Surfaces for radiative cooling: Silicon monoxide films on aluminum Granqvist, C. G.; Hjortsberg, A. Applied Physics Letters, Vol. 36, Issue 2 https://doi.org/10.1063/1.91406	journal	January 1980
Adsorption-based atmospheric water harvesting device for arid climates Kim, Hyunho; Rao, Sameer R.; Kapustin, Eugene A. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03162-7	journal	March 2018
A Janus emitter for passive heat release from enclosures Heo, Se-Yeon; Lee, Gil Ju; Kim, Do Hyeon Science Advances, Vol. 6, Issue 36 https://doi.org/10.1126/sciadv.abb1906	journal	September 2020
Fundamentals, Materials, and Applications for Daytime Radiative Cooling Li, Zizhong; Chen, Qiyuan; Song, Yan Advanced Materials Technologies, Vol. 5, Issue 5 https://doi.org/10.1002/admt.201901007	journal	February 2020
Scalable-manufactured randomized glass-polymer hybrid metamaterial for daytime radiative cooling Zhai, Yao; Ma, Yaoguang; David, Sabrina N. Science, Vol. 355, Issue 6329 https://doi.org/10.1126/science.aai7899	journal	February 2017
Radiative cooling to deep sub-freezing temperatures through a 24-h day–night cycle Chen, Zhen; Zhu, Linxiao; Raman, Aaswath Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13729	journal	December 2016
Multispectral Thermal Management Designs for Net-Zero Energy Buildings Li, Xiuqiang; Xie, Wanrong; Sui, Chenxi ACS Materials Letters, Vol. 2, Issue 12 https://doi.org/10.1021/acsmaterialslett.0c00322	journal	November 2020
Hybrid concentrated radiative cooling and solar heating in a single system Zhou, Lyu; Song, Haomin; Zhang, Nan Cell Reports Physical Science, Vol. 2, Issue 2 https://doi.org/10.1016/j.xcrp.2021.100338	journal	February 2021
Overview of scientific issues involved in selection of polymers for PV applications Kempe, Michael 2011 37th IEEE Photovoltaic Specialists Conference (PVSC) https://doi.org/10.1109/PVSC.2011.6185851	conference	June 2011
Radiative sky cooling: Fundamental principles, materials, and applications Zhao, Dongliang; Aili, Ablimit; Zhai, Yao Applied Physics Reviews, Vol. 6, Issue 2 https://doi.org/10.1063/1.5087281	journal	June 2019
Crystallization Schemes in the Sugar Industry Frenzel, Stefan ChemBioEng Reviews, Vol. 7, Issue 5 https://doi.org/10.1002/cben.202000010	journal	August 2020
A polydimethylsiloxane-coated metal structure for all-day radiative cooling Zhou, Lyu; Song, Haomin; Liang, Jianwei Nature Sustainability, Vol. 2, Issue 8 https://doi.org/10.1038/s41893-019-0348-5	journal	August 2019
Switchable Cavitation in Silicone Coatings for Energy‐Saving Cooling and Heating Zhao, Huaixia; Sun, Qiangqiang; Zhou, Ji Advanced Materials, Vol. 32, Issue 29 https://doi.org/10.1002/adma.202000870	journal	June 2020
Diffuse Reflection of Light from a Matt Surface Berry, Eugene M. Journal of the Optical Society of America, Vol. 7, Issue 8 https://doi.org/10.1364/JOSA.7.000627	journal	January 1923
New refrigerants and system configurations for vapor-compression refrigeration McLinden, Mark O.; Seeton, Christopher J.; Pearson, Andy Science, Vol. 370, Issue 6518 https://doi.org/10.1126/science.abe3692	journal	November 2020
Magnitude of urban heat islands largely explained by climate and population Manoli, Gabriele; Fatichi, Simone; Schläpfer, Markus Nature, Vol. 573, Issue 7772 https://doi.org/10.1038/s41586-019-1512-9	journal	September 2019
Radiative human body cooling by nanoporous polyethylene textile Hsu, Po-Chun; Song, Alex Y.; Catrysse, Peter B. Science, Vol. 353, Issue 6303 https://doi.org/10.1126/science.aaf5471	journal	September 2016
Broadband directional control of thermal emission Xu, Jin; Mandal, Jyotirmoy; Raman, Aaswath P. Science, Vol. 372, Issue 6540 https://doi.org/10.1126/science.abc5381	journal	April 2021
A “PDMS-in-water” emulsion enables mechanochemically robust superhydrophobic surfaces with self-healing nature Ge, Mingzheng; Cao, Chunyan; Liang, Fanghua Nanoscale Horizons, Vol. 5, Issue 1 https://doi.org/10.1039/C9NH00519F	journal	January 2020
Paints as a Scalable and Effective Radiative Cooling Technology for Buildings Mandal, Jyotirmoy; Yang, Yuan; Yu, Nanfang Joule, Vol. 4, Issue 7 https://doi.org/10.1016/j.joule.2020.04.010	journal	July 2020
Reconfigurable and Renewable Nano‐Micro‐Structured Plastics for Radiative Cooling Gao, Wei; Lei, Zhouyue; Wu, Kai Advanced Functional Materials, Vol. 31, Issue 21 https://doi.org/10.1002/adfm.202100535	journal	March 2021
A Subambient Open Roof Surface under the Mid-Summer Sun Gentle, Angus R.; Smith, Geoff B. Advanced Science, Vol. 2, Issue 9 https://doi.org/10.1002/advs.201500119	journal	May 2015
Physical and behavioral adaptations to prevent overheating of the living wings of butterflies Tsai, Cheng-Chia; Childers, Richard A.; Nan Shi, Norman Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14408-8	journal	January 2020
Full Daytime Sub-ambient Radiative Cooling in Commercial-like Paints with High Figure of Merit Li, Xiangyu; Peoples, Joseph; Huang, Zhifeng Cell Reports Physical Science, Vol. 1, Issue 10 https://doi.org/10.1016/j.xcrp.2020.100221	journal	October 2020
Hierarchically porous polymer coatings for highly efficient passive daytime radiative cooling Mandal, Jyotirmoy; Fu, Yanke; Overvig, Adam C. Science, Vol. 362, Issue 6412 https://doi.org/10.1126/science.aat9513	journal	September 2018
Inflatable Elastomeric Macroporous Polymers Synthesized from Medium Internal Phase Emulsion Templates Tebboth, Michael; Jiang, Qixiang; Kogelbauer, Andreas ACS Applied Materials & Interfaces, Vol. 7, Issue 34 https://doi.org/10.1021/acsami.5b05123	journal	August 2015
The radiative cooling of selective surfaces Catalanotti, S.; Cuomo, V.; Piro, G. Solar Energy, Vol. 17, Issue 2, p. 83-89 https://doi.org/10.1016/0038-092X(75)90062-6	journal	May 1975
High-performance subambient radiative cooling enabled by optically selective and thermally insulating polyethylene aerogel Leroy, A.; Bhatia, B.; Kelsall, C. C. Science Advances, Vol. 5, Issue 10 https://doi.org/10.1126/sciadv.aat9480	journal	October 2019
Bio-Inspired Self-Cleaning Surfaces Liu, Kesong; Jiang, Lei Annual Review of Materials Research, Vol. 42, Issue 1 https://doi.org/10.1146/annurev-matsci-070511-155046	journal	August 2012

Similar Records

Effects of geometry and composition of soft polymer films embedded with nanoparticles on rates for optothermal heat dissipation

Journal Article · Tue Jun 12 00:00:00 EDT 2018 · Nanoscale · OSTI ID:1831812

Roper, D. Keith; Berry, Keith R.; Dunklin, Jeremy R.; +4 more

Radiative cooling for energy sustainability: Materials, systems, and applications

Journal Article · Tue Sep 20 00:00:00 EDT 2022 · Physical Review Materials · OSTI ID:1831812

Zhou, Lyu; Rada, Jacob; Tian, Yanpei; +4 more

Multiwalled carbon nanotube/polydimethylsiloxane composite films as high performance flexible electric heating elements

Journal Article · Mon Aug 04 00:00:00 EDT 2014 · Applied Physics Letters · OSTI ID:1831812

Yan, Jing

Related Subjects

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
building envelope
radiative cooling
sustainability
thermal management

Title: Sustainable and Inexpensive Polydimethylsiloxane Sponges for Daytime Radiative Cooling

Citation Formats

References (42)

Similar Records

Related Subjects