A new carbon-incorporated lithium phosphate solid electrolyte

Xia, He-Yi; Wang, Xin-Xin; Ren, Guo-Xi; Wang, Wei-Wen; Zhou, Yong-Ning; Shadike, Zulipiya; Hu, Enyuan; Yang, Xiao-Qing; Zheng, Jie-Yun; Liu, Xiao-Song; Fu, Zheng-Wen

doi:10.1016/j.jpowsour.2021.230603

Title: A new carbon-incorporated lithium phosphate solid electrolyte

Journal Article · Fri Oct 08 00:00:00 EDT 2021 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2021.230603· OSTI ID:1827723

Xia, He-Yi ^[1]; Wang, Xin-Xin ^[1]; Ren, Guo-Xi ^[2]; Wang, Wei-Wen ^[1]; Zhou, Yong-Ning ^[1];

^[3];

^[4];

^[4]; Zheng, Jie-Yun ^[5]; Liu, Xiao-Song ^[2];

^[1]

Fudan Univ., Shanghai (China)
Chinese Academy of Sciences (CAS), Shanghai (China)
Shanghai Jiao Tong Univ. (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Tianmu Lake Institute of Advanced Energy Storage Technologies, Yangtze River Delta Physics Research Center, Liyang City, Jiangsu (China)

A novel carbon-incorporated lithium phosphate (LiCPON) solid electrolyte is prepared to overcome the deterioration of lithium phosphorus oxynitride (LiPON) via hydrolysis reaction in air as well as improve its ionic conductivity for application in all-solid-state batteries. Physical and electrochemical properties of LiCPON electrolyte have been systematically investigated. The ionic conductivities of LiCPON is about 3.06 × 10^-6 S cm^-1, while relatively low ionic conductivity of 7.46 × 10^-7 S cm^-1 is achieved for LiPON. All-solid-state thin-film LiFeFe(CN)₆/LiCPON/Li full cell consists of two unit cells externally connected in parallel delivers a high discharge capacity of 7.8 mAh. The high overall voltage of 5.0 V is achieved for two unit cells connected in series. XPS results reveal that the addition of C in LiPON can alleviate the hydrolysis reaction of LiPON and improve its chemical stability in air. Overall, high ionic conductivity and improved air stability make glassy LiCPON a promising new electrolyte for all-solid-state Li metal batteries.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: SC0012704; 28-ID-2

OSTI ID:: 1827723

Alternate ID(s):: OSTI ID: 1868594

Report Number(s):: BNL-222254-2021-JAAM

Journal Information:: Journal of Power Sources, Vol. 514; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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