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Title: Determination of Carbon Functional Groups in Pyrolysis Bio-Oils using 13C NMR: Laboratory Analytical Procedure (LAP)

Technical Report ·
DOI:https://doi.org/10.2172/1825871· OSTI ID:1825871

Pyrolysis is a process that can be used to convert biomass to solid, liquid and gaseous products for use as renewable chemicals and fuels. The liquid fraction, known as “bio-oil” is complex and challenging to characterize, particularly by means of GC/MS, GPC, LC and FT-IR. NMR is capable of analyzing whole bio-oil samples and can provide quantitative results to characterize different functional groups or types of carbon present in bio-oil. This Laboratory Analytical Procedure (LAP) quantifies different carbon functional groups in whole bio-oil samples. This information can be used for comparisons between different pyrolysis experimental conditions or different upgrading processes and catalysts, and also allow for comparisons between bio-oils produced at different facilities.

Research Organization:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office
DOE Contract Number:
AC36-08GO28308
OSTI ID:
1825871
Report Number(s):
NREL/TP-5100-80969; MainId:78747; UUID:ca9c06ca-6065-497f-9e01-f2f810c24fd1; MainAdminID:63045
Country of Publication:
United States
Language:
English