Ferroelectric Polarization and Second Harmonic Generation in Supramolecular Cocrystals with Two Axes of Charge-Transfer

Narayanan, Ashwin; Cao, Dennis; Frazer, Laszlo; Tayi, Alok S.; Blackburn, Anthea K.; Sue, Andrew C.-H.; Ketterson, John B.; Stoddart, J. Fraser; Stupp, Samuel I.

doi:10.1021/jacs.7b02279

Title: Ferroelectric Polarization and Second Harmonic Generation in Supramolecular Cocrystals with Two Axes of Charge-Transfer

Journal Article · Thu Jun 29 00:00:00 EDT 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b02279· OSTI ID:1821883

Narayanan, Ashwin ^[1]; Cao, Dennis ^[1]; Frazer, Laszlo ^[1]; Tayi, Alok S. ^[1]; Blackburn, Anthea K. ^[1]; Sue, Andrew C.-H. ^[1]; Ketterson, John B. ^[1];

^[1];

^[2]

Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Chicago, IL (United States)
Northwestern Univ., Chicago, IL (United States)

Ferroelectricity in organic materials remains a subject of great interest, given its potential impact as lightweight information storage media. Here we report supramolecular charge-transfer cocrystals formed by electron acceptor and donor molecules that exhibit ferroelectric behavior along two distinct crystallographic axes. The solid-state superstructure of the cocrystals reveals that a 2:1 ratio of acceptor to donor molecules assemble into nearly orthogonal mixed stacks in which the molecules are positioned for charge-transfer in face-to-face and edge-to-face orientations, held together by an extended hydrogen-bonding network. Polarization hysteresis was observed along the face-to-face and edge-to-face axes at room temperature. The noncentrosymmetric nature of the cocrystals, required to observe ferroelectric behavior, is demonstrated using second harmonic generation measurements. This finding suggests the possibility of designing supramolecular arrays in which organic molecules support multidimensional information storage.

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Research Organization:: Northwestern Univ., Evanston, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Bio-Inspired Energy Science (CBES)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-00ER45810

OSTI ID:: 1821883

Alternate ID(s):: OSTI ID: 1846799

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 27; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 53 works

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
99 GENERAL AND MISCELLANEOUS
Charge transfer
Nonlinear optics
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