Magnetic and dielectric property control in the multivalent nanoscale perovskite Eu0.5Ba0.5TiO3

Farahmand, Nasim; McGinn, Christine K.; Zhang, Qize; Gai, Zheng; Kymissis, Ioannis; O'Brien, Stephen

doi:10.1039/d1nr00588j

Title: Magnetic and dielectric property control in the multivalent nanoscale perovskite Eu_0.5Ba_0.5TiO₃

Journal Article · Thu May 06 00:00:00 EDT 2021 · Nanoscale

DOI:https://doi.org/10.1039/d1nr00588j· OSTI ID:1819575

Farahmand, Nasim ^[1]; McGinn, Christine K. ^[2]; Zhang, Qize ^[3];

^[4]; Kymissis, Ioannis ^[2];

^[1]

City Univ. of New York (CUNY), NY (United States). The CUNY Energy Inst.
Columbia Univ., New York, NY (United States)
City Univ. of New York (CUNY), NY (United States). The Graduate Center of the City University of New York
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

We report nanoscale Eu_0.5Ba_0.5TiO₃, a multiferroic in the bulk and candidate in the search to quantify the electric dipole moment of the electron. Eu_0.5Ba_0.5TiO₃, in the form of nanoparticles and other nanostructures is interesting for nanocomposite integration, biomedical imaging and fundamental research, based upon the prospect of polarizability, f-orbital magnetism and tunable optical/radio luminescence. We developed a [non-hydrolytic]sol–[H₂O-activated]gel route, derived from in-house metallic Ba_(s)/Eu_(s) alkoxide precursors and Ti{(OCH(CH₃)₂}₄. Two distinct nanoscale compounds of Ba:Ti:Eu with the parent perovskite crystal structure were produced, with variable dielectric, magnetic and optical properties, based on altering the oxidizing/reducing conditions. Eu_0.5Ba_0.5TiO₃ prepared under air/O₂ atmospheres produced a spherical core–shell nanostructure (30–35 nm), with perovskite Eu_0.5Ba_0.5TiO₃ nanocrystal core-insulating oxide shell layer (~3 nm), presumed a pre-pyrochlore layer abundant with Eu³⁺. Fluorescence spectroscopy shows a high intensity ⁵D₀ → ⁷F₂ transition at 622 nm and strong red fluorescence. The core/shell structure demonstrated excellent capacitive properties: assembly into dielectric thin films gave low conductivity (2133 GΩ mm^-1) and an extremely stable, low loss permittivity of ε_eff ~25 over a wide frequency range (tanδ < 0.01, 100 kHz–2 MHz). Eu_0.5Ba_0.5TiO₃ prepared under H₂/argon produced more irregular shaped nanocrystals (20–25) nm, with a thin film permittivity around 4 times greater (ε_eff 101, tan δ < 0.05, 10 kHz–2 MHz, σ ~59.54 kΩ mm^-1). Field-cooled magnetization values of 0.025 emu g^-1 for EBTO-Air and 0.84 emu g^-1 for EBTO-Argon were observed. X-ray photoelectron spectroscopy analysis reveals a complex interplay of Eu^II/III/Ti^III/IV configurations which contribute to the observed ferroic and fluorescence behavior.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; 1461499; 1547830; CNMS2017-211

OSTI ID:: 1819575

Alternate ID(s):: OSTI ID: 1782964

Journal Information:: Nanoscale, Vol. 13, Issue 23; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (95)

Emergent phenomena at multiferroic heterointerfaces Yu, P.; Chu, Y. H.; Ramesh, R. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 370, Issue 1977 https://doi.org/10.1098/rsta.2012.0199	journal	October 2012
Traversing Energy Landscapes Away from Equilibrium: Strategies for Accessing and Utilizing Metastable Phase Space Parija, Abhishek; Waetzig, Gregory R.; Andrews, Justin L. The Journal of Physical Chemistry C, Vol. 122, Issue 45 https://doi.org/10.1021/acs.jpcc.8b04622	journal	July 2018
Narrow band photoluminescence of europium-doped liquid crystals Binnemans, Koen; Moors, Dries Journal of Materials Chemistry, Vol. 12, Issue 12 https://doi.org/10.1039/b206810a	journal	September 2002
Surfactant-Free Shape Control of Gold Nanoparticles Enabled by Unified Theoretical Framework of Nanocrystal Synthesis Wall, Matthew A.; Harmsen, Stefan; Pal, Soumik Advanced Materials, Vol. 29, Issue 21 https://doi.org/10.1002/adma.201605622	journal	April 2017
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Synthesis of BaTiO ₃ @TiO ₂ -sheet Core-Shell Structured Nanocomposites Nawanil, Chanisa; Panprom, Parinya; Makcharoen, Worawut Integrated Ferroelectrics, Vol. 195, Issue 1 https://doi.org/10.1080/10584587.2019.1570033	journal	January 2019
Barium titanate perovskite nanoparticles as a photoreactive medium for chemical warfare agent detoxification Giannakoudakis, Dimitrios A.; Pearsall, Frederick; Florent, Marc Journal of Colloid and Interface Science, Vol. 531 https://doi.org/10.1016/j.jcis.2018.07.053	journal	December 2018
Why Are There so Few Magnetic Ferroelectrics? Hill, Nicola A. The Journal of Physical Chemistry B, Vol. 104, Issue 29 https://doi.org/10.1021/jp000114x	journal	July 2000
Multiferroics: Past, present, and future Spaldin, Nicola A. MRS Bulletin, Vol. 42, Issue 05 https://doi.org/10.1557/mrs.2017.86	journal	May 2017
A multiferroic material to search for the permanent electric dipole moment of the electron Rushchanskii, K. Z.; Kamba, S.; Goian, V. Nature Materials, Vol. 9, Issue 8 https://doi.org/10.1038/nmat2799	journal	July 2010
Nanoparticles as multimodal photon transducers of ionizing radiation Pratt, Edwin C.; Shaffer, Travis M.; Zhang, Qize Nature Nanotechnology, Vol. 13, Issue 5 https://doi.org/10.1038/s41565-018-0086-2	journal	March 2018
Comparison of Methods for Surface Modification of Barium Titanate Nanoparticles for Aqueous Dispersibility: Toward Biomedical Utilization of Perovskite Oxides Huang, Richard H.; Sobol, Nicholas B.; Younes, Ali ACS Applied Materials & Interfaces, Vol. 12, Issue 46 https://doi.org/10.1021/acsami.0c10063	journal	September 2020
Emergent Superstructural Dynamic Order due to Competing Antiferroelectric and Antiferrodistortive Instabilities in Bulk ${EuTiO}_{3}$ Kim, Jong-Woo; Thompson, Paul; Brown, Simon Physical Review Letters, Vol. 110, Issue 2 https://doi.org/10.1103/PhysRevLett.110.027201	journal	January 2013
Multiferroic crossover in perovskite oxides Weston, L.; Cui, X. Y.; Ringer, S. P. Physical Review B, Vol. 93, Issue 16 https://doi.org/10.1103/PhysRevB.93.165210	journal	April 2016
Magnetic and Electric Phase Control in Epitaxial ${EuTiO}_{3}$ from First Principles Fennie, Craig J.; Rabe, Karin M. Physical Review Letters, Vol. 97, Issue 26 https://doi.org/10.1103/PhysRevLett.97.267602	journal	December 2006
STRUCTURAL, MAGNETIC AND DIELECTRIC PROPERTIES OF Fe -DOPED BaTiO ₃ SOLIDS Guo, Zhengang; Yang, Lihong; Qiu, Hongmei Modern Physics Letters B, Vol. 26, Issue 09 https://doi.org/10.1142/S021798491250056X	journal	April 2012
Europium-Based Fluorescence Nanoparticle Sensor for Rapid and Ultrasensitive Detection of an Anthrax Biomarker Ai, Kelong; Zhang, Baohua; Lu, Lehui Angewandte Chemie International Edition, Vol. 48, Issue 2 https://doi.org/10.1002/anie.200804231	journal	January 2009
Correlation among photoluminescence and the electronic and atomic structures of Sr2SiO4:xEu3+ phosphors: X-ray absorption and emission studies Zheng, Shi-Yan; Chiou, Jau-Wern; Li, Yueh-Han Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-69428-7	journal	July 2020
Manipulating multiple order parameters via oxygen vacancies: The case of $E u_{0.5} B a_{0.5} Ti O_{3 - δ}$ Li, Weiwei; He, Qian; Wang, Le Physical Review B, Vol. 96, Issue 11 https://doi.org/10.1103/PhysRevB.96.115105	journal	September 2017
Fluorescence properties with red-shift of Eu2+ emission in novel phosphor-silicate apatite Sr3LaNa(PO4)2SiO4 phosphors Guo, Yue; Moon, Byung Kee; Choi, Byung Chun Ceramics International, Vol. 42, Issue 16 https://doi.org/10.1016/j.ceramint.2016.08.163	journal	December 2016
Abnormal Reduction, Eu ³⁺ → Eu ²⁺ , and Defect Centers in Eu ³⁺ -Doped Pollucite, CsAlSi ₂ O ₆ , Prepared in an Oxidizing Atmosphere Xie, Hongde; Lu, Juan; Guan, Ying Inorganic Chemistry, Vol. 53, Issue 2 https://doi.org/10.1021/ic402169w	journal	December 2013
Outstanding Photoluminescence in Pr3+-Doped Perovskite Ceramics Zhang, Jiameng; Hao, Yanan; Bi, Meihua Micromachines, Vol. 9, Issue 9 https://doi.org/10.3390/mi9090419	journal	August 2018
Ferroelectric order in individual nanometre-scale crystals Polking, Mark J.; Han, Myung-Geun; Yourdkhani, Amin Nature Materials, Vol. 11, Issue 8 https://doi.org/10.1038/nmat3371	journal	July 2012
Review of functional titanium oxides. I: TiO2 and its modifications Rahimi, Nazanin; Pax, Randolph A.; Gray, Evan MacA. Progress in Solid State Chemistry, Vol. 44, Issue 3 https://doi.org/10.1016/j.progsolidstchem.2016.07.002	journal	September 2016
Inherently Eu ²⁺ /Eu ³⁺ Codoped Sc ₂ O ₃ Nanoparticles as High-Performance Nanothermometers Pan, Yue; Xie, Xiaoji; Huang, Qianwen Advanced Materials, Vol. 30, Issue 14 https://doi.org/10.1002/adma.201705256	journal	February 2018
Dielectric, magnetic and structural properties of novel multiferroic Eu _0.5 Ba _0.5 TiO ₃ ceramics Goian, V.; Kamba, S.; Nuzhnyy, D. Journal of Physics: Condensed Matter, Vol. 23, Issue 2 https://doi.org/10.1088/0953-8984/23/2/025904	journal	December 2010
Magnetodielectric effect and optic soft mode behaviour in quantum paraelectric EuTiO ₃ ceramics Kamba, S.; Nuzhnyy, D.; Vaněk, P. Europhysics Letters (EPL), Vol. 80, Issue 2 https://doi.org/10.1209/0295-5075/80/27002	journal	September 2007
Monomer Derived Poly(Furfuryl)/BaTiO ₃ 0–3 Nanocomposite Capacitors: Maximization of the Effective Permittivity Through Control at the Interface Pearsall, Frederick A.; Lombardi, Julien; O’Brien, Stephen ACS Applied Materials & Interfaces, Vol. 9, Issue 46 https://doi.org/10.1021/acsami.7b13879	journal	November 2017
Synthesis of luminescent bioapatite nanoparticles for utilization as a biological probe Doat, A.; Pellé, F.; Gardant, N. Journal of Solid State Chemistry, Vol. 177, Issue 4-5 https://doi.org/10.1016/j.jssc.2003.10.023	journal	April 2004
Oxygen-Vacancy-Induced Antiferromagnetism to Ferromagnetism Transformation in Eu0.5Ba0.5TiO3−δ Multiferroic Thin Films Li, Weiwei; Zhao, Run; Wang, Le Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02618	journal	September 2013
Rare earths in barites: distribution and effects on aqueous partitioning Guichard, François; Church, Thomas M.; Treuil, Michel Geochimica et Cosmochimica Acta, Vol. 43, Issue 7 https://doi.org/10.1016/0016-7037(79)90088-7	journal	July 1979
Barium titanate nanocrystals and nanocrystal thin films: Synthesis, ferroelectricity, and dielectric properties Huang, Limin; Chen, Zhuoying; Wilson, James D. Journal of Applied Physics, Vol. 100, Issue 3 https://doi.org/10.1063/1.2218765	journal	August 2006
25th Anniversary Article: Colloidal Quantum Dot Materials and Devices: A Quarter-Century of Advances Kim, Jin Young; Voznyy, Oleksandr; Zhitomirsky, David Advanced Materials, Vol. 25, Issue 36 https://doi.org/10.1002/adma.201301947	journal	September 2013
Soft-x-ray-absorption studies of the location of extra charges induced by substitution in controlled-valence materials Abbate, M.; de Groot, F. M. F.; Fuggle, J. C. Physical Review B, Vol. 44, Issue 11 https://doi.org/10.1103/PhysRevB.44.5419	journal	September 1991
Effects of Eu substituting positions and concentrations on luminescent, dielectric, and magnetic properties of SrTiO3 ceramics Jiang, Chunge; Fang, Liang; Shen, Mingrong Applied Physics Letters, Vol. 94, Issue 7 https://doi.org/10.1063/1.3082097	journal	February 2009
XPS and FTIR Surface Characterization of TiO ₂ Particles Used in Polymer Encapsulation Erdem, Bedri; Hunsicker, Robert A.; Simmons, Gary W. Langmuir, Vol. 17, Issue 9 https://doi.org/10.1021/la0015213	journal	May 2001
Antiferrodistortive phase transition in EuTiO $_{3}$ Goian, V.; Kamba, S.; Pacherová, O. Physical Review B, Vol. 86, Issue 5 https://doi.org/10.1103/PhysRevB.86.054112	journal	August 2012
Asymmetric leakage in (Ba, Sr)TiO ₃ nanoparticle/parylene-C composite capacitors Yang, Shyuan; Tull, Brian R.; Pervez, Nadia K. Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 1 https://doi.org/10.1002/polb.23156	journal	August 2012
The `dissolution' of europium and ytterbium in alcohols Carretas, J. M.; Branco, J.; Marçalo, J. Journal of Alloys and Compounds, Vol. 275-277 https://doi.org/10.1016/S0925-8388(98)00454-X	journal	July 1998
Limit on the Electron Electric Dipole Moment Using Paramagnetic Ferroelectric ${Eu}_{0.5} {Ba}_{0.5} {TiO}_{3}$ Eckel, S.; Sushkov, A. O.; Lamoreaux, S. K. Physical Review Letters, Vol. 109, Issue 19 https://doi.org/10.1103/PhysRevLett.109.193003	journal	November 2012
Europium incorporated barium titanate thin films for optical applications Maneeshya, L. V.; Lekshmy, S. Sujatha; Thomas, P. V. Journal of Materials Science: Materials in Electronics, Vol. 25, Issue 6 https://doi.org/10.1007/s10854-014-1903-5	journal	April 2014
Structure–property trends in a hollandite multiferroic by Fe doping: structural, magnetic and dielectric characterization of nanocrystalline BaMn _3−x Fe _x Ti ₄ O _14+δ Pearsall, Frederick; Farahmand, Nasim; Lombardi, Julien Journal of Materials Chemistry C, Vol. 8, Issue 23 https://doi.org/10.1039/d0tc00703j	journal	January 2020
X-ray powder diffraction structural characterization of Ba1-xEuxTiO3 ternary oxides Lu, D. -Y.; Sugano, M.; Su, W. -H. Crystal Research and Technology, Vol. 40, Issue 7 https://doi.org/10.1002/crat.200410412	journal	July 2005
Role of nonlocal exchange in the electronic structure of correlated oxides Iori, Federico; Gatti, Matteo; Rubio, Angel Physical Review B, Vol. 85, Issue 11 https://doi.org/10.1103/PhysRevB.85.115129	journal	March 2012
Influence of processing conditions on the grain growth and electrical properties of barium zirconate titanate ferroelectric ceramics Jha, Priyanka Arora; Jha, A. K. Journal of Alloys and Compounds https://doi.org/10.1016/j.jallcom.2011.11.012	journal	November 2011
Revisiting the fascinating properties of EuTiO 3 and its mixed crystals with SrTiO 3 : Possible candidates for novel functionalities Bussmann-Holder, Annette; Köhler, Jürgen Journal of Physics and Chemistry of Solids, Vol. 84 https://doi.org/10.1016/j.jpcs.2014.12.019	journal	September 2015
Preparation and luminescent properties of Eu-doped BaTiO ₃ thin films by sol–gel process Li, Juan; Kuwabara, Makoto Science and Technology of Advanced Materials, Vol. 4, Issue 2 https://doi.org/10.1016/S1468-6996(03)00027-5	journal	January 2003
Luminescence properties of different Eu sites in LiMgPO ₄ :Eu ²⁺ , Eu ³⁺ Baran, A.; Mahlik, S.; Grinberg, M. Journal of Physics: Condensed Matter, Vol. 26, Issue 38 https://doi.org/10.1088/0953-8984/26/38/385401	journal	September 2014
Multiferroic and magnetoelectric materials Eerenstein, W.; Mathur, N. D.; Scott, J. F. Nature, Vol. 442, Issue 7104 https://doi.org/10.1038/nature05023	journal	August 2006
Field Dependence of Magnetic Disorder in Nanoparticles Zákutná, Dominika; Nižňanský, Daniel; Barnsley, Lester C. Physical Review X, Vol. 10, Issue 3 https://doi.org/10.1103/PhysRevX.10.031019	journal	July 2020
Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality Royer, Sébastien; Duprez, Daniel; Can, Fabien Chemical Reviews, Vol. 114, Issue 20 https://doi.org/10.1021/cr500032a	journal	September 2014
Barium titanate nanoparticles: Short-range lattice distortions with long-range cubic order Shi, Chenyang; Billinge, Simon J. L.; Puma, Eric Physical Review B, Vol. 98, Issue 8 https://doi.org/10.1103/PhysRevB.98.085421	journal	August 2018
Effects of Eu substitution on luminescent and magnetic properties of BaTiO3 nanomaterials Fuentes, S.; Barraza, N.; Veloso, E. Journal of Alloys and Compounds, Vol. 569 https://doi.org/10.1016/j.jallcom.2013.02.127	journal	August 2013
Changes in Electronic Structure upon Lithium Insertion into the A-Site Deficient Perovskite Type Oxides (Li,La)TiO ₃ Nakayama, Masanobu; Usui, Tatsuya; Uchimoto, Yoshiharu The Journal of Physical Chemistry B, Vol. 109, Issue 9 https://doi.org/10.1021/jp046062j	journal	March 2005
Metallic and Insulating Oxide Interfaces Controlled by Electronic Correlations Jang, H. W.; Felker, D. A.; Bark, C. W. Science, Vol. 331, Issue 6019 https://doi.org/10.1126/science.1198781	journal	February 2011
Hollandites as a new class of multiferroics Liu, Shuangyi; Akbashev, Andrew R.; Yang, Xiaohao Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06203	journal	August 2014
Coupling between magnetism and dielectric properties in quantum paraelectric ${EuTiO}_{3}$ Katsufuji, T.; Takagi, H. Physical Review B, Vol. 64, Issue 5 https://doi.org/10.1103/PhysRevB.64.054415	journal	July 2001
The effects of the additive of Eu ions on elastic and electric properties of BaTiO ₃ ceramics Sitko, D.; Garbarz-Glos, B.; Piekarczyk, W. Integrated Ferroelectrics, Vol. 173, Issue 1 https://doi.org/10.1080/10584587.2016.1183413	journal	June 2016
Revised Kubelka–Munk theory I Theory and application Yang, Li; Kruse, Björn Journal of the Optical Society of America A, Vol. 21, Issue 10 https://doi.org/10.1364/JOSAA.21.001933	journal	January 2004
Internal Barrier Layer Capacitance Effect in Hexagonal Perovskite Ba ₄ YMn ₃ O _11.5 Ceramics Kuang, Xiaojun; Bridges, Craig; Allix, Mathieu Chemistry of Materials, Vol. 18, Issue 21 https://doi.org/10.1021/cm0612752	journal	October 2006
Synthesis of Monodisperse Nanoparticles of Barium Titanate: Toward a Generalized Strategy of Oxide Nanoparticle Synthesis O'Brien, Stephen; Brus, Louis; Murray, Christopher B. Journal of the American Chemical Society, Vol. 123, Issue 48 https://doi.org/10.1021/ja011414a	journal	December 2001
Prospects for an electron electric-dipole-moment search with ferroelectric (Eu,Ba)TiO $_{3}$ ceramics Sushkov, A. O.; Eckel, S.; Lamoreaux, S. K. Physical Review A, Vol. 81, Issue 2 https://doi.org/10.1103/PhysRevA.81.022104	journal	February 2010
Multiferroic and Magnetoelectric Oxides: The Emerging Scenario Rao, C. N. R.; Sundaresan, A.; Saha, Rana The Journal of Physical Chemistry Letters, Vol. 3, Issue 16 https://doi.org/10.1021/jz300688b	journal	August 2012
Nanomaterials for Electronic Packaging: Toward Extreme Miniaturization [Nanopackaging Das, Rabindra; Markovich, Voya IEEE Nanotechnology Magazine, Vol. 4, Issue 4 https://doi.org/10.1109/MNANO.2010.938653	journal	December 2010
Nanoscale effects and polaronic relaxation in ${CaCu}_{3} {Ti}_{4} O_{12}$ compounds Ribeiro, Willian C.; Joanni, Ednan; Savu, Raluca Solid State Communications, Vol. 151, Issue 2 https://doi.org/10.1016/j.ssc.2010.10.034	journal	January 2011
Pseudo-Jahn–Teller Effect—A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids Bersuker, Isaac B. Chemical Reviews, Vol. 113, Issue 3 https://doi.org/10.1021/cr300279n	journal	January 2013
Electron Spin Resonance Investigations and Compensation Mechanism of Europium-Doped Barium Titanate Ceramics Lu, Da-Yong; Sun, Xiu-Yun; Toda, Masayuki Japanese Journal of Applied Physics, Vol. 45, Issue 11 https://doi.org/10.1143/JJAP.45.8782	journal	November 2006
Oxide Semiconductor Thin-Film Transistors: A Review of Recent Advances Fortunato, E.; Barquinha, P.; Martins, R. Advanced Materials, Vol. 24, Issue 22 https://doi.org/10.1002/adma.201103228	journal	May 2012
Compromising Science by Ignorant Instrument Calibration—Need to Revisit Half a Century of Published XPS Data Greczynski, Grzegorz; Hultman, Lars Angewandte Chemie International Edition, Vol. 59, Issue 13 https://doi.org/10.1002/anie.201916000	journal	March 2020
Photoelectron spectroscopic study of the valence and core-level electronic structure of ${BaTiO}_{3}$ Hudson, L. T.; Kurtz, R. L.; Robey, S. W. Physical Review B, Vol. 47, Issue 3 https://doi.org/10.1103/PhysRevB.47.1174	journal	January 1993
Perovskite Catalysts—A Special Issue on Versatile Oxide Catalysts Lin, Yu-Chuan; Hohn, Keith Catalysts, Vol. 4, Issue 3 https://doi.org/10.3390/catal4030305	journal	August 2014
Understanding the $L_{2, 3}$ x-ray absorption spectra of early $3 d$ transition elements Laskowski, Robert; Blaha, Peter Physical Review B, Vol. 82, Issue 20 https://doi.org/10.1103/PhysRevB.82.205104	journal	November 2010
The electromechanical behavior of europium doped BaTiO3 Jankowska-Sumara, I.; Sitko, D.; Podgórna, M. Journal of Alloys and Compounds, Vol. 724 https://doi.org/10.1016/j.jallcom.2017.07.090	journal	November 2017
Electromagnetic Mixing Formulas and Applications Sihvola, Ari https://doi.org/10.1049/PBEW047E	book	January 1999
Final-state effects in the x-ray photoemission spectrum of ${EuPd}_{2}$ $P_{2}$ Wertheim, G. K.; Sampathkumaran, E. V.; Laubschat, C. Physical Review B, Vol. 31, Issue 10 https://doi.org/10.1103/PhysRevB.31.6836	journal	May 1985
Europium barium titanate—A magnetic ferroelectric compound Janes, D. L.; Bodnar, R. E.; Taylor, A. L. Journal of Applied Physics, Vol. 49, Issue 3 https://doi.org/10.1063/1.324974	journal	March 1978
Luminescent Europium(III) Nanoparticles for Sensing and Imaging of Temperature in the Physiological Range Peng, Hongshang; Stich, Matthias I. J.; Yu, Jiangbo Advanced Materials, Vol. 22, Issue 6 https://doi.org/10.1002/adma.200901614	journal	February 2010
Stoichiometric Control over Ferroic Behavior in Ba(Ti _{1– x} Fe _x )O ₃ Nanocrystals Lombardi, Julien; Yang, Long; Pearsall, Frederick A. Chemistry of Materials, Vol. 31, Issue 4 https://doi.org/10.1021/acs.chemmater.8b04447	journal	January 2019
Photoacoustic imaging in the second near-infrared window: a review Upputuri, Paul Kumar; Pramanik, Manojit Journal of Biomedical Optics, Vol. 24, Issue 04 https://doi.org/10.1117/1.JBO.24.4.040901	journal	April 2019
Magnetoelectric Composites Srinivasan, G. Annual Review of Materials Research, Vol. 40, Issue 1 https://doi.org/10.1146/annurev-matsci-070909-104459	journal	June 2010
Polymer–Nanocrystal Nanocomposites: Device Concepts in Capacitors and Multiferroics Pearsall, Frederick A.; Lombardi, Julien; Farahmand, Nasim IEEE Transactions on Nanotechnology, Vol. 19 https://doi.org/10.1109/TNANO.2019.2939093	journal	January 2020
Perovskite ferroelectric nanomaterials Nuraje, Nurxat; Su, Kai Nanoscale, Vol. 5, Issue 19 https://doi.org/10.1039/c3nr02543h	journal	January 2013
Erratum: Structure and performance of dielectric films based on self-assembled nanocrystals with a high dielectric constant Huang, Limin; Liu, Shuangyi; Van Tassell, Barry J. Nanotechnology, Vol. 24, Issue 49 https://doi.org/10.1088/0957-4484/24/49/499601	journal	November 2013
Searching for new ferroelectrics and multiferroics: A user’s point of view Scott, J. F. npj Computational Materials, Vol. 1, Issue 1 https://doi.org/10.1038/npjcompumats.2015.6	journal	November 2015
Apparent giant dielectric constants, dielectric relaxation, and ac-conductivity of hexagonal perovskites La1.2Sr2.7BO7.33 (B=Ru, Ir) Lunkenheimer, P.; Götzfried, T.; Fichtl, R. Journal of Solid State Chemistry, Vol. 179, Issue 12 https://doi.org/10.1016/j.jssc.2006.09.005	journal	December 2006
Binding energies of Eu2+ and Eu3+ ions in β-Ca2SiO4 doped with europium Baran, Anna; Barzowska, Justyna; Grinberg, Marek Optical Materials, Vol. 35, Issue 12 https://doi.org/10.1016/j.optmat.2013.05.030	journal	October 2013
Long-Lived Two-Photon Excited Luminescence of Water-Soluble Europium Complex: Applications in Biological Imaging Using Two-Photon Scanning Microscopy Picot, Alexandre; D'Aléo, Anthony; Baldeck, Patrice L. Journal of the American Chemical Society, Vol. 130, Issue 5 https://doi.org/10.1021/ja076837c	journal	February 2008
Breakdown voltages in ceramic capacitors with cracks Teverovsky, Alexander IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 19, Issue 4 https://doi.org/10.1109/TDEI.2012.6260022	journal	August 2012
Three-dimensional nanomagnetism Fernández-Pacheco, Amalio; Streubel, Robert; Fruchart, Olivier Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15756	journal	June 2017
Artificial charge-modulationin atomic-scale perovskite titanate superlattices Ohtomo, A.; Muller, D. A.; Grazul, J. L. Nature, Vol. 419, Issue 6905 https://doi.org/10.1038/nature00977	journal	September 2002
Bioactive, luminescent and mesoporous europium-doped hydroxyapatite as a drug carrier Yang, Piaoping; Quan, Zewei; Li, Chunxia Biomaterials, Vol. 29, Issue 32 https://doi.org/10.1016/j.biomaterials.2008.07.042	journal	November 2008
Multiferroics: Different ways to combine magnetism and ferroelectricity Khomskii, D. I. Journal of Magnetism and Magnetic Materials, Vol. 306, Issue 1 https://doi.org/10.1016/j.jmmm.2006.01.238	journal	November 2006
X-ray photoelectron spectroscopy of amorphous and quasiamorphous phases of $Ba Ti O_{3}$ and $Sr Ti O_{3}$ Ehre, David; Cohen, Hagai; Lyahovitskaya, Vera Physical Review B, Vol. 77, Issue 18 https://doi.org/10.1103/PhysRevB.77.184106	journal	May 2008
Origin of band gaps in 3d perovskite oxides Varignon, Julien; Bibes, Manuel; Zunger, Alex Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09698-6	journal	April 2019
Electronic structure of early 3 d -transition-metal oxides by analysis of the 2 p core-level photoemission spectra Bocquet, A. E.; Mizokawa, T.; Morikawa, K. Physical Review B, Vol. 53, Issue 3 https://doi.org/10.1103/PhysRevB.53.1161	journal	January 1996

Similar Records

Structure and microwave dielectric characteristics of lithium-excess Ca{sub 0.6}Nd{sub 0.8/3}TiO{sub 3}/(Li{sub 0.5}Nd{sub 0.5})TiO{sub 3} ceramics

Journal Article · Fri Nov 15 00:00:00 EST 2013 · Materials Research Bulletin · OSTI ID:1819575

Zhou, Changrong; Chen, Guohua; Cen, Zhenyong; +3 more

The magnetic properties of Bi{sub 0.9}Ba{sub 0.1}Fe{sub 0.81}M{sub 0.09}Ti{sub 0.1}O{sub 3} solid solutions (M = Co, Mn, Sc, Al)

Journal Article · Tue Nov 15 00:00:00 EST 2011 · Materials Research Bulletin · OSTI ID:1819575

Shi, Chenyang; Hao, Yongmei; Tan, Yanqing; +1 more

Improvements in electrical and dielectric properties of substituted multiferroic LaMnO{sub 3} based nanostructures synthesized by co-precipitation method

Journal Article · Sat Dec 15 00:00:00 EST 2012 · Materials Research Bulletin · OSTI ID:1819575

Mahmood, Azhar; Ashiq, Muhammad Naeem; Sher, Muhammad

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
nanoscale
magnetic
dielectric

Title: Magnetic and dielectric property control in the multivalent nanoscale perovskite Eu0.5Ba0.5TiO3

Citation Formats

References (95)

Similar Records

Related Subjects

Title: Magnetic and dielectric property control in the multivalent nanoscale perovskite Eu_0.5Ba_0.5TiO₃