4D Printing via an Unconventional Fused Deposition Modeling Route to High-Performance Thermosets

Chen, Qiyi; Han, Lu; Ren, Jingbo; Rong, Lihan; Cao, Pengfei; Advincula, Rigoberto C.

doi:10.1021/acsami.0c13976

Title: 4D Printing via an Unconventional Fused Deposition Modeling Route to High-Performance Thermosets

Journal Article · Mon Oct 26 00:00:00 EDT 2020 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.0c13976· OSTI ID:1805009

Chen, Qiyi ^[1];

^[2]; Ren, Jingbo ^[1]; Rong, Lihan ^[1];

^[2];

^[3]

Case Western Reserve Univ., Cleveland, OH (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Case Western Reserve Univ., Cleveland, OH (United States); Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

An unprecedented four-dimensional (4D) printing process allowing high-performance and shape memory thermoset to be printed, for the first time, by fused deposition modeling (FDM) with isotropic properties has been achieved. Here, bisphenol A-based epoxy and benzoxazine were formulated to a low-temperature thermoplastic and high-temperature thermoset resin, which is melt-extrudable and can be postcured into covalently cross-linked material. Carbon nanotube (CNT) was added in the resin to work as both mechanical enhancement filler and rheology modifier to prevent shape deformation during postcuring process. The cross-layer reaction fuses individual layers into an integrity, thus eliminating layer delamination induced by FDM, offering isotropic mechanical properties regardless of the printing orientations. The highly cross-linked network provides outstanding mechanical strength and superb thermal stability. The excellent shape memory performance with fast recovery rate and large recovery degree is also obtained in the three-dimensional (3D) printed composites.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1805009

Journal Information:: ACS Applied Materials and Interfaces, Vol. 12, Issue 44; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: 4D Printing via an Unconventional Fused Deposition Modeling Route to High-Performance Thermosets

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