Effect of cobalt substitution on structure and magnetic properties of Nd0.4Zr0.6Fe10–xCoxSi2 (x = 0–3) alloys and their ribbons

Gjoka, M.; Sarafidis, C.; Giannopoulos, G.; Niarchos, D.; Hadjipanayis, G.; Tabares, J. A.; Pérez Alcázar, G. A.; Zamora, L. E.

doi:10.1016/j.jre.2019.03.013

Title: Effect of cobalt substitution on structure and magnetic properties of Nd_0.4Zr_0.6Fe_10–xCo_xSi₂ (x = 0–3) alloys and their ribbons

Journal Article · Tue Oct 01 00:00:00 EDT 2019 · Journal of Rare Earths

DOI:https://doi.org/10.1016/j.jre.2019.03.013· OSTI ID:1800712

Gjoka, M. ^[1]; Sarafidis, C. ^[2]; Giannopoulos, G. ^[3]; Niarchos, D. ^[3]; Hadjipanayis, G. ^[4]; Tabares, J. A. ^[5]; Pérez Alcázar, G. A. ^[5]; Zamora, L. E. ^[5]

Institute of Nanoscience and Nanotechnology (NCSR) Athens (Greece); Univ. of Delaware, Newark, DE (United States)
Aristotle University of Thessaloniki (Greece)
Institute of Nanoscience and Nanotechnology (NCSR) Athens (Greece)
Univ. of Delaware, Newark, DE (United States)
Universidad del Valle (Colombia)

This paper reports the stabilization of the RFe₁₂-type based compounds where part of R and Fe are substituted with Zr and Co and Si, respectively, in order to examine whether these rare-earth-lean materials are suitable for applications as permanent magnets. Structural and magnetic characterization of the family of alloys with the general formula Nd_0.4Zr_0.6Fe_10–xCo_xSi₂ (x = 0–3) and their melt-spun ribbons were carried out using X-ray diffraction and Mössbauer spectroscopy. The ThMn₁₂-type structure is obtained for all samples as the majority phase with a minority α-Fe(CoSi) phase (less than 5 wt%) as it was estimated by XRD for x = 1 and 2. The Curie temperature increases linearly with Co substitution from 561 K for x = 0 to 712 K for x = 3. The saturation magnetization decreases slightly from 130.5 (x = 1) to 129.1 A·m²/kg (x = 3), while the anisotropy field is following the same trend.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-90ER45413

OSTI ID:: 1800712

Alternate ID(s):: OSTI ID: 1778571

Journal Information:: Journal of Rare Earths, Vol. 37, Issue 10; ISSN 1002-0721

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (16)

A new magnet material with ThMn 12 structure: (Nd 1−x Zr x )(Fe 1−y Co y ) 11+z Ti 1 − z N α ( α =0.6–1.3) Suzuki, S.; Kuno, T.; Urushibata, K. Journal of Magnetism and Magnetic Materials, Vol. 401 https://doi.org/10.1016/j.jmmm.2015.10.042	journal	March 2016
Structure and magnetic properties of Sm _1-x Zr _x Fe ₁₀ Si ₂ (x=0.2-0.6) alloys Gjoka, M.; Sarafidis, C.; Psycharis, V. Journal of Physics: Conference Series, Vol. 903 https://doi.org/10.1088/1742-6596/903/1/012033	journal	October 2017
Hyperfine interactions and crystal site occupancies in RTiFe11−xCox (R=Y, Dy and Er) as seen by Mössbauer spectroscopy Bara, J. J.; Bogacz, B. F.; Pedziwiatr, A. T. Journal of Alloys and Compounds, Vol. 307, Issue 1-2 https://doi.org/10.1016/S0925-8388(00)00847-1	journal	July 2000
Structure and permanent magnet properties of Zr1-R Fe10Si2 alloys with R = Y, La, Ce, Pr and Sm Gabay, A. M.; Cabassi, R.; Fabbrici, S. Journal of Alloys and Compounds, Vol. 683 https://doi.org/10.1016/j.jallcom.2016.05.092	journal	October 2016
(Sm,Zr)(Fe,Co) _11.0-11.5 Ti _1.0-0.5 compounds as new permanent magnet materials Kuno, Tomoko; Suzuki, Shunji; Urushibata, Kimiko AIP Advances, Vol. 6, Issue 2 https://doi.org/10.1063/1.4943051	journal	February 2016
Effect of Zr substitution on the structural and magnetic properties of the series Nd1−xZrxFe10Si2 with the ThMn12 type structure Gjoka, M.; Psycharis, V.; Devlin, E. Journal of Alloys and Compounds, Vol. 687 https://doi.org/10.1016/j.jallcom.2016.06.098	journal	December 2016
The origin of high magnetic properties in (R,Zr)(Fe,Co)11.0–11.5Ti1.0–0.5Ny (y=1.0–1.4 for R=Nd, y=0 for R=Sm) compounds Kobayashi, K.; Suzuki, S.; Kuno, T. Journal of Magnetism and Magnetic Materials, Vol. 426 https://doi.org/10.1016/j.jmmm.2016.11.070	journal	March 2017
A study on the formation of ThMn12 and NaZn13 structures in RFe10Si2 Sakurada, S.; Tsutai, A.; Sahashi, M. Journal of Alloys and Compounds, Vol. 187, Issue 1 https://doi.org/10.1016/0925-8388(92)90521-A	journal	August 1992
Structure and properties of some novel ternary Fe‐rich rare‐earth intermetallics (invited) Buschow, K. H. J. Journal of Applied Physics, Vol. 63, Issue 8 https://doi.org/10.1063/1.340865	journal	April 1988
The heat capacity of PrCo2 and NdCo2 between 8 and 300°K Deenadas, C.; Craig, R. S.; Marzouk, N. Journal of Solid State Chemistry, Vol. 4, Issue 1 https://doi.org/10.1016/0022-4596(72)90124-7	journal	January 1972
ThMn12-type structure and uniaxial magnetic anisotropy in ZrFe10Si2 and Zr1−Ce Fe10Si2 alloys Gabay, A. M.; Hadjipanayis, G. C. Journal of Alloys and Compounds, Vol. 657 https://doi.org/10.1016/j.jallcom.2015.10.073	journal	February 2016
Recent developments in RFe12-type compounds for permanent magnets Gabay, A. M.; Hadjipanayis, G. C. Scripta Materialia, Vol. 154 https://doi.org/10.1016/j.scriptamat.2017.10.033	journal	September 2018
Some novel ternary ThMn12-type compounds De Mooij, D. B.; Buschow, K. H. J. Journal of the Less Common Metals, Vol. 136, Issue 2 https://doi.org/10.1016/0022-5088(88)90424-9	journal	January 1988
Effects of cobalt addition on microstructure and magnetic properties of PrNdFeB/Fe 7 Co 3 nanocomposite Ding, Hewei; Cui, Chunxiang; Yang, Wei Journal of Rare Earths, Vol. 35, Issue 5 https://doi.org/10.1016/S1002-0721(17)60935-9	journal	May 2017
Formation, crystal structure and magnetic properties of (1:12) compounds in the Fe–Gd–Mo–Zr system Zinkevich, M.; Mattern, N.; Bächer, I. Journal of Alloys and Compounds, Vol. 336, Issue 1-2 https://doi.org/10.1016/S0925-8388(01)01901-6	journal	April 2002
A (Nd, Zr)(Fe, Co) _11.5 Ti _0.5 N _x compound as a permanent magnet material Suzuki, S.; Kuno, T.; Urushibata, K. AIP Advances, Vol. 4, Issue 11 https://doi.org/10.1063/1.4902176	journal	November 2014

Similar Records

Microstructure and Hard Magnetic Properties of Sm_1-xZr_x(Fe,Co)_11.3-yTi_0.7By Ingots and Thick Melt-Spun Ribbons

Journal Article · Tue Aug 03 00:00:00 EDT 2021 · IEEE Transactions on Magnetics · OSTI ID:1800712

Gabay, Alexander M.; Hadjipanayis, George C.

Isotropic nanocrystalline Sm(Fe,Co)_11.3Ti_0.7 magnets modified with B and Zr

Journal Article · Tue Mar 02 00:00:00 EST 2021 · Journal of Magnetism and Magnetic Materials · OSTI ID:1800712

Gabay, Alexander M.; Hadjipanayis, George C.

Role of Ce substitution in the magneto-crystalline anisotropy of tetragonal ZrFe10Si2

Journal Article · Mon Oct 01 00:00:00 EDT 2018 · Journal of Alloys and Compounds · OSTI ID:1800712

Salazar, D.; Martín-Cid, A.; Garitaonandia, J. S.; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry
Permanent magnets
X-ray diffraction
Mössbauer spectroscopy
Rare-earth-lean magnetic materials
Magnetic properties
Melt-spun ribbons

Title: Effect of cobalt substitution on structure and magnetic properties of Nd0.4Zr0.6Fe10–xCoxSi2 (x = 0–3) alloys and their ribbons

Citation Formats

References (16)

Similar Records

Related Subjects

Title: Effect of cobalt substitution on structure and magnetic properties of Nd_0.4Zr_0.6Fe_10–xCo_xSi₂ (x = 0–3) alloys and their ribbons