All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents

Fan, Xiulin; Ji, Xiao; Chen, Long; Chen, Ji; Deng, Tao; Han, Fudong; Yue, Jie; Piao, Nan; Wang, Ruixing; Zhou, Xiuquan; Xiao, Xuezhang; Chen, Lixin; Wang, Chunsheng

doi:10.1038/s41560-019-0474-3

Title: All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents

Journal Article · Mon Oct 07 00:00:00 EDT 2019 · Nature Energy

DOI:https://doi.org/10.1038/s41560-019-0474-3· OSTI ID:1799452

Fan, Xiulin ^[1];

^[2]; Chen, Long ^[2]; Chen, Ji ^[2]; Deng, Tao ^[2]; Han, Fudong ^[2]; Yue, Jie ^[2]; Piao, Nan ^[2]; Wang, Ruixing ^[2];

^[2];

^[3]; Chen, Lixin ^[3];

^[2]

University of Maryland, College Park, MD (United States); Zhejiang University, Hangzhou (China)
University of Maryland, College Park, MD (United States)
Zhejiang University, Hangzhou (China)

We report carbonate electrolytes are commonly used in commercial non-aqueous Li-ion batteries. However, the high affinity between the solvents and the ions and high flammability of the carbonate electrolytes limits the battery operation temperature window from -20 to +50 °C and voltage window from 0.0 to 4.3 V. Here we tamed the affinity between solvents and Li ions of the nonflammable electrolytes by dissolving the fluorinated electrolytes into highly fluorinated non-polar solvents. The tamed non-flammable electrolytes have a wide voltage window of 0.0 to 5.6 V, wide liquid range from -125 to +70 °C, high Li-ion transference number of 0.7, and low Li-ion desolvation energy. In a wide temperature from -95 to +70 °C, the electrolytes enable both commercial graphite anodes and LiNi0.8Mn0.1Co0.1O2 cathodes to achieve a high Coulombic efficiencies of >99.9%, and the most aggressive Li2 anodes and 5.4 V LiCoMnO4 to achieve a Coulombic efficiencies of >99.4% and 99%, respectively. Even at -85 °C, the LiNi_0.8Co_0.15Al_0.05O₂||Li battery can still deliver ~50% of room-temperature capacity

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Research Organization:: Univ. of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008202

OSTI ID:: 1799452

Journal Information:: Nature Energy, Vol. 4, Issue 10; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (60)

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries Fan, Xiulin; Chen, Long; Ji, Xiao Chem, Vol. 4, Issue 1 https://doi.org/10.1016/j.chempr.2017.10.017	journal	January 2018
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Organic Batteries Operated at −70°C Dong, Xiaoli; Guo, Zhaowei; Guo, Ziyang Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.01.017	journal	May 2018
A safe, high-rate and high-energy polymer lithium-ion battery based on gelled membranes prepared by electrospinning Croce, Fausto; Focarete, Maria Letizia; Hassoun, Jusef Energy & Environmental Science, Vol. 4, Issue 3 https://doi.org/10.1039/c0ee00348d	journal	January 2011
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials Lee, Jinhyuk; Kitchaev, Daniil A.; Kwon, Deok-Hwang Nature, Vol. 556, Issue 7700 https://doi.org/10.1038/s41586-018-0015-4	journal	April 2018
Molecular Dynamics Simulations of Ionic Liquids: Cation and Anion Dependence of Self-Diffusion Coefficients of Ions Tsuzuki, Seiji; Shinoda, Wataru; Saito, Hiroaki The Journal of Physical Chemistry B, Vol. 113, Issue 31 https://doi.org/10.1021/jp811128b	journal	August 2009
Recent advances in NiMH battery technology Fetcenko, M. A.; Ovshinsky, S. R.; Reichman, B. Journal of Power Sources, Vol. 165, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.10.036	journal	March 2007
Automatic atom type and bond type perception in molecular mechanical calculations Wang, Junmei; Wang, Wei; Kollman, Peter A. Journal of Molecular Graphics and Modelling, Vol. 25, Issue 2 https://doi.org/10.1016/j.jmgm.2005.12.005	journal	October 2006
Molecular Force Field for Ionic Liquids V: Hydroxyethylimidazolium, Dimethoxy-2- Methylimidazolium, and Fluoroalkylimidazolium Cations and Bis(Fluorosulfonyl)Amide, Perfluoroalkanesulfonylamide, and Fluoroalkylfluorophosphate Anions Shimizu, Karina; Almantariotis, Dimitrios; Gomes, Margarida F. Costa The Journal of Physical Chemistry B, Vol. 114, Issue 10 https://doi.org/10.1021/jp9120468	journal	March 2010
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Lithium Fluoride Additives for Stable Cycling of Lithium Batteries at High Current Densities Choudhury, Snehashis; Archer, Lynden A. Advanced Electronic Materials, Vol. 2, Issue 2 https://doi.org/10.1002/aelm.201500246	journal	January 2016
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
Liquefied gas electrolytes for electrochemical energy storage devices Rustomji, Cyrus S.; Yang, Yangyuchen; Kim, Tae Kyoung Science, Vol. 356, Issue 6345 https://doi.org/10.1126/science.aal4263	journal	June 2017
First-Principles Studies on Cation Dopants and Electrolyte\|Cathode Interphases for Lithium Garnets Miara, Lincoln J.; Richards, William Davidson; Wang, Yan E. Chemistry of Materials, Vol. 27, Issue 11 https://doi.org/10.1021/acs.chemmater.5b01023	journal	May 2015
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Elucidation of transport mechanism and enhanced alkali ion transference numbers in mixed alkali metal–organic ionic molten salts Chen, Fangfang; Forsyth, Maria Physical Chemistry Chemical Physics, Vol. 18, Issue 28 https://doi.org/10.1039/C6CP01411A	journal	January 2016
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Interphase Engineering Enabled All-Ceramic Lithium Battery Han, Fudong; Yue, Jie; Chen, Cheng Joule, Vol. 2, Issue 3 https://doi.org/10.1016/j.joule.2018.02.007	journal	March 2018
Preparation of Li2S-P2S5 Amorphous Solid Electrolytes by Mechanical Milling Hayashi, Akitoshi; Hama, Shigenori; Morimoto, Hideyuki Journal of the American Ceramic Society, Vol. 84, Issue 2 https://doi.org/10.1111/j.1151-2916.2001.tb00685.x	journal	February 2001
Influence of sputtering conditions on ionic conductivity of LiPON thin films Hamon, Y.; Douard, A.; Sabary, F. Solid State Ionics, Vol. 177, Issue 3-4 https://doi.org/10.1016/j.ssi.2005.10.021	journal	January 2006
Fast, efficient generation of high-quality atomic charges. AM1-BCC model: II. Parameterization and validation Jakalian, Araz; Jack, David B.; Bayly, Christopher I. Journal of Computational Chemistry, Vol. 23, Issue 16 https://doi.org/10.1002/jcc.10128	journal	October 2002
Ultimate Limits to Intercalation Reactions for Lithium Batteries Whittingham, M. Stanley Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr5003003	journal	October 2014
Improving low-temperature performance of spinel LiNi0.5Mn1.5O4 electrode and LiNi0.5Mn1.5O4/Li4Ti5O12 full-cell by coating solid-state electrolyte Li-Al-Ti-P-O Bi, Kun; Zhao, Shi-Xi; Huang, Chao Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.03.071	journal	June 2018
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes Cheng, Xin-Bing; Zhao, Chen-Zi; Yao, Yu-Xing Chem, Vol. 5, Issue 1 https://doi.org/10.1016/j.chempr.2018.12.002	journal	January 2019
Nanostructured high-energy cathode materials for advanced lithium batteries Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo Nature Materials, Vol. 11, Issue 11 https://doi.org/10.1038/nmat3435	journal	October 2012
Addition of a thin-film inorganic solid electrolyte (Lipon) as a protective film in lithium batteries with a liquid electrolyte Dudney, Nancy J. Journal of Power Sources, Vol. 89, Issue 2, p. 176-179 https://doi.org/10.1016/S0378-7753(00)00427-4	journal	August 2000
HEV battery heating using AC currents Stuart, T. A.; Hande, A. Journal of Power Sources, Vol. 129, Issue 2 https://doi.org/10.1016/j.jpowsour.2003.10.014	journal	April 2004
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Fire-extinguishing organic electrolytes for safe batteries Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0033-8	journal	November 2017
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries Assat, Gaurav; Tarascon, Jean-Marie Nature Energy, Vol. 3, Issue 5 https://doi.org/10.1038/s41560-018-0097-0	journal	April 2018
Structure and Li+ dynamics of Sb-doped Li7La3Zr2O12 fast lithium ion conductors Ramakumar, S.; Satyanarayana, L.; Manorama, Sunkara V. Physical Chemistry Chemical Physics, Vol. 15, Issue 27 https://doi.org/10.1039/c3cp50991e	journal	January 2013
The rechargeable revolution: A better battery Van Noorden, Richard Nature, Vol. 507, Issue 7490 https://doi.org/10.1038/507026a	journal	March 2014
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Competitive lithium solvation of linear and cyclic carbonates from quantum chemistry Borodin, Oleg; Olguin, Marco; Ganesh, P. Physical Chemistry Chemical Physics, Vol. 18, Issue 1 https://doi.org/10.1039/C5CP05121E	journal	January 2016
High‐Energy Rechargeable Metallic Lithium Battery at −70 °C Enabled by a Cosolvent Electrolyte Dong, Xiaoli; Lin, Yuxiao; Li, Panlong Angewandte Chemie, Vol. 131, Issue 17 https://doi.org/10.1002/ange.201900266	journal	March 2019
Lithium batteries: To the limits of lithium Evarts, Eric C. Nature, Vol. 526, Issue 7575 https://doi.org/10.1038/526S93a	journal	October 2015
Achieving High Energy Density through Increasing the Output Voltage: A Highly Reversible 5.3 V Battery Chen, Long; Fan, Xiulin; Hu, Enyuan Chem, Vol. 5, Issue 4 https://doi.org/10.1016/j.chempr.2019.02.003	journal	April 2019
Interface Stability in Solid-State Batteries Richards, William D.; Miara, Lincoln J.; Wang, Yan Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04082	journal	December 2015
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
A new approach toward improved low temperature performance of Li-ion battery Zhang, S. S.; Xu, K.; Jow, T. R. Electrochemistry Communications, Vol. 4, Issue 11 https://doi.org/10.1016/S1388-2481(02)00490-3	journal	November 2002
Electrochemical performance and kinetics of Li1+x(Co1/3Ni1/3Mn1/3)1−xO2 cathodes and graphite anodes in low-temperature electrolytes Smart, M. C.; Whitacre, J. F.; Ratnakumar, B. V. Journal of Power Sources, Vol. 168, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.10.106	journal	June 2007
Lithium-ion battery structure that self-heats at low temperatures Wang, Chao-Yang; Zhang, Guangsheng; Ge, Shanhai Nature, Vol. 529, Issue 7587 https://doi.org/10.1038/nature16502	journal	January 2016
Promise and reality of post-lithium-ion batteries with high energy densities Choi, Jang Wook; Aurbach, Doron Nature Reviews Materials, Vol. 1, Issue 4 https://doi.org/10.1038/natrevmats.2016.13	journal	March 2016
Temperature Dependence of the Magnetic Susceptibility of Water Cini, R.; Torrini, M. The Journal of Chemical Physics, Vol. 49, Issue 6 https://doi.org/10.1063/1.1670491	journal	September 1968
Nonflammable Electrolytes for Li-Ion Batteries Based on a Fluorinated Phosphate Xu, Kang; Zhang, Shengshui; Allen, Jan L. Journal of The Electrochemical Society, Vol. 149, Issue 8 https://doi.org/10.1149/1.1490356	journal	January 2002
The nanoscale circuitry of battery electrodes Zhu, Changbao; Usiskin, Robert E.; Yu, Yan Science, Vol. 358, Issue 6369 https://doi.org/10.1126/science.aao2808	journal	December 2017
Fast charging of lithium-ion batteries at all temperatures Yang, Xiao-Guang; Zhang, Guangsheng; Ge, Shanhai Proceedings of the National Academy of Sciences, Vol. 115, Issue 28 https://doi.org/10.1073/pnas.1807115115	journal	June 2018
Li ⁺ Solvation in Pure, Binary, and Ternary Mixtures of Organic Carbonate Electrolytes Skarmoutsos, Ioannis; Ponnuchamy, Veerapandian; Vetere, Valentina The Journal of Physical Chemistry C, Vol. 119, Issue 9 https://doi.org/10.1021/jp511132c	journal	February 2015
VMD: Visual molecular dynamics Humphrey, William; Dalke, Andrew; Schulten, Klaus Journal of Molecular Graphics, Vol. 14, Issue 1 https://doi.org/10.1016/0263-7855(96)00018-5	journal	February 1996
2-Methoxyethyl (methyl) carbonate-based electrolytes for Li-ion batteries Gu, G. Y.; Bouvier, S.; Wu, C. Electrochimica Acta, Vol. 45, Issue 19 https://doi.org/10.1016/S0013-4686(00)00394-7	journal	June 2000
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
Fast, efficient generation of high-quality atomic charges. AM1-BCC model: I. Method Jakalian, Araz; Bush, Bruce L.; Jack, David B. Journal of Computational Chemistry, Vol. 21, Issue 2 https://doi.org/10.1002/(SICI)1096-987X(20000130)21:2<132::AID-JCC5>3.0.CO;2-P	journal	January 2000

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Title: All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents

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