A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries

Wu, Erik A.; Banerjee, Swastika; Tang, Hanmei; Richardson, Peter M.; Doux, Jean-Marie; Qi, Ji; Zhu, Zhuoying; Grenier, Antonin; Li, Yixuan; Zhao, Enyue; Deysher, Grayson; Sebti, Elias; Nguyen, Han; Stephens, Ryan; Verbist, Guy; Chapman, Karena W.; Clément, Raphaële J.; Banerjee, Abhik; Meng, Ying Shirley; Ong, Shyue Ping

doi:10.1038/s41467-021-21488-7

Title: A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries

Journal Article · Tue Feb 23 00:00:00 EST 2021 · Nature Communications

DOI:https://doi.org/10.1038/s41467-021-21488-7· OSTI ID:1783756

Wu, Erik A. ^[1]; Banerjee, Swastika ^[1]; Tang, Hanmei ^[1];

^[2];

^[1]; Qi, Ji ^[1];

^[1]; Grenier, Antonin ^[3]; Li, Yixuan ^[1]; Zhao, Enyue ^[1]; Deysher, Grayson ^[1]; Sebti, Elias ^[2]; Nguyen, Han ^[1]; Stephens, Ryan ^[4]; Verbist, Guy ^[5];

^[3]; Clément, Raphaële J. ^[2]; Banerjee, Abhik ^[6];

^[1];

^[1]

Univ. of California San Diego, La Jolla, CA (United States)
Univ. of California, Santa Barbara, CA (United States)
Stony Brook Univ., NY (United States)
Shell International Exploration & Production Inc., Houston, TX (United States)
Shell Global Solutions International BV, The Hague (Netherlands)
Univ. of California San Diego, La Jolla, CA (United States); TCG Centres for Research and Education in Science and Technology (TCG CREST), Kolkata (India)

Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report the discovery of the ion conductor Na_3-xY_1-xZr_xCl₆ (NYZC) that is both electrochemically stable (up to 3.8 V vs. Na/Na⁺) and chemically compatible with oxide cathodes. Its high ionic conductivity of 6.6 × 10^–5 S cm^–1 at ambient temperature, several orders of magnitude higher than oxide coatings, is attributed to abundant Na vacancies and cooperative MCl₆ rotation, resulting in an extremely low interfacial impedance. A SSSB comprising a NaCrO₂ + NYZC composite cathode, Na₃PS₄ electrolyte, and Na-Sn anode exhibits an exceptional first-cycle Coulombic efficiency of 97.1% at room emperature and can cycle over 1000 cycles with 89.3% capacity retention at 40 °C. These findings highlight the immense potential of halides for SSSB applications.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; ECCS-1542148

OSTI ID:: 1783756

Report Number(s):: BNL-221438-2021-JACI

Journal Information:: Nature Communications, Vol. 12, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (66)

Double-slit photoelectron interference in strong-field ionization of the neon dimer Kunitski, Maksim; Eicke, Nicolas; Huber, Pia Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-07882-8	journal	January 2019
Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives Zhao, Wenjia; Yi, Jin; He, Ping Electrochemical Energy Reviews, Vol. 2, Issue 4 https://doi.org/10.1007/s41918-019-00048-0	journal	August 2019
High-Voltage Superionic Halide Solid Electrolytes for All-Solid-State Li-Ion Batteries Park, Kern-Ho; Kaup, Kavish; Assoud, Abdeljalil ACS Energy Letters, Vol. 5, Issue 2 https://doi.org/10.1021/acsenergylett.9b02599	journal	January 2020
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
High sodium ion conductivity of glass–ceramic electrolytes with cubic Na3PS4 Hayashi, Akitoshi; Noi, Kousuke; Tanibata, Naoto Journal of Power Sources, Vol. 258 https://doi.org/10.1016/j.jpowsour.2014.02.054	journal	July 2014
Superionic Conductors: Li 10+δ [Sn y Si 1– y ] 1+δ P 2−δ S 12 with a Li 10 GeP 2 S 12 -type Structure in the Li 3 PS 4 –Li 4 SnS 4 –Li 4 SiS 4 Quasi-ternary System Sun, Yulong; Suzuki, Kota; Hori, Satoshi Chemistry of Materials, Vol. 29, Issue 14 https://doi.org/10.1021/acs.chemmater.7b00886	journal	July 2017
Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries Li, Xiaona; Liang, Jianwen; Yang, Xiaofei Energy & Environmental Science, Vol. 13, Issue 5 https://doi.org/10.1039/C9EE03828K	journal	January 2020
The inorganic crystal structure data base Bergerhoff, G.; Hundt, R.; Sievers, R. Journal of Chemical Information and Modeling, Vol. 23, Issue 2 https://doi.org/10.1021/ci00038a003	journal	May 1983
Exceptional Superionic Conductivity in Disordered Sodium Decahydro- closo -decaborate Udovic, Terrence J.; Matsuo, Motoaki; Tang, Wan Si Advanced Materials, Vol. 26, Issue 45 https://doi.org/10.1002/adma.201403157	journal	October 2014
Targeting Superionic Conductivity by Turning on Anion Rotation at Room Temperature in Fast Ion Conductors Zhang, Zhizhen; Li, Hui; Kaup, Kavish Matter, Vol. 2, Issue 6 https://doi.org/10.1016/j.matt.2020.04.027	journal	June 2020
A stable 3 V all-solid-state sodium–ion battery based on a closo -borate electrolyte Duchêne, L.; Kühnel, R. -S.; Stilp, E. Energy & Environmental Science, Vol. 10, Issue 12 https://doi.org/10.1039/C7EE02420G	journal	January 2017
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Air-stable Li ₃ InCl ₆ electrolyte with high voltage compatibility for all-solid-state batteries Li, Xiaona; Liang, Jianwen; Luo, Jing Energy & Environmental Science, Vol. 12, Issue 9 https://doi.org/10.1039/C9EE02311A	journal	January 2019
Taming Active Material-Solid Electrolyte Interfaces with Organic Cathode for All-Solid-State Batteries Hao, Fang; Chi, Xiaowei; Liang, Yanliang Joule, Vol. 3, Issue 5 https://doi.org/10.1016/j.joule.2019.03.017	journal	May 2019
Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries Zhang, Dechao; Cao, Xiaoting; Xu, Di Electrochimica Acta, Vol. 259 https://doi.org/10.1016/j.electacta.2017.10.173	journal	January 2018
Na ₃ SbS ₄ : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries Banerjee, Abhik; Park, Kern Ho; Heo, Jongwook W. Angewandte Chemie International Edition, Vol. 55, Issue 33 https://doi.org/10.1002/anie.201604158	journal	July 2016
High temperature NMR approach of mixtures of rare earth and alkali fluorides: An insight into the local structure Bessada, Catherine; Rakhmatullin, Aydar; Rollet, Anne-Laure Journal of Fluorine Chemistry, Vol. 130, Issue 1 https://doi.org/10.1016/j.jfluchem.2008.07.010	journal	January 2009
High-power all-solid-state batteries using sulfide superionic conductors Kato, Yuki; Hori, Satoshi; Saito, Toshiya Nature Energy, Vol. 1, Issue 4 https://doi.org/10.1038/nenergy.2016.30	journal	March 2016
All-solid-state sodium-sulfur battery showing full capacity with activated carbon MSP20-sulfur-Na3SbS4 composite Ando, Taka; Sakuda, Atsushi; Tatsumisago, Masahiro Electrochemistry Communications, Vol. 116 https://doi.org/10.1016/j.elecom.2020.106741	journal	July 2020
Anion Reorientations in the Superionic Conducting Phase of Na ₂ B ₁₂ H ₁₂ Verdal, Nina; Udovic, Terrence J.; Stavila, Vitalie The Journal of Physical Chemistry C, Vol. 118, Issue 31 https://doi.org/10.1021/jp506252c	journal	July 2014
Moment Tensor Potentials: A Class of Systematically Improvable Interatomic Potentials Shapeev, Alexander V. Multiscale Modeling & Simulation, Vol. 14, Issue 3 https://doi.org/10.1137/15M1054183	journal	January 2016
Tern�re Halogenide vom Typ A3MX6. III [1, 2]. Synthese, Strukturen und Ionenleitf�higkeit der Halogenide Na3MX6 (X = Cl, Br) Wickleder, Mathias S.; Meyer, Gerd Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 621, Issue 3 https://doi.org/10.1002/zaac.19956210321	journal	March 1995
Investigating Sodium Storage Mechanisms in Tin Anodes: A Combined Pair Distribution Function Analysis, Density Functional Theory, and Solid-State NMR Approach Stratford, Joshua M.; Mayo, Martin; Allan, Phoebe K. Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b01398	journal	May 2017
Multinuclear Magnetic Resonance Study of Sodium Salts in Water Solutions Makulski, Włodzimierz Magnetochemistry, Vol. 5, Issue 4 https://doi.org/10.3390/magnetochemistry5040068	journal	December 2019
Accelerating high-throughput searches for new alloys with active learning of interatomic potentials Gubaev, Konstantin; Podryabinkin, Evgeny V.; Hart, Gus L. W. Computational Materials Science, Vol. 156 https://doi.org/10.1016/j.commatsci.2018.09.031	journal	January 2019
First principles study on electrochemical and chemical stability of solid electrolyte–electrode interfaces in all-solid-state Li-ion batteries Zhu, Yizhou; He, Xingfeng; Mo, Yifei Journal of Materials Chemistry A, Vol. 4, Issue 9 https://doi.org/10.1039/C5TA08574H	journal	January 2016
Core–Shell Fe _{1– x} S@Na _2.9 PS _3.95 Se _0.05 Nanorods for Room Temperature All-Solid-State Sodium Batteries with High Energy Density Wan, Hongli; Mwizerwa, Jean Pierre; Qi, Xingguo ACS Nano, Vol. 12, Issue 3 https://doi.org/10.1021/acsnano.8b00073	journal	February 2018
New Na-Ion Solid Electrolytes Na ₄₋ _x Sn ₁₋ _x Sb _x S ₄ (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries Heo, Jongwook W.; Banerjee, Abhik; Park, Kern Ho Advanced Energy Materials, Vol. 8, Issue 11 https://doi.org/10.1002/aenm.201702716	journal	January 2018
Algorithms and tools for high-throughput geometry-based analysis of crystalline porous materials Willems, Thomas F.; Rycroft, Chris H.; Kazi, Michaeel Microporous and Mesoporous Materials, Vol. 149, Issue 1 https://doi.org/10.1016/j.micromeso.2011.08.020	journal	February 2012
Vacancy-Driven Na ⁺ Superionic Conduction in New Ca-Doped Na ₃ PS ₄ for All-Solid-State Na-Ion Batteries Moon, Chang Ki; Lee, Hyun-Jae; Park, Kern Ho ACS Energy Letters, Vol. 3, Issue 10 https://doi.org/10.1021/acsenergylett.8b01479	journal	September 2018
Fast parallel algorithms for short-range molecular dynamics Plimpton, S. https://doi.org/10.2172/10176421	report	May 1993
Gradiently Sodiated Alucone as an Interfacial Stabilizing Strategy for Solid‐State Na Metal Batteries Zhang, Shumin; Zhao, Yang; Zhao, Feipeng Advanced Functional Materials, Vol. 30, Issue 22 https://doi.org/10.1002/adfm.202001118	journal	April 2020
Sodium-Storage Behavior of Exfoliated MoS₂ as an Electrode Material for Solid-State Batteries with Na₃PS₄ as the Solid Electrolyte Santhosha, Aggunda L.; Medenbach, Lukas; Palaniselvam, Thangavelu The Journal of Physical Chemistry C, Vol. 124, Issue 19 https://doi.org/10.1021/acs.jpcc.0c00387	journal	April 2020
Nanoscaled Na ₃ PS ₄ Solid Electrolyte for All-Solid-State FeS ₂ /Na Batteries with Ultrahigh Initial Coulombic Efficiency of 95% and Excellent Cyclic Performances Wan, Hongli; Mwizerwa, Jean Pierre; Qi, Xingguo ACS Applied Materials & Interfaces, Vol. 10, Issue 15 https://doi.org/10.1021/acsami.8b01805	journal	December 2017
Trisodium yttrium(III) hexachloride Liao, Wuping; Dronskowski, Richard Acta Crystallographica Section E Structure Reports Online, Vol. 60, Issue 6 https://doi.org/10.1107/S1600536804011043	journal	May 2004
Tailored Organic Electrode Material Compatible with Sulfide Electrolyte for Stable All-Solid-State Sodium Batteries Chi, Xiaowei; Liang, Yanliang; Hao, Fang Angewandte Chemie International Edition, Vol. 57, Issue 10 https://doi.org/10.1002/anie.201712895	journal	February 2018
Compatibility issues between electrodes and electrolytes in solid-state batteries Tian, Yaosen; Shi, Tan; Richards, William D. Energy & Environmental Science, Vol. 10, Issue 5 https://doi.org/10.1039/C7EE00534B	journal	January 2017
High-Performance All-Solid-State Na–S Battery Enabled by Casting–Annealing Technology Fan, Xiulin; Yue, Jie; Han, Fudong ACS Nano, Vol. 12, Issue 4 https://doi.org/10.1021/acsnano.7b08856	journal	March 2018
Influence of Anion Charge on Li Ion Diffusion in a New Solid-State Electrolyte, Li ₃ LaI ₆ Xu, Zhenming; Chen, Xin; Liu, Ke Chemistry of Materials, Vol. 31, Issue 18 https://doi.org/10.1021/acs.chemmater.9b02075	journal	August 2019
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Room-temperature-operating Na solid-state battery with complex hydride as electrolyte Murgia, Fabrizio; Brighi, Matteo; Černý, Radovan Electrochemistry Communications, Vol. 106 https://doi.org/10.1016/j.elecom.2019.106534	journal	September 2019
Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries Asano, Tetsuya; Sakai, Akihiro; Ouchi, Satoru Advanced Materials, Vol. 30, Issue 44 https://doi.org/10.1002/adma.201803075	journal	September 2018
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
The Materials Application Programming Interface (API): A simple, flexible and efficient API for materials data based on REpresentational State Transfer (REST) principles Ong, Shyue Ping; Cholia, Shreyas; Jain, Anubhav Computational Materials Science, Vol. 97 https://doi.org/10.1016/j.commatsci.2014.10.037	journal	February 2015
Development of solid-state electrolytes for sodium-ion battery–A short review Wang, Yumei; Song, Shufeng; Xu, Chaohe Nano Materials Science, Vol. 1, Issue 2 https://doi.org/10.1016/j.nanoms.2019.02.007	journal	June 2019
Li−Fe−P−O ₂ Phase Diagram from First Principles Calculations Ong, Shyue Ping; Wang, Lei; Kang, Byoungwoo Chemistry of Materials, Vol. 20, Issue 5 https://doi.org/10.1021/cm702327g	journal	February 2008
Elucidating Reversible Electrochemical Redox of Li ₆ PS ₅ Cl Solid Electrolyte Tan, Darren H. S.; Wu, Erik A.; Nguyen, Han ACS Energy Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acsenergylett.9b01693	journal	August 2019
Data-Driven First-Principles Methods for the Study and Design of Alkali Superionic Conductors Deng, Zhi; Zhu, Zhuoying; Chu, Iek-Heng Chemistry of Materials, Vol. 29, Issue 1 https://doi.org/10.1021/acs.chemmater.6b02648	journal	September 2016
Structure of NaYF ₄ Upconverting Nanoparticles: A Multinuclear Solid-State NMR and DFT Computational Study Arnold, Alexandre A.; Terskikh, Victor; Li, Qian Ying The Journal of Physical Chemistry C, Vol. 117, Issue 48 https://doi.org/10.1021/jp405813a	journal	November 2013
Site-Occupation-Tuned Superionic Li _x ScCl _{3+ x} Halide Solid Electrolytes for All-Solid-State Batteries Liang, Jianwen; Li, Xiaona; Wang, Shuo Journal of the American Chemical Society, Vol. 142, Issue 15 https://doi.org/10.1021/jacs.0c00134	journal	March 2020
NaCrO ₂ cathode for high-rate sodium-ion batteries Yu, Chan-Yeop; Park, Jae-Sang; Jung, Hun-Gi Energy & Environmental Science, Vol. 8, Issue 7 https://doi.org/10.1039/C5EE00695C	journal	January 2015
High ionic conductivity in lithium lanthanum titanate Inaguma, Yoshiyuki; Liquan, Chen; Itoh, Mitsuru Solid State Communications, Vol. 86, Issue 10, p. 689-693 https://doi.org/10.1016/0038-1098(93)90841-A	journal	June 1993
Improving the ionic conductivity of NASICON through aliovalent cation substitution of Na3Zr2Si2PO12 Jolley, Adam G.; Cohn, Gil; Hitz, Gregory T. Ionics, Vol. 21, Issue 11 https://doi.org/10.1007/s11581-015-1498-8	journal	July 2015
Crystallization of closo-borate electrolytes from solution enabling infiltration into slurry-casted porous electrodes for all-solid-state batteries Duchêne, Léo; Kim, Dong Hyeon; Song, Yong Bae Energy Storage Materials, Vol. 26 https://doi.org/10.1016/j.ensm.2019.11.027	journal	April 2020
High-Performance All-Inorganic Solid-State Sodium–Sulfur Battery Yue, Jie; Han, Fudong; Fan, Xiulin ACS Nano, Vol. 11, Issue 5 https://doi.org/10.1021/acsnano.7b01445	journal	April 2017
Interface Stability in Solid-State Batteries Richards, William D.; Miara, Lincoln J.; Wang, Yan Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04082	journal	December 2015
Lithium Chlorides and Bromides as Promising Solid‐State Chemistries for Fast Ion Conductors with Good Electrochemical Stability Wang, Shuo; Bai, Qiang; Nolan, Adelaide M. Angewandte Chemie International Edition, Vol. 58, Issue 24 https://doi.org/10.1002/anie.201901938	journal	June 2019
Phase stability, electrochemical stability and ionic conductivity of the Li _10±1 MP ₂ X ₁₂ (M = Ge, Si, Sn, Al or P, and X = O, S or Se) family of superionic conductors Ong, Shyue Ping; Mo, Yifei; Richards, William Davidson Energy Environ. Sci., Vol. 6, Issue 1 https://doi.org/10.1039/C2EE23355J	journal	January 2013
Rotational Motion in LiBH ₄ /LiI Solid Solutions Martelli, Pascal; Remhof, Arndt; Borgschulte, Andreas The Journal of Physical Chemistry A, Vol. 115, Issue 21 https://doi.org/10.1021/jp201372b	journal	June 2011
Active learning of linearly parametrized interatomic potentials Podryabinkin, Evgeny V.; Shapeev, Alexander V. Computational Materials Science, Vol. 140 https://doi.org/10.1016/j.commatsci.2017.08.031	journal	December 2017
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav Computational Materials Science, Vol. 68 https://doi.org/10.1016/j.commatsci.2012.10.028	journal	February 2013
Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations Tang, Hanmei; Deng, Zhi; Lin, Zhuonan Chemistry of Materials, Vol. 30, Issue 1 https://doi.org/10.1021/acs.chemmater.7b04096	journal	December 2017
Performance and Cost Assessment of Machine Learning Interatomic Potentials Zuo, Yunxing; Chen, Chi; Li, Xiangguo The Journal of Physical Chemistry A, Vol. 124, Issue 4 https://doi.org/10.1021/acs.jpca.9b08723	journal	October 2019
Motif-Based Design of an Oxysulfide Class of Lithium Superionic Conductors: Toward Improved Stability and Record-High Li-Ion Conductivity Banerjee, Swastika; Zhang, Xiuwen; Wang, Lin-Wang Chemistry of Materials, Vol. 31, Issue 18 https://doi.org/10.1021/acs.chemmater.9b01639	journal	August 2019
A sodium-ion sulfide solid electrolyte with unprecedented conductivity at room temperature Hayashi, A.; Masuzawa, N.; Yubuchi, S. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13178-2	journal	November 2019

Similar Records

Materials design of sodium chloride solid electrolytes Na3MCl6 for all-solid-state sodium-ion batteries

Journal Article · Thu Sep 16 00:00:00 EDT 2021 · Journal of Materials Chemistry. A · OSTI ID:1783756

Park, Dongsu; Kim, Kwangnam; Chun, Gin Hyung; +3 more

Room-Temperature All-solid-state Rechargeable Sodium-ion Batteries with a Cl-doped Na₃PS₄ Superionic Conductor

Journal Article · Tue Sep 20 00:00:00 EDT 2016 · Scientific Reports · OSTI ID:1783756

Chu, Iek-Heng; Kompella, Christopher S.; Nguyen, Han; +5 more

Material Design Strategy for Halide Solid Electrolytes Li₃MX₆ (X = Cl, Br, and I) for All-Solid-State High-Voltage Li-Ion Batteries

Journal Article · Wed May 12 00:00:00 EDT 2021 · Chemistry of Materials · OSTI ID:1783756

Kim, Kwangnam; Park, Dongsu; Jung, Hun-Gi; +4 more

Related Subjects

99 GENERAL AND MISCELLANEOUS
Batteries
Engineering

CSD 2057627: Experimental Crystal Structure Determination A., Wu, Erik; Swastika, Banerjee,; Hanmei, Tang, https://doi.org/10.25505/fiz.icsd.cc27242k The current record is supplemented by this dataset	dataset	January 2021
CSD 2057626: Experimental Crystal Structure Determination A., Wu, Erik; Swastika, Banerjee,; Hanmei, Tang, https://doi.org/10.25505/fiz.icsd.cc27241j The current record is supplemented by this dataset	dataset	January 2021

Title: A stable cathode-solid electrolyte composite for high-voltage, long-cycle-life solid-state sodium-ion batteries

Citation Formats

References (66)

Linked Research (2)

Similar Records

Related Subjects