Friction stir gradient alloying: A high-throughput method to explore the influence of V in enabling HCP to BCC transformation in a γ-FCC dominated high entropy alloy

Agrawal, Priyanka; Shukla, Shivakant; Gupta, Sanya; Agrawal, Priyanshi; Mishra, Rajiv S.

doi:10.1016/j.apmt.2020.100853

Title: Friction stir gradient alloying: A high-throughput method to explore the influence of V in enabling HCP to BCC transformation in a γ-FCC dominated high entropy alloy

Journal Article · Tue Oct 13 00:00:00 EDT 2020 · Applied Materials Today

DOI:https://doi.org/10.1016/j.apmt.2020.100853· OSTI ID:1779117

Agrawal, Priyanka ^[1];

^[2]; Gupta, Sanya ^[3]; Agrawal, Priyanshi ^[1]; Mishra, Rajiv S. ^[1]

Univ. of North Texas, Denton, TX (United States). Center for Friction Stir Processing; Univ. of North Texas, Denton, TX (United States). Advanced Materials and Manufacturing Processes Inst.
Univ. of North Texas, Denton, TX (United States). Center for Friction Stir Processing; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of North Texas, Denton, TX (United States). Center for Friction Stir Processing

The compositional possibilities in high entropy alloys (HEAs) is very vast and effective strategies are needed to establish potential alloy chemistries. In this study, friction stir gradient alloying (FSGA), a recently-introduced high-throughput (HT) technique incorporating compositional and microstructural gradients, was used to explore the possibility of introducing a bcc transformation domain in γ-fcc dominated TRIP HEA Fe_38.5Mn₂₀Cr₁₅Co₂₀Si₅Cu_1.5 (at.%) by vanadium addition. FSGA has accelerated the process of attaining the composition-microstructure library and the results suggest that vanadium addition of ~1 at.% results in nucleation of α-bcc. Additionally, this is the first observation of ε-hcp to α-bcc transformation in a TRIP HEA and supports the Olson-Cohen model of martensitic transformation (γ-fcc → ε-hcp → α-bcc). ε-hcp is nucleated with a pyramidal orientation by the formation of planar faults on the {111} close-packed planes of γ-fcc, and α-bcc is nucleated in the vicinity of ε-hcp along the {111} γ-fcc trace. There are indications for the formation of basal orientated ε-hcp from intersecting ε-hcp planes orientated for the pyramidal slip. Thus, the study shows the nucleation and growth of the α-bcc phase attributed to the dual effects of chemistry and strain and potential co-existence of all the three phases.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1779117

Journal Information:: Applied Materials Today, Vol. 21, Issue 21; ISSN 2352-9407

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (43)

Criterion for Sigma Phase Formation in Cr- and V-Containing High-Entropy Alloys Tsai, Ming-Hung; Tsai, Kun-Yo; Tsai, Che-Wei Materials Research Letters, Vol. 1, Issue 4 https://doi.org/10.1080/21663831.2013.831382	journal	August 2013
Reversed strength-ductility relationship in microstructurally flexible high entropy alloy Nene, S. S.; Frank, M.; Liu, K. Scripta Materialia, Vol. 154 https://doi.org/10.1016/j.scriptamat.2018.05.043	journal	September 2018
Towards heterogeneous AlxCoCrFeNi high entropy alloy via friction stir processing Wang, Tianhao; Shukla, Shivakant; Komarasamy, Mageshwari Materials Letters, Vol. 236 https://doi.org/10.1016/j.matlet.2018.10.161	journal	February 2019
Effects of Mn, Ti and V on the microstructure and properties of AlCrFeCoNiCu high entropy alloy Li, B. S.; Wang, Y. P.; Ren, M. X. Materials Science and Engineering: A, Vol. 498, Issue 1-2 https://doi.org/10.1016/j.msea.2008.08.025	journal	December 2008
The martensite transformation in stainless steel Venables, J. A. The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, Vol. 7, Issue 73 https://doi.org/10.1080/14786436208201856	journal	January 1962
Extremely high fatigue resistance in an ultrafine grained high entropy alloy Liu, K.; Nene, S. S.; Frank, M. Applied Materials Today, Vol. 15 https://doi.org/10.1016/j.apmt.2019.04.001	journal	June 2019
Microstructural development in equiatomic multicomponent alloys Cantor, B.; Chang, I. T. H.; Knight, P. Materials Science and Engineering: A, Vol. 375-377 https://doi.org/10.1016/j.msea.2003.10.257	journal	July 2004
�ber den Mechanismus der Stahlh�rtung Kurdjumow, G.; Sachs, G. Zeitschrift f�r Physik, Vol. 64, Issue 5-6 https://doi.org/10.1007/BF01397346	journal	May 1930
On the stress dependence of partial dislocation separation and deformation microstructure in austenitic stainless steels Byun, T. S. Acta Materialia, Vol. 51, Issue 11 https://doi.org/10.1016/S1359-6454(03)00117-4	journal	June 2003
Design of a twinning-induced plasticity high entropy alloy Deng, Y.; Tasan, C. C.; Pradeep, K. G. Acta Materialia, Vol. 94 https://doi.org/10.1016/j.actamat.2015.04.014	journal	August 2015
High ductility and transformation-induced-plasticity in metastable stainless steel processed by selective laser melting with low power Polatidis, E.; Čapek, J.; Arabi-Hashemi, A. Scripta Materialia, Vol. 176 https://doi.org/10.1016/j.scriptamat.2019.09.035	journal	February 2020
Excellent high cyclic fatigue properties of a novel ultrafine-grained medium entropy alloy Shukla, Shivakant; Mishra, Rajiv S. Materials Science and Engineering: A, Vol. 779 https://doi.org/10.1016/j.msea.2020.139122	journal	March 2020
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes Yeh, J.-W.; Chen, S.-K.; Lin, S.-J. Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303 https://doi.org/10.1002/adem.200300567	journal	May 2004
Unexpected strength–ductility response in an annealed, metastable, high-entropy alloy Nene, S. S.; Sinha, S.; Frank, M. Applied Materials Today, Vol. 13 https://doi.org/10.1016/j.apmt.2018.09.002	journal	December 2018
Hierarchical microstructure for improved fatigue properties in a eutectic high entropy alloy Shukla, Shivakant; Wang, Tianhao; Cotton, Shomari Scripta Materialia, Vol. 156 https://doi.org/10.1016/j.scriptamat.2018.07.022	journal	November 2018
A critical review of high entropy alloys and related concepts Miracle, D. B.; Senkov, O. N. Acta Materialia, Vol. 122 https://doi.org/10.1016/j.actamat.2016.08.081	journal	January 2017
Friction stir welding and processing Mishra, R. S.; Ma, Z. Y. Materials Science and Engineering: R: Reports, Vol. 50, Issue 1-2 https://doi.org/10.1016/j.mser.2005.07.001	journal	August 2005
Revealing Extraordinary Intrinsic Tensile Plasticity in Gradient Nano-Grained Copper Fang, T. H.; Li, W. L.; Tao, N. R. Science, Vol. 331, Issue 6024 https://doi.org/10.1126/science.1200177	journal	February 2011
Immiscible nanostructured copper-aluminum-niobium alloy with excellent precipitation strengthening upon friction stir processing and aging Sinha, Subhasis; Komarasamy, Mageshwari; Thapliyal, Saket Scripta Materialia, Vol. 164 https://doi.org/10.1016/j.scriptamat.2019.01.038	journal	April 2019
Theory of designing the gradient microstructured metals for overcoming strength-ductility trade-off Fan, Jitang; Zhu, Linli; Lu, Jian Scripta Materialia, Vol. 184 https://doi.org/10.1016/j.scriptamat.2020.03.045	journal	July 2020
A crystallographic extension to the Olson-Cohen model for predicting strain path dependence of martensitic transformation Zecevic, Milovan; Upadhyay, Manas V.; Polatidis, Efthymios Acta Materialia, Vol. 166 https://doi.org/10.1016/j.actamat.2018.12.060	journal	March 2019
A mechanism for the strain-induced nucleation of martensitic transformations Olson, G. B.; Cohen, Morris Journal of the Less Common Metals, Vol. 28, Issue 1 https://doi.org/10.1016/0022-5088(72)90173-7	journal	July 1972
Corrosion-resistant high entropy alloy with high strength and ductility Nene, S. S.; Frank, M.; Liu, K. Scripta Materialia, Vol. 166 https://doi.org/10.1016/j.scriptamat.2019.03.028	journal	June 2019
High-entropy alloys George, Easo P.; Raabe, Dierk; Ritchie, Robert O. Nature Reviews Materials, Vol. 4, Issue 8 https://doi.org/10.1038/s41578-019-0121-4	journal	June 2019
Suppressed martensitic transformation under biaxial loading in low stacking fault energy metastable austenitic steels Polatidis, E.; Hsu, W. -N.; Šmíd, M. Scripta Materialia, Vol. 147 https://doi.org/10.1016/j.scriptamat.2017.12.026	journal	April 2018
Improvement of Microstructure and Mechanical Properties of CoCrCuFeNi High-Entropy Alloys By V Addition Qin, Gang; Wang, Shu; Chen, Ruirun Journal of Materials Engineering and Performance, Vol. 28, Issue 2 https://doi.org/10.1007/s11665-018-3837-1	journal	January 2019
Enhanced strength and ductility in a friction stir processing engineered dual phase high entropy alloy Nene, S. S.; Liu, K.; Frank, M. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-16509-9	journal	November 2017
Strong and Ductile Non-equiatomic High-Entropy Alloys: Design, Processing, Microstructure, and Mechanical Properties Li, Zhiming; Raabe, Dierk JOM, Vol. 69, Issue 11 https://doi.org/10.1007/s11837-017-2540-2	journal	August 2017
Making strong nanomaterials ductile with gradients Lu, K. Science, Vol. 345, Issue 6203 https://doi.org/10.1126/science.1255940	journal	September 2014
Microstructurally flexible high entropy alloys: Linkages between alloy design and deformation behavior Nene, S. S.; Frank, M.; Agrawal, P. Materials & Design, Vol. 194 https://doi.org/10.1016/j.matdes.2020.108968	journal	September 2020
Partial dislocations on the {110} planes in the B.C.C. lattice and the transition of the F.C.C. into the B.C.C. lattice Bogers, A. J.; Burgers, W. G. Acta Metallurgica, Vol. 12, Issue 2 https://doi.org/10.1016/0001-6160(64)90194-4	journal	February 1964
Investigating the deformation mechanisms of a highly metastable high entropy alloy using in-situ neutron diffraction Frank, M.; Chen, Y.; Nene, S. S. Materials Today Communications, Vol. 23 https://doi.org/10.1016/j.mtcomm.2019.100858	journal	June 2020
Physical Vapor Deposition Method for the High-Throughput Synthesis of Solid-State Material Libraries Guerin, Samuel; Hayden, Brian E. Journal of Combinatorial Chemistry, Vol. 8, Issue 1 https://doi.org/10.1021/cc050117p	journal	January 2006
Formation of simple crystal structures in Cu-Co-Ni-Cr-Al-Fe-Ti-V alloys with multiprincipal metallic elements Yeh, Jien-Wei; Lin, Su-Jien; Chin, Tsung-Shune Metallurgical and Materials Transactions A, Vol. 35, Issue 8 https://doi.org/10.1007/s11661-006-0234-4	journal	August 2004
Effect of vanadium addition on the microstructure and properties of AlCoCrFeNi high entropy alloy Dong, Yong; Zhou, Kaiyao; Lu, Yiping Materials & Design, Vol. 57 https://doi.org/10.1016/j.matdes.2013.12.048	journal	May 2014
Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range Lu, Yiping; Gao, Xuzhou; Jiang, Li Acta Materialia, Vol. 124 https://doi.org/10.1016/j.actamat.2016.11.016	journal	February 2017
High-throughput screening of laser additive manufactured metallic glass via ultrasonic wave Zhai, Linlin; Lu, Yunzhuo; Zhao, Xinyu Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-54293-w	journal	November 2019
Lattice strain framework for plastic deformation in complex concentrated alloys including high entropy alloys Mishra, R. S.; Kumar, N.; Komarasamy, M. Materials Science and Technology, Vol. 31, Issue 10 https://doi.org/10.1179/1743284715Y.0000000050	journal	March 2015
Effect of vanadium addition on the microstructure, hardness, and wear resistance of Al0.5CoCrCuFeNi high-entropy alloy Chen, Min-Rui; Lin, Su-Jien; Yeh, Jien-Wei Metallurgical and Materials Transactions A, Vol. 37, Issue 5 https://doi.org/10.1007/s11661-006-0081-3	journal	May 2006
The martensite transformation in 18% Cr-8% Ni steels Lagneborgj, R. Acta Metallurgica, Vol. 12, Issue 7 https://doi.org/10.1016/0001-6160(64)90176-2	journal	July 1964
A general mechanism of martensitic nucleation: Part III. Kinetics of martensitic nucleation Olson, G. B.; Cohen, Morris Metallurgical Transactions A, Vol. 7, Issue 11 https://doi.org/10.1007/BF02654989	journal	November 1976
Towards V-based high-entropy alloys for nuclear fusion applications Barron, P. J.; Carruthers, A. W.; Fellowes, J. W. Scripta Materialia, Vol. 176 https://doi.org/10.1016/j.scriptamat.2019.09.028	journal	February 2020
Vanadium is an optimal element for strengthening in both fcc and bcc high-entropy alloys Yin, Binglun; Maresca, Francesco; Curtin, W. A. Acta Materialia, Vol. 188 https://doi.org/10.1016/j.actamat.2020.01.062	journal	April 2020

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Title: Friction stir gradient alloying: A high-throughput method to explore the influence of V in enabling HCP to BCC transformation in a γ-FCC dominated high entropy alloy

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