Isomer of linker for NU-1000 yields a new she-type, catalytic, and hierarchically porous, Zr-based metal–organic framework

Lu, Zhiyong; Wang, Rui; Liao, Yijun; Farha, Omar K.; Bi, Wentuan; Sheridan, Thomas R.; Zhang, Kun; Duan, Jiaxin; Liu, Jian; Hupp, Joseph T.

doi:10.1039/d0cc07974j

Title: Isomer of linker for NU-1000 yields a new she-type, catalytic, and hierarchically porous, Zr-based metal–organic framework

Journal Article · Mon Feb 22 00:00:00 EST 2021 · ChemComm

DOI:https://doi.org/10.1039/d0cc07974j· OSTI ID:1778900

^[1]; Wang, Rui ^[2];

^[2];

^[2]; Bi, Wentuan ^[3]; Sheridan, Thomas R. ^[2]; Zhang, Kun ^[4]; Duan, Jiaxin ^[2];

^[2]; Hupp, Joseph T. ^[2]

Hohai Univ., Nanjing (China); Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Univ. of Science and Technology of China, Hefei (China)
Northwestern Univ., Evanston, IL (United States); Nanjing Univ. of Science & Technology, Nanjing (China)

The well-known MOF (metal–organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy^4–) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy^4– to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous, she-type MOF Zr₆(μ₃-O)4(μ₃-OH)₄(C₆H₅COO)₃(COO)₃(TBAPy-2)_3/2 (NU-601), where TBAPy-2^4– is the 4,5,9,10 isomer of TBAPy^4–. In conclusion, NU-601 shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.

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Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Defense Threat Reduction Agency (DTRA)

Grant/Contract Number:: SC0012702; HDTRA1-18-1-0003

OSTI ID:: 1778900

Alternate ID(s):: OSTI ID: 1770493

Journal Information:: ChemComm, Vol. 57, Issue 29; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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