The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals

Smock, Sara R.; Chen, Yunhua; Rossini, Aaron J.; Brutchey, Richard L.

doi:10.1021/acs.accounts.0c00741

Title: The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals

Journal Article · Fri Jan 15 00:00:00 EST 2021 · Accounts of Chemical Research

DOI:https://doi.org/10.1021/acs.accounts.0c00741· OSTI ID:1765699

Smock, Sara R. ^[1]; Chen, Yunhua ^[2];

^[2];

^[1]

Univ. of Southern California, Los Angeles, CA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

Since the initial discovery of colloidal lead halide perovskite nanocrystals, there has been significant interest placed on these semiconductors because of their remarkable optoelectronic properties, including very high photoluminescence quantum yields, narrow size- and composition-tunable emission over a wide color gamut, defect tolerance, and suppressed blinking. These material attributes have made them attractive components for next-generation solar cells, light emitting diodes, low-threshold lasers, single photon emitters, and X-ray scintillators. While a great deal of research has gone into the various applications of colloidal lead halide perovskite nanocrystals, comparatively little work has focused on the fundamental surface chemistry of these materials. While the surface chemistry of colloidal semiconductor nanocrystals is generally affected by their particle morphology, surface stoichiometry, and organic ligands that contribute to the first coordination sphere of their surface atoms, these attributes are markedly different in lead halide perovskite nanocrystals because of their ionicity. Herein, emerging work on the surface chemistry of lead halide perovskite nanocrystals is highlighted, with a particular focus placed on the most-studied composition of CsPbBr₃. We begin with an in-depth exploration of the native surface chemistry of as-prepared, 0-D cuboidal CsPbBr₃ nanocrystals, including an atomistic description of their surface termini, vacancies, and ionic bonding with ligands. We then proceed to discuss various post-synthetic surface treatments that have been developed to increase the photoluminescence quantum yields and stability of CsPbBr₃ nanocrystals, including the use of tetraalkylammonium bromides, metal bromides, zwitterions, and phosphonic acids, and how these various ligands are known to bind to the nanocrystal surface. To underscore the effect of post-synthetic surface treatments on the application of these materials, we focus on lead halide perovskite nanocrystal-based light emitting diodes, and the positive effect of various surface treatments on external quantum efficiencies. We also discuss the current state-of-the-art in the surface chemistry of 1-D nanowires and 2-D nanoplatelets of CsPbBr₃, which are more quantum confined than the corresponding cuboidal nanocrystals but also generally possess a higher defect density because of their increased surface area-to-volume ratios.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; Alfred P. Sloan Foundation

Grant/Contract Number:: FG02-11ER46826; SC0006812

OSTI ID:: 1765699

Report Number(s):: IS-J-10,410

Journal Information:: Accounts of Chemical Research, Vol. 54, Issue 3; ISSN 0001-4842

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (86)

Chalcogenol Ligand Toolbox for CdSe Nanocrystals and Their Influence on Exciton Relaxation Pathways Buckley, Jannise J.; Couderc, Elsa; Greaney, Matthew J. ACS Nano, Vol. 8, Issue 3 https://doi.org/10.1021/nn406109v	journal	February 2014
Relaxation of Exciton Confinement in CdSe Quantum Dots by Modification with a Conjugated Dithiocarbamate Ligand Frederick, Matthew T.; Weiss, Emily A. ACS Nano, Vol. 4, Issue 6 https://doi.org/10.1021/nn1007435	journal	May 2010
Quantifying the Thermodynamics of Ligand Binding to CsPbBr ₃ Quantum Dots Smock, Sara R.; Williams, Travis J.; Brutchey, Richard L. Angewandte Chemie International Edition, Vol. 57, Issue 36 https://doi.org/10.1002/anie.201806916	journal	August 2018
Bipolar-shell resurfacing for blue LEDs based on strongly confined perovskite quantum dots Dong, Yitong; Wang, Ya-Kun; Yuan, Fanglong Nature Nanotechnology, Vol. 15, Issue 8 https://doi.org/10.1038/s41565-020-0714-5	journal	July 2020
Bandgap Control via Structural and Chemical Tuning of Transition Metal Perovskite Chalcogenides Niu, Shanyuan; Huyan, Huaixun; Liu, Yang Advanced Materials, Vol. 29, Issue 9 https://doi.org/10.1002/adma.201604733	journal	December 2016
Nontemplate Synthesis of CH ₃ NH ₃ PbBr ₃ Perovskite Nanoparticles Schmidt, Luciana C.; Pertegás, Antonio; González-Carrero, Soranyel Journal of the American Chemical Society, Vol. 136, Issue 3 https://doi.org/10.1021/ja4109209	journal	January 2014
Identifying and Reducing Interfacial Losses to Enhance Color-Pure Electroluminescence in Blue-Emitting Perovskite Nanoplatelet Light-Emitting Diodes Hoye, Robert L. Z.; Lai, May-Ling; Anaya, Miguel ACS Energy Letters, Vol. 4, Issue 5 https://doi.org/10.1021/acsenergylett.9b00571	journal	April 2019
Rashba Effect in a Single Colloidal CsPbBr ₃ Perovskite Nanocrystal Detected by Magneto-Optical Measurements Isarov, Maya; Tan, Liang Z.; Bodnarchuk, Maryna I. Nano Letters, Vol. 17, Issue 8 https://doi.org/10.1021/acs.nanolett.7b02248	journal	July 2017
Light Generation in Lead Halide Perovskite Nanocrystals: LEDs, Color Converters, Lasers, and Other Applications Yan, Fei; Tan, Swee Tiam; Li, Xiao Small, Vol. 15, Issue 47 https://doi.org/10.1002/smll.201902079	journal	October 2019
Phosphonic Acid Stabilized Colloidal CsPbX ₃ (X=Br, I) Perovskite Nanocrystals and Their Surface Chemistry Koh, Weon-kyu; Park, Sungjun; Ham, Yongnam ChemistrySelect, Vol. 1, Issue 13 https://doi.org/10.1002/slct.201600809	journal	August 2016
Über die Cäsium- und Kalium-Bleihalogenide Wells, H. L. Zeitschrift für anorganische Chemie, Vol. 3, Issue 1 https://doi.org/10.1002/zaac.18930030124	journal	January 1893
Lead Halide Perovskite Nanocrystals in the Research Spotlight: Stability and Defect Tolerance Huang, He; Bodnarchuk, Maryna I.; Kershaw, Stephen V. ACS Energy Letters, Vol. 2, Issue 9 https://doi.org/10.1021/acsenergylett.7b00547	journal	August 2017
Organic Surfactant-Controlled Composition of the Surfaces of CdSe Quantum Dots Morris-Cohen, Adam J.; Frederick, Matthew T.; Lilly, G. Daniel The Journal of Physical Chemistry Letters, Vol. 1, Issue 7 https://doi.org/10.1021/jz100224q	journal	March 2010
Bright Light-Emitting Diodes Based on Organometal Halide Perovskite Nanoplatelets Ling, Yichuan; Yuan, Zhao; Tian, Yu Advanced Materials, Vol. 28, Issue 2 https://doi.org/10.1002/adma.201503954	journal	November 2015
Self-Assembly of CdSe Nanoplatelets into Stacks of Controlled Size Induced by Ligand Exchange Antanovich, Artsiom; Prudnikau, Anatol; Matsukovich, Anna The Journal of Physical Chemistry C, Vol. 120, Issue 10 https://doi.org/10.1021/acs.jpcc.5b12139	journal	January 2016
Colloidal Nanocrystals with Molecular Metal Chalcogenide Surface Ligands Kovalenko, M. V.; Scheele, M.; Talapin, D. V. Science, Vol. 324, Issue 5933 https://doi.org/10.1126/science.1170524	journal	June 2009
Interfacial Modification of Perovskite Solar Cells Using an Ultrathin MAI Layer Leads to Enhanced Energy Level Alignment, Efficiencies, and Reproducibility Hawash, Zafer; Raga, Sonia R.; Son, Dae-Yong The Journal of Physical Chemistry Letters, Vol. 8, Issue 17 https://doi.org/10.1021/acs.jpclett.7b01508	journal	August 2017
Simultaneous Cationic and Anionic Ligand Exchange For Colloidally Stable CsPbBr ₃ Nanocrystals Imran, Muhammad; Ijaz, Palvasha; Goldoni, Luca ACS Energy Letters, Vol. 4, Issue 4 https://doi.org/10.1021/acsenergylett.9b00140	journal	March 2019
Crystal Growth of the Perovskite Semiconductor CsPbBr ₃ : A New Material for High-Energy Radiation Detection Stoumpos, Constantinos C.; Malliakas, Christos D.; Peters, John A. Crystal Growth & Design, Vol. 13, Issue 7 https://doi.org/10.1021/cg400645t	journal	June 2013
Surface coordination chemistry of germanium nanocrystals synthesized by microwave-assisted reduction in oleylamine Smock, Sara R.; Tabatabaei, Katayoon; Williams, Travis J. Nanoscale, Vol. 12, Issue 4 https://doi.org/10.1039/C9NR09233A	journal	January 2020
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Highly Efficient Perovskite-Quantum-Dot Light-Emitting Diodes by Surface Engineering Pan, Jun; Quan, Li Na; Zhao, Yongbiao Advanced Materials, Vol. 28, Issue 39 https://doi.org/10.1002/adma.201600784	journal	August 2016
Room-temperature and gram-scale synthesis of CsPbX ₃ (X = Cl, Br, I) perovskite nanocrystals with 50–85% photoluminescence quantum yields Wei, Song; Yang, Yanchun; Kang, Xiaojiao Chemical Communications, Vol. 52, Issue 45 https://doi.org/10.1039/C6CC01500J	journal	January 2016
Bright-Emitting Perovskite Films by Large-Scale Synthesis and Photoinduced Solid-State Transformation of CsPbBr ₃ Nanoplatelets Shamsi, Javad; Rastogi, Prachi; Caligiuri, Vincenzo ACS Nano, Vol. 11, Issue 10 https://doi.org/10.1021/acsnano.7b04761	journal	September 2017
Colloidal CsPbX ₃ (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00035	journal	February 2018
Coherent Nanotwins and Dynamic Disorder in Cesium Lead Halide Perovskite Nanocrystals Bertolotti, Federica; Protesescu, Loredana; Kovalenko, Maksym V. ACS Nano, Vol. 11, Issue 4 https://doi.org/10.1021/acsnano.7b00017	journal	April 2017
Light-Induced Self-Assembly of Cubic CsPbBr ₃ Perovskite Nanocrystals into Nanowires Liu, Jiakai; Song, Kepeng; Shin, Yongwoo Chemistry of Materials, Vol. 31, Issue 17 https://doi.org/10.1021/acs.chemmater.9b00680	journal	December 2018
When Ligand Exchange Leads to Ion Exchange: Nanocrystal Facets Dictate the Outcome Hewavitharana, Indika K.; Brock, Stephanie L. ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b05534	journal	November 2017
2D Behaviors of Excitons in Cesium Lead Halide Perovskite Nanoplatelets Li, Jing; Luo, Laihao; Huang, Hongwen The Journal of Physical Chemistry Letters, Vol. 8, Issue 6 https://doi.org/10.1021/acs.jpclett.7b00017	journal	February 2017
Stable Ultraconcentrated and Ultradilute Colloids of CsPbX ₃ (X = Cl, Br) Nanocrystals Using Natural Lecithin as a Capping Ligand Krieg, Franziska; Ong, Quy K.; Burian, Max Journal of the American Chemical Society, Vol. 141, Issue 50 https://doi.org/10.1021/jacs.9b09969	journal	November 2019
Trapping and Detrapping in Colloidal Perovskite Nanoplatelets: Elucidation and Prevention of Nonradiative Processes through Chemical Treatment Vonk, Sander J. W.; Fridriksson, Magnus B.; Hinterding, Stijn O. M. The Journal of Physical Chemistry C, Vol. 124, Issue 14 https://doi.org/10.1021/acs.jpcc.0c02287	journal	March 2020
Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals De Roo, Jonathan; Ibáñez, Maria; Geiregat, Pieter ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b06295	journal	January 2016
What Defines a Perovskite? Breternitz, Joachim; Schorr, Susan Advanced Energy Materials, Vol. 8, Issue 34 https://doi.org/10.1002/aenm.201802366	journal	October 2018
Der Chelateffekt Schwarzenbach, G. Helvetica Chimica Acta, Vol. 35, Issue 7 https://doi.org/10.1002/hlca.19520350721	journal	December 1952
Ligand Exchange on Colloidal CdSe Nanocrystals Using Thermally Labile tert -Butylthiol for Improved Photocurrent in Nanocrystal Films Webber, David H.; Brutchey, Richard L. Journal of the American Chemical Society, Vol. 134, Issue 2 https://doi.org/10.1021/ja208878h	journal	December 2011
Atomic-level passivation mechanism of ammonium salts enabling highly efficient perovskite solar cells Alharbi, Essa A.; Alyamani, Ahmed Y.; Kubicki, Dominik J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10985-5	journal	July 2019
Compositionally Dependent Phase Identity of Colloidal CsPbBr _{3– x} I _x Quantum Dots Cottingham, Patrick; Brutchey, Richard L. Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03553	journal	October 2016
Surface Termination of CsPbBr ₃ Perovskite Quantum Dots Determined by Solid-State NMR Spectroscopy Chen, Yunhua; Smock, Sara R.; Flintgruber, Anne H. Journal of the American Chemical Society, Vol. 142, Issue 13 https://doi.org/10.1021/jacs.9b13396	journal	March 2020
Structure of Colloidal Quantum Dots from Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy Piveteau, Laura; Ong, Ta-Chung; Rossini, Aaron J. Journal of the American Chemical Society, Vol. 137, Issue 43 https://doi.org/10.1021/jacs.5b09248	journal	October 2015
Role of Capped Oleyl Amine in the Moisture‐Induced Structural Transformation of CsPbBr ₃ Perovskite Nanocrystals Sandeep, K.; Gopika, K. Y.; Revathi, M. R. physica status solidi (RRL) – Rapid Research Letters, Vol. 13, Issue 11 https://doi.org/10.1002/pssr.201900387	journal	May 2019
Crystal Structure of Individual CsPbBr ₃ Perovskite Nanocubes Brennan, Michael C.; Kuno, Masaru; Rouvimov, Sergei Inorganic Chemistry, Vol. 58, Issue 2 https://doi.org/10.1021/acs.inorgchem.8b03078	journal	December 2018
Stable Hexylphosphonate-Capped Blue-Emitting Quantum-Confined CsPbBr ₃ Nanoplatelets Shamsi, Javad; Kubicki, Dominik; Anaya, Miguel ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00935	journal	May 2020
Direct optical lithography of functional inorganic nanomaterials Wang, Yuanyuan; Fedin, Igor; Zhang, Hao Science, Vol. 357, Issue 6349 https://doi.org/10.1126/science.aan2958	journal	July 2017
Targeted Ligand-Exchange Chemistry on Cesium Lead Halide Perovskite Quantum Dots for High-Efficiency Photovoltaics Wheeler, Lance M.; Sanehira, Erin M.; Marshall, Ashley R. Journal of the American Chemical Society, Vol. 140, Issue 33 https://doi.org/10.1021/jacs.8b04984	journal	July 2018
Photon Driven Transformation of Cesium Lead Halide Perovskites from Few-Monolayer Nanoplatelets to Bulk Phase Wang, Yue; Li, Xiaoming; Sreejith, Sivaramapanicker Advanced Materials, Vol. 28, Issue 48 https://doi.org/10.1002/adma.201604110	journal	October 2016
The Effects of Chemisorption on the Luminescence of CdSe Quantum Dots Bullen, C.; Mulvaney, P. Langmuir, Vol. 22, Issue 7 https://doi.org/10.1021/la051898e	journal	March 2006
On the crystal structure of colloidally prepared CsPbBr ₃ quantum dots Cottingham, Patrick; Brutchey, Richard L. Chemical Communications, Vol. 52, Issue 30 https://doi.org/10.1039/C6CC01088A	journal	January 2016
All-Inorganic Germanium Nanocrystal Films by Cationic Ligand Exchange Wheeler, Lance M.; Nichols, Asa W.; Chernomordik, Boris D. Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b05192	journal	January 2016
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017
Surface Ligand Management Aided by a Secondary Amine Enables Increased Synthesis Yield of CsPbI ₃ Perovskite Quantum Dots and High Photovoltaic Performance Wang, Yao; Yuan, Jianyu; Zhang, Xuliang Advanced Materials, Vol. 32, Issue 32 https://doi.org/10.1002/adma.202000449	journal	July 2020
Facet-Specific Ligand Interactions on Ternary AgSbS ₂ Colloidal Quantum Dots Choi, Hyekyoung; Kim, Sungwoo; Luther, Joseph M. Chemistry - A European Journal, Vol. 23, Issue 70 https://doi.org/10.1002/chem.201703681	journal	November 2017
Origin of the Substitution Mechanism for the Binding of Organic Ligands on the Surface of CsPbBr ₃ Perovskite Nanocubes Ravi, Vikash Kumar; Santra, Pralay K.; Joshi, Niharika The Journal of Physical Chemistry Letters, Vol. 8, Issue 20 https://doi.org/10.1021/acs.jpclett.7b02192	journal	September 2017
Sensitivity-Enhanced ²⁰⁷ Pb Solid-State NMR Spectroscopy for the Rapid, Non-Destructive Characterization of Organolead Halide Perovskites Hanrahan, Michael P.; Men, Long; Rosales, Bryan A. Chemistry of Materials, Vol. 30, Issue 20 https://doi.org/10.1021/acs.chemmater.8b01899	journal	September 2018
Insight into the Ligand-Mediated Synthesis of Colloidal CsPbBr ₃ Perovskite Nanocrystals: The Role of Organic Acid, Base, and Cesium Precursors Pan, Aizhao; He, Bo; Fan, Xiaoyun ACS Nano, Vol. 10, Issue 8 https://doi.org/10.1021/acsnano.6b03863	journal	July 2016
Rationalizing and Controlling the Surface Structure and Electronic Passivation of Cesium Lead Halide Nanocrystals Bodnarchuk, Maryna I.; Boehme, Simon C.; ten Brinck, Stephanie ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b01669	journal	November 2018
Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX ₃ ) Song, Jizhong; Li, Jianhai; Li, Xiaoming Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201502567	journal	October 2015
Highly Luminescent and Stable Perovskite Nanocrystals with Octylphosphonic Acid as a Ligand for Efficient Light-Emitting Diodes Tan, Yeshu; Zou, Yatao; Wu, Linzhong ACS Applied Materials & Interfaces, Vol. 10, Issue 4 https://doi.org/10.1021/acsami.7b17166	journal	January 2018
Colloidal Synthesis of Strongly Fluorescent CsPbBr ₃ Nanowires with Width Tunable down to the Quantum Confinement Regime Imran, Muhammad; Di Stasio, Francesco; Dang, Zhiya Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b03081	journal	September 2016
Boosting Tunable Blue Luminescence of Halide Perovskite Nanoplatelets through Postsynthetic Surface Trap Repair Bohn, Bernhard J.; Tong, Yu; Gramlich, Moritz Nano Letters, Vol. 18, Issue 8 https://doi.org/10.1021/acs.nanolett.8b02190	journal	July 2018
Solution-Phase Synthesis of Cesium Lead Halide Perovskite Nanowires Zhang, Dandan; Eaton, Samuel W.; Yu, Yi Journal of the American Chemical Society, Vol. 137, Issue 29 https://doi.org/10.1021/jacs.5b05404	journal	July 2015
The Surface Chemistry of Colloidal HgSe Nanocrystals, toward Stoichiometric Quantum Dots by Design Grigel, Valeriia; Sagar, Laxmi Kishore; De Nolf, Kim Chemistry of Materials, Vol. 30, Issue 21 https://doi.org/10.1021/acs.chemmater.8b02908	journal	October 2018
The perovskite structure—a review of its role in ceramic science and technology Bhalla, A. S.; Guo, Ruyan; Roy, Rustum Materials Research Innovations, Vol. 4, Issue 1 https://doi.org/10.1007/s100190000062	journal	November 2000
Stable Ligand Coordination at the Surface of Colloidal CsPbBr ₃ Nanocrystals Quarta, Danila; Imran, Muhammad; Capodilupo, Agostina-Lina The Journal of Physical Chemistry Letters, Vol. 10, Issue 13 https://doi.org/10.1021/acs.jpclett.9b01634	journal	June 2019
Crystal Structure, Morphology, and Surface Termination of Cyan-Emissive, Six-Monolayers-Thick CsPbBr ₃ Nanoplatelets from X-ray Total Scattering Bertolotti, Federica; Nedelcu, Georgian; Vivani, Anna ACS Nano, Vol. 13, Issue 12 https://doi.org/10.1021/acsnano.9b07626	journal	November 2019
Highly Luminescent Cesium Lead Halide Perovskite Nanocrystals with Tunable Composition and Thickness by Ultrasonication Tong, Yu; Bladt, Eva; Aygüler, Meltem F. Angewandte Chemie International Edition, Vol. 55, Issue 44 https://doi.org/10.1002/anie.201605909	journal	September 2016
Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic–Inorganic Lead Halide Perovskites Noel, Nakita K.; Abate, Antonio; Stranks, Samuel D. ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn5036476	journal	September 2014
Colloidal Synthesis of Quantum Confined Single Crystal CsPbBr ₃ Nanosheets with Lateral Size Control up to the Micrometer Range Shamsi, Javad; Dang, Zhiya; Bianchini, Paolo Journal of the American Chemical Society, Vol. 138, Issue 23 https://doi.org/10.1021/jacs.6b03166	journal	June 2016
Polymer solutions near an interface. Adsorption and depletion layers De Gennes, P. G. Macromolecules, Vol. 14, Issue 6 https://doi.org/10.1021/ma50007a007	journal	November 1981
Polymers at an interface. 2. Interaction between two plates carrying adsorbed polymer layers De Gennes, Pierre Gilles Macromolecules, Vol. 15, Issue 2 https://doi.org/10.1021/ma00230a055	journal	March 1982
CsPbBr ₃ Quantum Dots 2.0: Benzenesulfonic Acid Equivalent Ligand Awakens Complete Purification Yang, Dandan; Li, Xiaoming; Zhou, Wenhan Advanced Materials https://doi.org/10.1002/adma.201900767	journal	June 2019
Composition and Size-Dependent Extinction Coefficient of Colloidal PbSe Quantum Dots Moreels, Iwan; Lambert, Karel; De Muynck, David Chemistry of Materials, Vol. 19, Issue 25 https://doi.org/10.1021/cm071410q	journal	December 2007
Depressed Phase Transitions and Thermally Persistent Local Distortions in CsPbBr ₃ Quantum Dots Cottingham, Patrick; Brutchey, Richard L. Chemistry of Materials, Vol. 30, Issue 19 https://doi.org/10.1021/acs.chemmater.8b02295	journal	September 2018
Solution Synthesis Approach to Colloidal Cesium Lead Halide Perovskite Nanoplatelets with Monolayer-Level Thickness Control Akkerman, Quinten A.; Motti, Silvia Genaro; Srimath Kandada, Ajay Ram Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b12124	journal	January 2016
Enhanced Stabilization and Easy Phase Transfer of CsPbBr ₃ Perovskite Quantum Dots Promoted by High-Affinity Polyzwitterionic Ligands Wang, Sisi; Du, Liang; Jin, Zhicheng Journal of the American Chemical Society, Vol. 142, Issue 29 https://doi.org/10.1021/jacs.0c03682	journal	June 2020
Composition-, Size-, and Surface Functionalization-Dependent Optical Properties of Lead Bromide Perovskite Nanocrystals Ijaz, Palvasha; Imran, Muhammad; Soares, Márcio M. The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00266	journal	February 2020
Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies Bekenstein, Yehonadav; Koscher, Brent A.; Eaton, Samuel W. Journal of the American Chemical Society, Vol. 137, Issue 51 https://doi.org/10.1021/jacs.5b11199	journal	December 2015
Surface Termination, Morphology, and Bright Photoluminescence of Cesium Lead Halide Perovskite Nanocrystals ten Brinck, Stephanie; Infante, Ivan ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00595	journal	November 2016
Color-stable highly luminescent sky-blue perovskite light-emitting diodes Xing, Jun; Zhao, Yongbiao; Askerka, Mikhail Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05909-8	journal	August 2018
Photoluminescence Lifetimes Exceeding 8 μs and Quantum Yields Exceeding 30% in Hybrid Perovskite Thin Films by Ligand Passivation deQuilettes, Dane W.; Koch, Susanne; Burke, Sven ACS Energy Letters, Vol. 1, Issue 2 https://doi.org/10.1021/acsenergylett.6b00236	journal	July 2016
Temperature-Driven Transformation of CsPbBr ₃ Nanoplatelets into Mosaic Nanotiles in Solution through Self-Assembly Dang, Zhiya; Dhanabalan, Balaji; Castelli, Andrea Nano Letters, Vol. 20, Issue 3 https://doi.org/10.1021/acs.nanolett.9b05036	journal	January 2020
Accelerated Carrier Relaxation through Reduced Coulomb Screening in Two-Dimensional Halide Perovskite Nanoplatelets Hintermayr, Verena A.; Polavarapu, Lakshminarayana; Urban, Alexander S. ACS Nano, Vol. 12, Issue 10 https://doi.org/10.1021/acsnano.8b05029	journal	September 2018
Design Principles for Trap-Free CsPbX ₃ Nanocrystals: Enumerating and Eliminating Surface Halide Vacancies with Softer Lewis Bases Nenon, David P.; Pressler, Kimo; Kang, Jun Journal of the American Chemical Society, Vol. 140, Issue 50 https://doi.org/10.1021/jacs.8b11035	journal	November 2018
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Polymers at an interface; a simplified view de Gennes, P. G. Advances in Colloid and Interface Science, Vol. 27, Issue 3-4 https://doi.org/10.1016/0001-8686(87)85003-0	journal	July 1987
Ultrathin Colloidal Cesium Lead Halide Perovskite Nanowires Zhang, Dandan; Yu, Yi; Bekenstein, Yehonadav Journal of the American Chemical Society, Vol. 138, Issue 40 https://doi.org/10.1021/jacs.6b08373	journal	September 2016
Ueber einige neue Mineralien des Urals Rose, Gustav Journal f�r Praktische Chemie, Vol. 19, Issue 1 https://doi.org/10.1002/prac.18400190179	journal	January 1840

Similar Records

Mechanistic Exploration of Dodecanethiol-Treated Colloidal CsPbBr₃ Nanocrystals with Photoluminescence Quantum Yields Reaching Near 100%

Journal Article · Fri Jun 21 00:00:00 EDT 2019 · Journal of Physical Chemistry. C · OSTI ID:1765699

Uddin, Md Aslam; Mobley, Justin K.; Masud, Abdullah A.; +5 more

Toward Stable Deep-Blue Luminescent Colloidal Lead Halide Perovskite Nanoplatelets: Systematic Photostability Investigation

Journal Article · Mon Mar 18 00:00:00 EDT 2019 · Chemistry of Materials · OSTI ID:1765699

Ha, Seung Kyun; Mauck, Catherine M.; Tisdale, William A.

Beyond Strain: Controlling the Surface Chemistry of CsPbI₃ Nanocrystal Films for Improved Stability against Ambient Reactive Oxygen Species

Journal Article · Mon Aug 31 00:00:00 EDT 2020 · Chemistry of Materials · OSTI ID:1765699

Moot, Taylor; Dikova, Desislava R.; Hazarika, Abhijit; +11 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Crystals
Ligands
Nanoparticles
Perovskites
Nanocrystals

Title: The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals

Citation Formats

References (86)

Similar Records

Related Subjects