Magnesium Todorokite: Influence of Morphology on Electrochemistry in Lithium, Sodium and Magnesium Based Batteries

Zhang, Bingjie; Quilty, Calvin D.; Wang, Lei; Hu, Xiaobing; Poyraz, Altug; Bock, David C.; Li, Yue Ru; Gerhardt, Liana; Wu, Lijun; Zhu, Yimei; Marschilok, Amy C.; Takeuchi, Esther S.; Takeuchi, Kenneth J.

doi:10.1149/1945-7111/aba33a

Title: Magnesium Todorokite: Influence of Morphology on Electrochemistry in Lithium, Sodium and Magnesium Based Batteries

Journal Article · Wed Jul 15 00:00:00 EDT 2020 · Journal of the Electrochemical Society (Online)

DOI:https://doi.org/10.1149/1945-7111/aba33a· OSTI ID:1765651

Zhang, Bingjie ^[1]; Quilty, Calvin D. ^[1]; Wang, Lei ^[2];

^[2]; Poyraz, Altug ^[3]; Bock, David C. ^[2]; Li, Yue Ru ^[1]; Gerhardt, Liana ^[4]; Wu, Lijun ^[2];

^[2];

^[5];

^[5]; Takeuchi, Kenneth J. ^[1]

Stony Brook Univ., NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Kennesaw State Univ., GA (United States)
Kennesaw State Univ., GA (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Samples of Mg-todorokite with mixed nanosheet & nanowire (referred to as nanosheets for the sake of simplicity) and pure nanowire morphology were prepared to probe the morphological impact on battery relevant electrochemistry. The samples had similar physicochemical properties where the Mg-todorokite nanosheets had a composition of Mg_0.20MnO₂ with a crystallite size of 9 nm and water content of 0.29 moles of H₂O per formula unit, while the nanowires had a composition of Mg_0.19MnO₂ with a crystallite size of 14 nm and water content of 0.28. The electrochemistry of the Mg-todorokite materials was evaluated using cyclic voltammetry, galvanostatic cycling, and rate capability testing. The Mg-todorokite nanosheets showed higher discharge capacity than the nanowires in lithium, sodium and magnesium-based electrolytes. Notably, the nanowire materials exhibited excellent cycling stability compared to the nanosheets in lithium and sodium-based batteries. Finally, x-ray absorption spectroscopy (XAS) of lithiated samples suggests that Mn in the nanosheet containing material was more highly reduced to Mn³⁺ after the 1st full discharge explaining the higher initial capacities observed. However, a MnO-like structural distortion was observed after extended cycling in the nanosheet material consistent with its poorer capacity retention.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; SC0012673; AC02-06CH11357; 1659657

OSTI ID:: 1765651

Report Number(s):: BNL-221019-2021-JAAM

Journal Information:: Journal of the Electrochemical Society (Online), Vol. 167, Issue 11; ISSN 1945-7111

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

References (43)

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Magnesium Manganese Oxide Nanoribbons: Synthesis, Characterization, and Catalytic Application Liu, Jia; Cai, Jun; Son, Young-Chan The Journal of Physical Chemistry B, Vol. 106, Issue 38 https://doi.org/10.1021/jp0208586	journal	September 2002
Todorokite-type manganese oxide nanowires as an intercalation cathode for Li-ion and Na-ion batteries Byles, B. W.; West, P.; Cullen, D. A. RSC Advances, Vol. 5, Issue 128 https://doi.org/10.1039/C5RA20624C	journal	January 2015
A new synthetic route to todorokite-type manganese oxides Ching, Stanton; Krukowska, Katarzyna S.; Suib, Steven L. Inorganica Chimica Acta, Vol. 294, Issue 2 https://doi.org/10.1016/S0020-1693(99)00208-X	journal	November 1999
The role of electronic and ionic conductivities in the rate performance of tunnel structured manganese oxides in Li-ion batteries Byles, B. W.; Palapati, N. K. R.; Subramanian, A. APL Materials, Vol. 4, Issue 4 https://doi.org/10.1063/1.4948272	journal	April 2016
Nanostructured Mn-based oxides for electrochemical energy storage and conversion Zhang, Kai; Han, Xiaopeng; Hu, Zhe Chemical Society Reviews, Vol. 44, Issue 3 https://doi.org/10.1039/C4CS00218K	journal	January 2015
Manganese oxide-based materials as electrochemical supercapacitor electrodes Wei, Weifeng; Cui, Xinwei; Chen, Weixing Chem. Soc. Rev., Vol. 40, Issue 3 https://doi.org/10.1039/C0CS00127A	journal	January 2011
Todorokite as a Li Insertion Cathode Duncan, M. J. Journal of The Electrochemical Society, Vol. 145, Issue 11 https://doi.org/10.1149/1.1838869	journal	January 1998
Fabrication of magnetic cryptomelane-type manganese oxide nanowires for water treatment Zhang, Tong; Zhang, Xiwang; Ng, Jiawei Chem. Commun., Vol. 47, Issue 6 https://doi.org/10.1039/C0CC03265D	journal	January 2011
Structural Defects of Silver Hollandite, Ag _x Mn ₈ O _{y ,} Nanorods: Dramatic Impact on Electrochemistry Wu, Lijun; Xu, Feng; Zhu, Yimei ACS Nano, Vol. 9, Issue 8 https://doi.org/10.1021/acsnano.5b03274	journal	July 2015
The structure of K _1.33 Mn ₈ O ₁₆ and cation ordering in hollandite-type structures Vicat, J.; Fanchon, E.; Strobel, P. Acta Crystallographica Section B Structural Science, Vol. 42, Issue 2 https://doi.org/10.1107/S0108768186098415	journal	April 1986
Ordering Heterogeneity of [MnO6] Octahedra in Tunnel-Structured MnO2 and Its Influence on Ion Storage Yuan, Yifei; Liu, Cong; Byles, Bryan W. Joule, Vol. 3, Issue 2 https://doi.org/10.1016/j.joule.2018.10.026	journal	February 2019
Recent Advances in Metal Oxide-based Electrode Architecture Design for Electrochemical Energy Storage Jiang, Jian; Li, Yuanyuan; Liu, Jinping Advanced Materials, Vol. 24, Issue 38 https://doi.org/10.1002/adma.201202146	journal	August 2012
Preparation and Characterization of Open Tunnel Oxide α-MnO2 Precipitated by Ozone Oxidation Kijima, Norihito; Yasuda, Hiroyuki; Sato, Toshio Journal of Solid State Chemistry, Vol. 159, Issue 1 https://doi.org/10.1006/jssc.2001.9136	journal	June 2001
Nanosized silver-coated and doped manganese dioxide for rechargeable lithium batteries Abuzeid, Hanaa M.; Hashem, Ahmed M.; Narayanan, N. Solid State Ionics, Vol. 182, Issue 1 https://doi.org/10.1016/j.ssi.2010.11.023	journal	February 2011
Formation of todorokite from “c-disordered” H+-birnessites: the roles of average manganese oxidation state and interlayer cations Zhao, Huaiyan; Liang, Xinran; Yin, Hui Geochemical Transactions, Vol. 16, Issue 1 https://doi.org/10.1186/s12932-015-0023-3	journal	July 2015
Single-step synthesis of manganese oxide octahedral molecular sieves with large pore sizes Huang, Hui; Chen, Chun-Hu; Xu, Linping Chemical Communications, Vol. 46, Issue 32 https://doi.org/10.1039/c0cc00624f	journal	January 2010
Todorokite-type MnO2 as a zinc-ion intercalating material Lee, Jonghyuk; Ju, Jeh Beck; Cho, Won Il Electrochimica Acta, Vol. 112 https://doi.org/10.1016/j.electacta.2013.08.136	journal	December 2013
Synthesis of metal-doped todorokite-type MnO2 and its cathode characteristics for rechargeable lithium batteries Kumagai, Naoaki; Komaba, Shinichi; Abe, Kiyoko Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.145	journal	August 2005
PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals Farrow, C. L.; Juhas, P.; Liu, J. W. Journal of Physics: Condensed Matter, Vol. 19, Issue 33 https://doi.org/10.1088/0953-8984/19/33/335219	journal	July 2007
Transformation of Birnessite to Buserite, Todorokite, and Manganite under Mild Hydrothermal Treatment Golden, D. C. Clays and Clay Minerals, Vol. 35, Issue 4 https://doi.org/10.1346/CCMN.1987.0350404	journal	January 1987
Synthesis of Todorokite at Atmospheric Pressure Feng, Xiong Han; Tan, Wen Feng; Liu, Fan Chemistry of Materials, Vol. 16, Issue 22 https://doi.org/10.1021/cm0499545	journal	November 2004
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/b702425h	journal	January 2007
Raman spectroscopy of AMn2O4 (A = Mn, Mg and Zn) spinels Malavasi, Lorenzo; Galinetto, Pietro; Mozzati, Maria C. Physical Chemistry Chemical Physics, Vol. 4, Issue 15 https://doi.org/10.1039/b203520k	journal	June 2002
Nature of Activated Manganese Oxide for Oxygen Evolution Huynh, Michael; Shi, Chenyang; Billinge, Simon J. L. Journal of the American Chemical Society, Vol. 137, Issue 47 https://doi.org/10.1021/jacs.5b06382	journal	November 2015
Structure of nanocrystalline materials using atomic pair distribution function analysis: Study of ${LiMoS}_{2}$ Petkov, V.; Billinge, S. J. L.; Larson, P. Physical Review B, Vol. 65, Issue 9 https://doi.org/10.1103/PhysRevB.65.092105	journal	February 2002
Two-Dimensional Holey Nanoarchitectures Created by Confined Self-Assembly of Nanoparticles via Block Copolymers: From Synthesis to Energy Storage Property Peng, Lele; Fang, Zhiwei; Li, Jing ACS Nano, Vol. 12, Issue 1 https://doi.org/10.1021/acsnano.7b08186	journal	December 2017
Manganese oxide minerals: Crystal structures and economic and environmental significance Post, J. E. Proceedings of the National Academy of Sciences, Vol. 96, Issue 7 https://doi.org/10.1073/pnas.96.7.3447	journal	March 1999
Investigation of α-MnO ₂ Tunneled Structures as Model Cation Hosts for Energy Storage Housel, Lisa M.; Wang, Lei; Abraham, Alyson Accounts of Chemical Research, Vol. 51, Issue 3 https://doi.org/10.1021/acs.accounts.7b00478	journal	February 2018
Improved electrochemical cycling stability of intercalation battery electrodes via control of material morphology Byles, Bryan W.; Clites, Mallory; Cullen, David A. Ionics, Vol. 25, Issue 2 https://doi.org/10.1007/s11581-018-2715-z	journal	September 2018
Revealing and Rationalizing the Rich Polytypism of Todorokite MnO ₂ Hu, Xiaobing; Kitchaev, Daniil A.; Wu, Lijun Journal of the American Chemical Society, Vol. 140, Issue 22 https://doi.org/10.1021/jacs.8b02971	journal	April 2018
Ab Initio Studies of Hydrogen Ion Insertion into β-, R-, and γ-MnO ₂ Polymorphs and the Implications for Shallow-Cycled Rechargeable Zn/MnO ₂ Batteries Vasiliev, Igor; Magar, Birendra Ale; Duay, Jonathon Journal of The Electrochemical Society, Vol. 165, Issue 14 https://doi.org/10.1149/2.1161814jes	journal	January 2018
Synthesis and characterization of the hollandite-type MnO2 as a cathode material in lithium batteries Dai, Jinxiang; Li, Sam F. Y.; Siow, Kok Siong Electrochimica Acta, Vol. 45, Issue 14 https://doi.org/10.1016/S0013-4686(99)00441-7	journal	March 2000
Ag1.8Mn8O16: Quadratisch-Planar koordinierte Ag⊕ Ionen in den Kanälen einer neuartigen Hollanditvariante Chang, Fung Ming; Jansen, Martin Angewandte Chemie, Vol. 96, Issue 11 https://doi.org/10.1002/ange.19840961120	journal	November 1984
Ultrahigh-pressure polyamorphism in GeO ₂ glass with coordination number >6 Kono, Yoshio; Kenney-Benson, Curtis; Ikuta, Daijo Proceedings of the National Academy of Sciences, Vol. 113, Issue 13 https://doi.org/10.1073/pnas.1524304113	journal	March 2016
Brittle fracture to recoverable plasticity: polytypism-dependent nanomechanics in todorokite-like nanobelts Amin Shikder, Md Ruhul; Maksud, Mahjabin; Vasudevamurthy, Gokul Nanoscale Advances, Vol. 1, Issue 1 https://doi.org/10.1039/C8NA00079D	journal	January 2019
Synchrotron X-ray diffraction study of the structure and dehydration behavior of todorokite Post, Jeffrey E.; Heaney, Peter J.; Hanson, Jonathan American Mineralogist, Vol. 88, Issue 1 https://doi.org/10.2138/am-2003-0117	journal	January 2003
Phase evolution of an alpha MnO 2 -based electrode for pseudo-capacitors probed by in operando Raman spectroscopy Cheng, Shuang; Yang, Lufeng; Chen, Dongchang Nano Energy, Vol. 9 https://doi.org/10.1016/j.nanoen.2014.07.008	journal	October 2014
Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides Shoemaker, Daniel P.; Chung, Duck Young; Mitchell, J. F. Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja303047e	journal	May 2012
Bacterially Produced Manganese Oxide and Todorokite: UV Raman Spectroscopic Comparison Kim, Hack-Sung; Stair, Peter C. The Journal of Physical Chemistry B, Vol. 108, Issue 44 https://doi.org/10.1021/jp048810a	journal	November 2004
In situ high-energy synchrotron X-ray diffraction studies and first principles modeling of α-MnO ₂ electrodes in Li–O ₂ and Li-ion coin cells Yang, Zhenzhen; Trahey, Lynn; Ren, Yang Journal of Materials Chemistry A, Vol. 3, Issue 14 https://doi.org/10.1039/C4TA06633B	journal	January 2015
Synthesis and Characterization of 2 × 4 Tunnel Structured Manganese Dioxides as Cathodes in Rechargeable Li, Na, and Mg Batteries Poyraz, Altug S.; Quilty, Calvin D.; Housel, Lisa M. Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.1341902jes	journal	January 2019
Synthesis and Electrochemistry of Silver Hollandite Zhu, Shali; Marschilok, Amy C.; Lee, Chia-Ying Electrochemical and Solid-State Letters, Vol. 13, Issue 8 https://doi.org/10.1149/1.3428747	journal	January 2010

Similar Records

Todorokite-type manganese oxide nanowires as an intercalation cathode for Li-ion and Na-ion batteries

Journal Article · Thu Dec 03 00:00:00 EST 2015 · RSC Advances · OSTI ID:1765651

Byles, B. W.; West, P.; Cullen, D. A.; +2 more

Review of the Stability/Capacity Trade-off in Silver Hollandite Lithium Battery Cathodes

Journal Article · Mon Jan 01 00:00:00 EST 2018 · MRS Advances · OSTI ID:1765651

Smith, Paul F.; Lutz, Diana M.; Takeuchi, Esther S.; +2 more

Deconvolution of Composition and Crystallite Size of Silver Hollandite Nanorods: Influence on Electrochemistry

Journal Article · Sat Dec 16 00:00:00 EST 2017 · Journal of the Electrochemical Society · OSTI ID:1765651

Durham, Jessica L.; Huang, Jianping; Zhang, Bingjie; +7 more

Related Subjects

25 ENERGY STORAGE

Title: Magnesium Todorokite: Influence of Morphology on Electrochemistry in Lithium, Sodium and Magnesium Based Batteries

Citation Formats

References (43)

Similar Records

Related Subjects