Quasi-one-dimensional magnetism in the spin-12 antiferromagnet BaNa2Cu(VO4)2

Sebastian, Sebin J.; Somesh, K.; Nandi, M.; Ahmed, N.; Bag, P.; Baenitz, M.; Koo, B.; Sichelschmidt, J.; Tsirlin, A. A.; Furukawa, Y.; Nath, R.

doi:10.1103/physrevb.103.064413

Title: Quasi-one-dimensional magnetism in the spin-12 antiferromagnet BaNa₂Cu(VO₄)₂

Journal Article · Mon Feb 08 00:00:00 EST 2021 · Physical Review B

DOI:https://doi.org/10.1103/physrevb.103.064413· OSTI ID:1764840

^[1]; Somesh, K. ^[1]; Nandi, M. ^[2]; Ahmed, N. ^[1]; Bag, P. ^[1]; Baenitz, M. ^[3];

^[3];

^[4];

^[2];

^[1]

Indian Inst. of Science Education and Research Thiruvananthapuram (India)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
Max Planck Inst. for Chemical Physics of Solids, Dresden (Germany)
Univ. of Augsburg (Germany)

Here, we report synthesis and magnetic properties of quasi-one-dimensional spin- $\frac{1}{2}$ Heisenberg antiferromagnetic chain compound ${BaNa}_{2} Cu {({VO}_{4})}_{2}$ . This orthovanadate has a centrosymmetric crystal structure, $C 2 / c$ , where the magnetic ${Cu}^{2 +}$ ions form spin chains. These chains are arranged in layers, with the chain direction changing by $62^{°}$ between the two successive layers. Alternatively, the spin lattice can be viewed as anisotropic triangular layers upon taking the interchain interactions into consideration. Despite this potential structural complexity, temperature-dependent magnetic susceptibility, heat capacity, electron spin resonance intensity, and nuclear magnetic resonance (NMR) shift agree well with the uniform spin- $1 / 2$ Heisenberg chain model with an intrachain coupling of $J / k_{B} ≃ 5.6$ K. The saturation field obtained from the magnetic isotherm measurement consistently reproduces the value of $J / k_{B}$ . Further, the ${}_{51}V$ NMR spin-lattice relaxation rate mimics the one-dimensional character in the intermediate temperature range, whereas magnetic long-range order sets in below $T_{N} ≃ 0.25$ K. The effective interchain coupling is estimated to be $J_{⊥} / k_{B} ≃ 0.1$ K. The theoretical estimation of exchange couplings using band-structure calculations reciprocate our experimental findings and unambiguously establish the one-dimensional character of the compound. Finally, the spin lattice of ${BaNa}_{2} Cu {({VO}_{4})}_{2}$ is compared with the chemically similar but not isostructural compound ${BaAg}_{2} Cu {({VO}_{4})}_{2}$ .

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Research Organization:: Ames Lab., Ames, IA (United States)

Sponsoring Organization:: Science and Engineering Research Board (SERB); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; Alexander von Humboldt Foundation

Grant/Contract Number:: CRG/2019/000960; AC02-07CH11358

OSTI ID:: 1764840

Report Number(s):: IS-J-10,411; TRN: US2206211

Journal Information:: Physical Review B, Vol. 103, Issue 6; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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