Charge transfer states impact the triplet pair dynamics of singlet fission polymers

He, Guiying; Busby, Erik; Appavoo, Kannatassen; Wu, Qin; Xia, Jianlong; Campos, Luis M.; Sfeir, Matthew Y.

doi:10.1063/5.0029858

Title: Charge transfer states impact the triplet pair dynamics of singlet fission polymers

Journal Article · Tue Dec 22 00:00:00 EST 2020 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/5.0029858· OSTI ID:1764590

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City Univ. of New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. of Alabama, Birmingham, AL (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Wuhan Univ. of Technology (China)
Columbia Univ., New York, NY (United States)

Polymers are desirable optoelectronic materials, stemming from their solution processability, tunable electronic properties, and large absorption coefficients. An exciting development is the recent discovery that singlet fission (SF), the conversion of a singlet exciton to a pair of triplet states, can occur along the backbone of an individual conjugated polymer chain. Here, compared to other intramolecular SF compounds, the nature of the triplet pair state in SF polymers remains poorly understood, hampering the development of new materials with optimized excited state dynamics.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; DMR-2004683; DMR-2004678

OSTI ID:: 1764590

Alternate ID(s):: OSTI ID: 1737841

Report Number(s):: BNL-220980-2021-JAAM; TRN: US2206445

Journal Information:: Journal of Chemical Physics, Vol. 153, Issue 24; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Charge transfer states impact the triplet pair dynamics of singlet fission polymers

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