Contrasting thermally-induced structural and microstructural evolution of alumino-silicates with tubular and planar arrangements: Case study of halloysite and kaolinite

Asgar, Hassnain; Jin, Jiaqi; Miller, Jan; Kuzmenko, Ivan; Gadikota, Greeshma

doi:10.1016/j.colsurfa.2020.126106

Title: Contrasting thermally-induced structural and microstructural evolution of alumino-silicates with tubular and planar arrangements: Case study of halloysite and kaolinite

Journal Article · Wed Jan 06 00:00:00 EST 2021 · Colloids and Surfaces. A, Physicochemical and Engineering Aspects

DOI:https://doi.org/10.1016/j.colsurfa.2020.126106· OSTI ID:1761201

Asgar, Hassnain ^[1]; Jin, Jiaqi ^[2]; Miller, Jan ^[2]; Kuzmenko, Ivan ^[3]; Gadikota, Greeshma ^[1]

Cornell Univ., Ithaca, NY (United States)
Univ. of Utah, Salt Lake City, UT (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Materials with the similar chemical structures but different morphological organization exhibit considerable differences in thermally induced chemo-morphological evolution. With recent advancements in multi-scale X-ray scattering measurements, it is now possible to non-invasively probe the structural and microstructural evolution of such materials. In this study, we investigate the chemo-morphological evolution of halloysite and contrast the results with those for kaolinite. Halloysite and kaolinite have tubular and planar morphologies, respectively. Both materials are alumino-silicates comprised of silica tetrahedral (T) and alumina octahedral (O) sheets organized in a TO structure. Four distinct stages in the structural evolution were identified. Stages I, II, III, and IV correspond to temperature ranges of 25-125 degrees C, 125-400 degrees C, 400-625 degrees C, and 625-875 degrees C. Major structural changes correspond to the removal of interlayer/adsorbed water in stage I, the existence of the halloysite structure without interlayer water in stage II, dehydroxylation of halloysite in stage III, and the conversion of ordered halloysite to amorphous meta-halloysite in stage IV. Additionally, heating halloysite up to 875 degrees C resulted in slight widening of the nanotubes, as the average pore radius increased from 6.4 nm to 6.6 nm. Heating also resulted in an increase of wall thickness of the nanotubes from similar to 120 nm (25 degrees C) to 161 nm (875 degrees C). The increase in the halloysite nanotube diameter was attributed to the expansion of the structure and an increase in the surface roughness. The pore sizes in halloysite nanotubes were also confirmed using N-2 adsorption-desorption and nano-X-ray computed tomography (nano-XCT) measurements. The interlayer basal spacing in halloysite changed from 9.8 angstrom to 7.2 angstrom after the removal of interlayer water. At temperatures in the range of 625-875 degrees C, heating halloysite causes a small widening of nanotube pores and a minor increase in the surface area. In contrast, the interlayer spacing in kaolinite collapses on heating which reduces the nanoscale porosity. These studies demonstrate the differences in the chemo-morphological evolution of alumino-silicates with tubular and planar morphologies.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Univ. of Utah, Salt Lake City, UT (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: SC0019285; AC02-06CH11357

OSTI ID:: 1761201

Alternate ID(s):: OSTI ID: 1778398; OSTI ID: 1797794

Journal Information:: Colloids and Surfaces. A, Physicochemical and Engineering Aspects, Vol. 613; ISSN 0927-7757

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Thermal dehydroxylation of kaolinite under isothermal conditions Gasparini, Elisa; Tarantino, Serena C.; Ghigna, Paolo Applied Clay Science, Vol. 80-81 https://doi.org/10.1016/j.clay.2013.07.017	journal	August 2013
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015
Characterization of halloysite (North East Rif, Morocco): evaluation of its suitability for the ceramics industry El Haddar, Abdelilah; Gharibi, Elkhadir; Azdimousa, Ali Clay Minerals, Vol. 53, Issue 1 https://doi.org/10.1180/clm.2018.5	journal	March 2018
Experiment study on the thermal properties of paraffin/kaolin thermal energy storage form-stable phase change materials Lv, Peizhao; Liu, Chenzhen; Rao, Zhonghao Applied Energy, Vol. 182 https://doi.org/10.1016/j.apenergy.2016.08.147	journal	November 2016
Amine modification on kaolinites to enhance CO2 adsorption Chen, Yen-Hua; Lu, De-Long Journal of Colloid and Interface Science, Vol. 436 https://doi.org/10.1016/j.jcis.2014.08.050	journal	December 2014
A spectroscopic comparison of selected Chinese kaolinite, coal bearing kaolinite and halloysite—A mid-infrared and near-infrared study Cheng, Hongfei; Yang, Jing; Liu, Qinfu Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 77, Issue 4 https://doi.org/10.1016/j.saa.2010.08.018	journal	November 2010
Tailless X‐Ray Single‐Crystal Reflection Curves Obtained by Multiple Reflection Bonse, U.; Hart, M. Applied Physics Letters, Vol. 7, Issue 9 https://doi.org/10.1063/1.1754396	journal	November 1965
Halloysite clay minerals — a review Joussein, E.; Petit, S.; Churchman, J. Clay Minerals, Vol. 40, Issue 4 https://doi.org/10.1180/0009855054040180	journal	December 2005
Mixed matrix membrane incorporated with large pore size halloysite nanotubes (HNTs) as filler for gas separation: Morphological diagram Hashemifard, S. A.; Ismail, A. F.; Matsuura, T. Chemical Engineering Journal, Vol. 172, Issue 1 https://doi.org/10.1016/j.cej.2011.06.031	journal	August 2011
Experimental Transformation of Kaolinite to Halloysite Singh, Balbir Clays and Clay Minerals, Vol. 44, Issue 6 https://doi.org/10.1346/CCMN.1996.0440614	journal	January 1996
Hydrothermally synthesized zeolites based on kaolinite: A review Johnson, E. B. G.; Arshad, Sazmal E. Applied Clay Science, Vol. 97-98 https://doi.org/10.1016/j.clay.2014.06.005	journal	August 2014
Mixed matrix membrane incorporated with large pore size halloysite nanotubes (HNT) as filler for gas separation: Experimental Hashemifard, S. A.; Ismail, A. F.; Matsuura, T. Journal of Colloid and Interface Science, Vol. 359, Issue 2 https://doi.org/10.1016/j.jcis.2011.03.077	journal	July 2011
Preparation of capric acid/halloysite nanotube composite as form-stable phase change material for thermal energy storage Mei, Dandan; Zhang, Bing; Liu, Ruichao Solar Energy Materials and Solar Cells, Vol. 95, Issue 10 https://doi.org/10.1016/j.solmat.2011.05.024	journal	October 2011
Observation of the Hydrated Form of Tubular Halloysite by an Electron Microscope Equipped with an Environmental Cell Kohyama, Norihiko Clays and Clay Minerals, Vol. 26, Issue 1 https://doi.org/10.1346/CCMN.1978.0260103	journal	January 1978
Dehydrated halloysite intercalated mechanochemically with urea: Thermal behavior and structural aspects Nicolini, Keller Paulo; Fukamachi, Cristiane Regina Budziak; Wypych, Fernando Journal of Colloid and Interface Science, Vol. 338, Issue 2 https://doi.org/10.1016/j.jcis.2009.06.058	journal	October 2009
Preparation and characterization of novel carbon dioxide adsorbents based on polyethylenimine-modified Halloysite nanotubes Cai, Haohao; Bao, Feng; Gao, Jie Environmental Technology, Vol. 36, Issue 10 https://doi.org/10.1080/09593330.2014.984772	journal	December 2014
Fluid structure and transport properties of water inside carbon nanotubes Liu, Yingchun; Wang, Qi; Wu, Tao The Journal of Chemical Physics, Vol. 123, Issue 23 https://doi.org/10.1063/1.2131070	journal	December 2005
Polyethylene glycol/halloysite@Ag nanocomposite PCM for thermal energy storage: Simultaneously high latent heat and enhanced thermal conductivity Song, Shaokun; Qiu, Feng; Zhu, Wanting Solar Energy Materials and Solar Cells, Vol. 193 https://doi.org/10.1016/j.solmat.2019.01.023	journal	May 2019
Lauric acid/intercalated kaolinite as form-stable phase change material for thermal energy storage Song, Shaokun; Dong, Lijie; Zhang, Yang Energy, Vol. 76 https://doi.org/10.1016/j.energy.2014.08.042	journal	November 2014
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Preparation of stearic acid/halloysite nanotube composite as form-stable PCM for thermal energy storage Mei, Dandan; Zhang, Bing; Liu, Ruichao International Journal of Energy Research, Vol. 35, Issue 9 https://doi.org/10.1002/er.1874	journal	May 2011
Silanization of heat-treated halloysite nanotubes using γ-aminopropyltriethoxysilane Jia, Shiyu; Fan, Mingde Applied Clay Science, Vol. 180 https://doi.org/10.1016/j.clay.2019.105204	journal	November 2019
Study of Natural Halloysite from the Dragon Mine, Utah (USA) García, Francisco J.; García Rodríguez, Sergio; Kalytta, Andreas Zeitschrift für anorganische und allgemeine Chemie, Vol. 635, Issue 4-5 https://doi.org/10.1002/zaac.200900076	journal	April 2009
Exploring the Role of Inorganic and Organic Interfaces on CO ₂ and CH ₄ Partitioning: Case Study of Silica, Illite, Calcite, and Kerogen Nanopores on Gas Adsorption and Nanoscale Transport Behaviors Mohammed, Sohaib; Gadikota, Greeshma Energy & Fuels, Vol. 34, Issue 3 https://doi.org/10.1021/acs.energyfuels.0c00052	journal	February 2020
Confinement Effects on Carbon Dioxide Methanation: A Novel Mechanism for Abiotic Methane Formation Le, Thu; Striolo, Alberto; Turner, C. Heath Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-09445-1	journal	August 2017
Role of clays in the disposal of nuclear waste: A review Lee, S. Y.; Tank, R. W. Applied Clay Science, Vol. 1, Issue 1-2 https://doi.org/10.1016/0169-1317(85)90570-8	journal	July 1985
Experimental and Molecular Modeling Study of Bubble Points of Hydrocarbon Mixtures in Nanoporous Media Pathak, Manas; Cho, Hyeyoung; Deo, Milind Energy & Fuels, Vol. 31, Issue 4 https://doi.org/10.1021/acs.energyfuels.6b02422	journal	February 2017
Halloysite Nanotubes Capturing Isotope Selective Atmospheric CO2 Jana, Subhra; Das, Sankar; Ghosh, Chiranjit Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep08711	journal	March 2015
The Dehydroxylation of the Kaolinite Clay Minerals using Infrared Emission Spectroscopy Frost, Ray L. Clays and Clay Minerals, Vol. 44, Issue 5 https://doi.org/10.1346/CCMN.1996.0440506	journal	January 1996
Dynamic Wettability Alteration of Calcite, Silica and Illite Surfaces in Subsurface Environments: A Case Study of Asphaltene Self-Assembly at Solid Interfaces Mohammed, Sohaib; Gadikota, Greeshma Applied Surface Science, Vol. 505 https://doi.org/10.1016/j.apsusc.2019.144516	journal	March 2020
Polyaniline in situ modified halloysite nanotubes incorporated asymmetric mixed matrix membrane for gas separation Surya Murali, R.; Padaki, Mahesh; Matsuura, T. Separation and Purification Technology, Vol. 132 https://doi.org/10.1016/j.seppur.2014.05.020	journal	August 2014
Phase behavior and flow in shale nanopores from molecular simulations Jin, Zhehui; Firoozabadi, Abbas Fluid Phase Equilibria, Vol. 430 https://doi.org/10.1016/j.fluid.2016.09.011	journal	December 2016
CO2 capture by kaolinite and its adsorption mechanism Chen, Yen-Hua; Lu, De-Long Applied Clay Science, Vol. 104 https://doi.org/10.1016/j.clay.2014.11.036	journal	February 2015
Amine-Impregnated Mesoporous Silica Nanotube as an Emerging Nanocomposite for CO ₂ Capture Niu, Mengya; Yang, Huaming; Zhang, Xiangchao ACS Applied Materials & Interfaces, Vol. 8, Issue 27 https://doi.org/10.1021/acsami.6b05044	journal	June 2016
Nika : software for two-dimensional data reduction Ilavsky, Jan Journal of Applied Crystallography, Vol. 45, Issue 2 https://doi.org/10.1107/S0021889812004037	journal	March 2012
Investigation of nanopore confinement on fluid flow in tight reservoirs Zhang, Yuan; Yu, Wei; Sepehrnoori, Kamy Journal of Petroleum Science and Engineering, Vol. 150 https://doi.org/10.1016/j.petrol.2016.11.005	journal	February 2017
Crystallohydrate Loaded Halloysite Nanocontainers for Thermal Energy Storage Zhu, Xiaolei; Shchukin, Dmitry Advanced Engineering Materials, Vol. 20, Issue 11 https://doi.org/10.1002/adem.201800618	journal	September 2018
Small-Angle Scattering from Polymeric Mass Fractals of Arbitrary Mass-Fractal Dimension Beaucage, G. Journal of Applied Crystallography, Vol. 29, Issue 2 https://doi.org/10.1107/S0021889895011605	journal	April 1996
Simulation of chemical reaction equilibria and kinetics in heterogeneous carbon micropores Turner, C. Heath; Brennan, John K.; Pikunic, Jorge Applied Surface Science, Vol. 196, Issue 1-4 https://doi.org/10.1016/S0169-4332(02)00074-0	journal	August 2002
Development of combined microstructure and structure characterization facility for in situ and operando studies at the Advanced Photon Source Ilavsky, Jan; Zhang, Fan; Andrews, Ross N. Journal of Applied Crystallography, Vol. 51, Issue 3 https://doi.org/10.1107/S160057671800643X	journal	June 2018
Integrated CO ₂ Capture, Conversion, and Storage To Produce Calcium Carbonate Using an Amine Looping Strategy Liu, Meishen; Gadikota, Greeshma Energy & Fuels, Vol. 33, Issue 3 https://doi.org/10.1021/acs.energyfuels.8b02803	journal	September 2018
Transport Properties and Distribution of Water Molecules Confined in Hydrophobic Nanopores and Nanoslits Liu, Yingchun; Wang, Qi; Lu, Linghong Langmuir, Vol. 20, Issue 16 https://doi.org/10.1021/la036325l	journal	August 2004
Elucidating Thermally Induced Structural and Chemical Transformations in Kaolinite Using Reactive Molecular Dynamics Simulations and X-ray Scattering Measurements Muraleedharan, Murali Gopal; Asgar, Hassnain; Mohammed, Sohaib Chemistry of Materials, Vol. 32, Issue 2 https://doi.org/10.1021/acs.chemmater.9b03929	journal	November 2019
Chemo-morphological coupling during serpentine heat treatment for carbon mineralization Liu, Meishen; Gadikota, Greeshma Fuel, Vol. 227 https://doi.org/10.1016/j.fuel.2018.04.097	journal	September 2018
Mechanistic insights into the colloidal assembly of mesoporous silica using in-operando cross-scale X-ray scattering and spectroscopic measurements Asgar, Hassnain; Seifert, Soenke; Kuzmenko, Ivan Materialia, Vol. 12 https://doi.org/10.1016/j.mtla.2020.100764	journal	August 2020
Surface-etched halloysite nanotubes in mixed matrix membranes for efficient gas separation Ge, Lei; Lin, Rijia; Wang, Li Separation and Purification Technology, Vol. 173 https://doi.org/10.1016/j.seppur.2016.09.015	journal	February 2017
Mechanical and Bonding Behaviors Behind the Bending Mechanism of Kaolinite Clay Layers Tunega, Daniel; Zaoui, Ali The Journal of Physical Chemistry C, Vol. 124, Issue 13 https://doi.org/10.1021/acs.jpcc.9b11274	journal	March 2020
Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering Beaucage, G. Journal of Applied Crystallography, Vol. 28, Issue 6 https://doi.org/10.1107/S0021889895005292	journal	December 1995
Capillary filling of confined water in nanopores: Coupling the increased viscosity and slippage Feng, Dong; Li, Xiangfang; Wang, Xiangzeng Chemical Engineering Science, Vol. 186 https://doi.org/10.1016/j.ces.2018.04.055	journal	August 2018
Lithium orthosilicate with halloysite as silicon source for high temperature CO ₂ capture Niu, Mengya; Li, Xiaoyu; Ouyang, Jing RSC Advances, Vol. 6, Issue 50 https://doi.org/10.1039/C6RA05004B	journal	January 2016
Removal of radiocobalt ions from aqueous solutions by natural halloysite nanotubes Li, Jie; Wen, Feng; Pan, Lisha Journal of Radioanalytical and Nuclear Chemistry, Vol. 295, Issue 1 https://doi.org/10.1007/s10967-012-1823-x	journal	May 2012
Silver behenate and silver stearate powders for calibration of SAS instruments Nyam-Osor, M.; Soloviov, D. V.; Kovalev, Yu S. Journal of Physics: Conference Series, Vol. 351 https://doi.org/10.1088/1742-6596/351/1/012024	journal	March 2012
Fourier Transform Raman Spectroscopy of Kaolinite, Dickite and Halloysite Frost, Ray L. Clays and Clay Minerals, Vol. 43, Issue 2 https://doi.org/10.1346/CCMN.1995.0430206	journal	January 1995
A new method for the model‐independent assessment of thickness in three‐dimensional images Hildebrand, T.; Rüegsegger, P. Journal of Microscopy, Vol. 185, Issue 1 https://doi.org/10.1046/j.1365-2818.1997.1340694.x	journal	January 1997
Probing the Influence of Thermally Induced Structural Changes on the Microstructural Evolution in Shale using Multiscale X-ray Scattering Measurements Liu, Meishen; Gadikota, Greeshma Energy & Fuels, Vol. 32, Issue 8 https://doi.org/10.1021/acs.energyfuels.8b01486	journal	June 2018
Ultra-Small-Angle X-ray Scattering Instrument at the Advanced Photon Source: History, Recent Development, and Current Status Ilavsky, J.; Zhang, F.; Allen, A. J. Metallurgical and Materials Transactions A, Vol. 44, Issue 1 https://doi.org/10.1007/s11661-012-1431-y	journal	October 2012
Novel aqueous amine looping approach for the direct capture, conversion and storage of CO ₂ to produce magnesium carbonate Liu, Meishen; Asgar, Hassnain; Seifert, Soenke Sustainable Energy & Fuels, Vol. 4, Issue 3 https://doi.org/10.1039/C9SE00316A	journal	January 2020
High-temperature transformation in kaolinite: the role of the crystallinity and of the firing atmosphere Dubois, J.; Murat, M.; Amroune, A. Applied Clay Science, Vol. 10, Issue 3 https://doi.org/10.1016/0169-1317(95)00030-8	journal	October 1995
Connecting the Morphological and Crystal Structural Changes during the Conversion of Lithium Hydroxide Monohydrate to Lithium Carbonate Using Multi-Scale X-ray Scattering Measurements Gadikota, Greeshma Minerals, Vol. 7, Issue 9 https://doi.org/10.3390/min7090169	journal	September 2017
Characterization studies of heat-treated halloysite nanotubes Aytekin, M. Türkay; Hoşgün, Halit L. Chemical Papers, Vol. 74, Issue 12 https://doi.org/10.1007/s11696-020-01263-6	journal	June 2020
Halloysite nanotubes: Novel and eco-friendly adsorbents for high-pressure CO2 capture Ramadass, Kavitha; Singh, Gurwinder; Lakhi, Kripal Singh Microporous and Mesoporous Materials, Vol. 277 https://doi.org/10.1016/j.micromeso.2018.10.035	journal	March 2019
Application of halloysite nanotubes for carbon dioxide capture Kim, Jinsoo; Rubino, Ilaria; Lee, Joo-Youp Materials Research Express, Vol. 3, Issue 4 https://doi.org/10.1088/2053-1591/3/4/045019	journal	April 2016
Thermodynamics, structure, and dynamics of water confined between hydrophobic plates Kumar, Pradeep; Buldyrev, Sergey V.; Starr, Francis W. Physical Review E, Vol. 72, Issue 5 https://doi.org/10.1103/PhysRevE.72.051503	journal	November 2005
Relating Structural and Microstructural Evolution to the Reactivity of Cellulose and Lignin during Alkaline Thermal Treatment with Ca(OH) ₂ for Sustainable Energy Production Integrated with CO ₂ Capture Asgar, Hassnain; Mohammed, Sohaib; Kuzmenko, Ivan ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 5 https://doi.org/10.1021/acssuschemeng.8b06584	journal	January 2019
High morphological stability and structural transition of halloysite (Hunan, China) in heat treatment Ouyang, Jing; Zhou, Zheng; Zhang, Yi Applied Clay Science, Vol. 101 https://doi.org/10.1016/j.clay.2014.08.010	journal	November 2014
Why Does Halloysite Roll?—A New Model Singh, Balbir Clays and Clay Minerals, Vol. 44, Issue 2 https://doi.org/10.1346/CCMN.1996.0440204	journal	January 1996
Effect of confinement on chemical reaction equilibria: The reactions 2NO⇔(NO)2 and N2+3H2⇔2NH3 in carbon micropores Turner, C. Heath; Johnson, J. Karl; Gubbins, Keith E. The Journal of Chemical Physics, Vol. 114, Issue 4 https://doi.org/10.1063/1.1328756	journal	January 2001
In situ structural characterization of ageing kinetics in aluminum alloy 2024 across angstrom-to-micrometer length scales Zhang, Fan; Levine, Lyle E.; Allen, Andrew J. Acta Materialia, Vol. 111 https://doi.org/10.1016/j.actamat.2016.03.058	journal	June 2016
From platy kaolinite to aluminosilicate nanoroll via one-step delamination of kaolinite: Effect of the temperature of intercalation Yuan, Peng; Tan, Daoyong; Annabi-Bergaya, Faïza Applied Clay Science, Vol. 83-84 https://doi.org/10.1016/j.clay.2013.08.027	journal	October 2013
Analysis of textural properties of CaO-based CO2 sorbents by ex situ USAXS Benedetti, Alberto; Ilavsky, Jan; Segre, Carlo Chemical Engineering Journal, Vol. 355 https://doi.org/10.1016/j.cej.2018.07.164	journal	January 2019
Properties and applications of halloysite nanotubes: recent research advances and future prospects Yuan, Peng; Tan, Daoyong; Annabi-Bergaya, Faïza Applied Clay Science, Vol. 112-113 https://doi.org/10.1016/j.clay.2015.05.001	journal	August 2015
Experimental investigation of confinement effect on phase behavior of hexane, heptane and octane using lab-on-a-chip technology Alfi, Mehrdad; Nasrabadi, Hadi; Banerjee, Debjyoti Fluid Phase Equilibria, Vol. 423 https://doi.org/10.1016/j.fluid.2016.04.017	journal	September 2016
Reactive geochemical transport simulation to study mineral trapping for CO ₂ disposal in deep arenaceous formations : TRANSPORT SIMULATION FOR CO Xu, Tianfu; Apps, John A.; Pruess, Karsten Journal of Geophysical Research: Solid Earth, Vol. 108, Issue B2 https://doi.org/10.1029/2002JB001979	journal	February 2003
The role of calcite and silica interfaces on the aggregation and transport of asphaltenes in confinement Mohammed, Sohaib; Gadikota, Greeshma Journal of Molecular Liquids, Vol. 274 https://doi.org/10.1016/j.molliq.2018.10.163	journal	January 2019
Kaolinite stabilized paraffin composite phase change materials for thermal energy storage Li, Chuanchang; Fu, Liangjie; Ouyang, Jing Applied Clay Science, Vol. 115 https://doi.org/10.1016/j.clay.2015.07.033	journal	October 2015
Kaolinite to Halloysite-7 Å Transformation in the Kaolin Deposit of SÃo Vicente de Pereira, Portugal Bobos, Iuliu Clays and Clay Minerals, Vol. 49, Issue 6 https://doi.org/10.1346/CCMN.2001.0490609	journal	January 2001
In Situ Angstrom-to-Micrometer Characterization of the Structural and Microstructural Changes in Kaolinite on Heating Using Ultrasmall-Angle, Small-Angle, and Wide-Angle X-ray Scattering (USAXS/SAXS/WAXS) Gadikota, Greeshma; Zhang, Fan; Allen, Andrew Industrial & Engineering Chemistry Research, Vol. 56, Issue 41 https://doi.org/10.1021/acs.iecr.7b02810	journal	October 2017
CO2-Induced displacement and diffusive transport of shale geofluids in silica nanopores of varying sizes Mohammed, Sohaib; Gadikota, Greeshma Journal of CO2 Utilization, Vol. 32 https://doi.org/10.1016/j.jcou.2019.03.023	journal	July 2019

Similar Records

Characterization of Natural Consolidated Halloysite Nanotube Structures

Journal Article · Wed Nov 24 00:00:00 EST 2021 · Minerals · OSTI ID:1761201

Jin, Jiaqi; Assemi, Shoeleh; Asgar, Hassnain; +5 more

Vertically oriented ZrO₂–TiO₂–Nb₂O₅–Al₂O₃ mixed nanopatterned bioceramics on Ti6Al7Nb implant assessed by laser spallation technique

Journal Article · Mon May 22 00:00:00 EDT 2017 · Journal of Alloys and Compounds · OSTI ID:1761201

Rafieerad, A. R.; Bushroa, A. R.; Nasiri-Tabrizi, B.; +4 more

Halloysite Clay Nanotubes for Enzyme Immobilization

Journal Article · Wed Dec 23 00:00:00 EST 2015 · Biomacromolecules · OSTI ID:1761201

Tully, Joshua; Yendluri, Raghuvara; Lvov, Yuri

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Halloysite
Nanotubes
Kaolinite
Thermal treatment
Ultra-Small/Small-angle X-ray Scattering
Wide-angle X-ray scattering
halloysite
thermal treatment

Title: Contrasting thermally-induced structural and microstructural evolution of alumino-silicates with tubular and planar arrangements: Case study of halloysite and kaolinite

Citation Formats

References (78)

Similar Records

Related Subjects