Mantle–melt partitioning of the highly siderophile elements: New results and application to Mars

Righter, Kevin; Rowland II, Richard Lee; Danielson, Lisa Renee; Humayun, Munir; Yang, Shuying; Mayer, Naemi; Pando, Kellye

doi:10.1111/maps.13598

Title: Mantle–melt partitioning of the highly siderophile elements: New results and application to Mars

Journal Article · Wed Dec 02 00:00:00 EST 2020 · Meteoritics and Planetary Science

DOI:https://doi.org/10.1111/maps.13598· OSTI ID:1756828

^[1];

^[2];

^[2]; Humayun, Munir ^[3]; Yang, Shuying ^[3]; Mayer, Naemi ^[4]; Pando, Kellye ^[1]

NASA Johnson Space Center, Houston, TX (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Florida State Univ., Tallahassee, FL (United States)
Florida State Univ., Tallahassee, FL (United States); Univ. of Hamburg (Germany)

Trace elements and extant and extinct isotopic attributes in Martian meteorites have been used to argue that Mars accreted quickly, differentiated into core and mantle, and established several mantle reservoirs, possibly within 10 Ma of T0. The partitioning of trace elements in the deep mantle has been relatively unstudied, despite the need for such knowledge in understanding magma ocean crystallization and the origin of depleted and enriched mantle reservoirs. The siderophile element composition of the Martian mantle and lithophile isotopic systems such as Sr, Hf, and Nd are thought to record evidence for early metal–silicate equilibrium and deep magma ocean at an intermediate depth and pressure of 800 km or 14 GPa. We have carried out experiments across this pressure range to better understand the mineral/melt partitioning of a wide range of elements. These new data are used to evaluate differentiation models for Mars and to help interpret the available isotopic data. The relatively incompatible nature of Re compared to mildly compatible Os means that the crystallization of a deep magma ocean will lead to residual liquids with superchondritic Re/Os, and solids with subchondritic Re/Os. Such material available in the mantle could be the source of enriched isotopic reservoir that produced shergottites with +γOs values. Slightly subchondritic Re/Os ratios in the crystallizing solids would provide a reservoir that could produce -γOs values. Finally, melting of mixtures of these two enriched and depleted endmembers could explain the Nd-Os isotopic correlations and systematics of shergottites.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE; National Aeronautics and Space Administration (NASA)

Grant/Contract Number:: 89233218CNA000001; 811073

OSTI ID:: 1756828

Report Number(s):: LA-UR-20-24059

Journal Information:: Meteoritics and Planetary Science, Vol. 55, Issue 12; ISSN 1086-9379

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Journal Article · Sat Aug 01 00:00:00 EDT 1987 · Geochim. Cosmochim. Acta; (United States) · OSTI ID:1756828

Bruegmann, G E; Arndt, N T; Hofmann, A W; +1 more

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58 GEOSCIENCES

Title: Mantle–melt partitioning of the highly siderophile elements: New results and application to Mars

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