Colloidal three-dimensional covalent organic frameworks and their application as porous liquids

Mow, Rachel E.; Lipton, Andrew S.; Shulda, Sarah; Gaulding, E. Ashley; Gennett, Thomas; Braunecker, Wade A.

doi:10.1039/d0ta06768g

Title: Colloidal three-dimensional covalent organic frameworks and their application as porous liquids

Journal Article · Tue Nov 03 00:00:00 EST 2020 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d0ta06768g· OSTI ID:1755699

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^[2]; Shulda, Sarah ^[3];

^[3]; Gennett, Thomas ^[1];

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Colorado School of Mines, Golden, CO (United States); National Renewable Energy Lab. (NREL), Golden, CO (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

Developing solid porous materials into free-flowing liquids with permanent porosity is a promising strategy for overcoming certain limitations of conventional sorbent materials employed in gas storage and separation applications. The ability to control the pore size and chemical functionalities of organic frameworks gives these particular nanoporous materials distinct advantages over other small cage-like molecules or hollow particles that have been developed into porous liquids. In this paper, we describe the synthesis of a 3D imine-linked colloidal covalent organic framework (COF)-based porous liquid, designed for efficient size-exclusion of solvent, as well as for long-term stability. By tethering ionic liquids to the colloid surface, the colloids can be dried, purified, and resuspended in a variety of solvents without irreversible aggregation typically observed of COF colloids. Colloid size could be controlled between 50 and 400 nm, with surface areas as high as 800 m² g^–1. The 3D intertwining morphology of the colloids had pore sizes ranging from 5 to 14 Å, allowing them to efficiently size-exclude bulky ionic liquids. The COF colloids were stable towards flocculation in an ionic liquid for >1 year. Permanent porosity was confirmed with a combination of 19F NMR measurements and gas sorption techniques. CO₂ and CH₄ uptake in these porous liquids increased more than 10 and 20-fold, respectively, over non-porous, neat ionic liquid control samples. The work not only advances the state of COF-based colloid science but also represents a practical advance towards developing more robust, tunable framework-based porous liquid materials for a host of gas storage and separation applications.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Fuel Cell Technologies Office; USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1755699

Alternate ID(s):: OSTI ID: 1702362

Report Number(s):: NREL/JA-5900-77341; MainId:26287; UUID:2960b480-1fdb-4284-90b1-6bdd5405a234; MainAdminID:19009

Journal Information:: Journal of Materials Chemistry. A, Vol. 8, Issue 44; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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