Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N2 and H2O

Mukherjee, Shreya; Yang, Xiaoxuan; Shan, Weitao; Samarakoon, Widitha; Karakalos, Stavros; Cullen, David A.; More, Karren; Wang, Maoyu; Feng, Zhenxing; Wang, Guofeng; Wu, Gang

doi:10.1002/smtd.201900821

Title: Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N₂ and H₂O

Journal Article · Wed Feb 05 00:00:00 EST 2020 · Small Methods

DOI:https://doi.org/10.1002/smtd.201900821· OSTI ID:1712715

Mukherjee, Shreya ^[1]; Yang, Xiaoxuan ^[1]; Shan, Weitao ^[2]; Samarakoon, Widitha ^[3]; Karakalos, Stavros ^[4];

^[5];

^[5]; Wang, Maoyu ^[3]; Feng, Zhenxing ^[3]; Wang, Guofeng ^[2];

^[1]

State Univ. of New York (SUNY), Buffalo, NY (United States)
Univ. of Pittsburgh, PA (United States)
Oregon State Univ., Corvallis, OR (United States)
Univ. of South Carolina, Columbia, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Ammonia (NH₃) electrosynthesis gains significant attention as NH₃ is essentially important for fertilizer production and fuel utilization. However, electrochemical nitrogen reduction reaction (NRR) remains a great challenge because of low activity and poor selectivity. Herein, a new class of atomically dispersed Ni site electrocatalyst is reported, which exhibits the optimal NH₃ yield of 115 µg cm^-2 h^-1 at –0.8 V versus reversible hydrogen electrode (RHE) under neutral conditions. High faradic efficiency of 21 ± 1.9% is achieved at -0.2 V versus RHE under alkaline conditions, although the ammonia yield is lower. The Ni sites are stabilized with nitrogen, which is verified by advanced X-ray absorption spectroscopy and electron microscopy. Density functional theory calculations provide insightful understanding on the possible structure of active sites, relevant reaction pathways, and confirm that the Ni-N₃ sites are responsible for the experimentally observed activity and selectivity. Extensive controls strongly suggest that the atomically dispersed NiN₃ site-rich catalyst provides more intrinsically active sites than those in N-doped carbon, instead of possible environmental contamination. Overall, this work further indicates that single-metal site catalysts with optimal nitrogen coordination is very promising for NRR and indeed improves the scaling relationship of transition metals.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC05-00OR22725; 1804534; 1804326; ACI-1053575; AC02‐06CH11357; DE‐AC02‐06CH11357

OSTI ID:: 1712715

Alternate ID(s):: OSTI ID: 1597537

Journal Information:: Small Methods, Vol. 4, Issue 6; ISSN 2366-9608

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 132 works

Citation information provided by
Web of Science

References (74)

Nano-grain dependent 3D hierarchical VS 2 microrods with enhanced intercalation kinetic for sodium storage properties Li, Wenbin; Huang, Jianfeng; Feng, Liangliang Journal of Power Sources, Vol. 398 https://doi.org/10.1016/j.jpowsour.2018.07.036	journal	September 2018
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Ionic Exchange of Metal–Organic Frameworks to Access Single Nickel Sites for Efficient Electroreduction of CO ₂ Zhao, Changming; Dai, Xinyao; Yao, Tao Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b02736	journal	June 2017
Nickel superoxide dismutase: structural and functional roles of Cys2 and Cys6 Ryan, Kelly C.; Johnson, Olivia E.; Cabelli, Diane E. JBIC Journal of Biological Inorganic Chemistry, Vol. 15, Issue 5 https://doi.org/10.1007/s00775-010-0645-y	journal	March 2010
Unveiling Active Sites of CO ₂ Reduction on Nitrogen-Coordinated and Atomically Dispersed Iron and Cobalt Catalysts Pan, Fuping; Zhang, Hanguang; Liu, Kexi ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.8b00398	journal	March 2018
Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN ₄ Sites for Oxygen Reduction Li, Jiazhan; Zhang, Hanguang; Samarakoon, Widitha Angewandte Chemie International Edition, Vol. 58, Issue 52 https://doi.org/10.1002/anie.201909312	journal	November 2019
Facile Ammonia Synthesis from Electrocatalytic N ₂ Reduction under Ambient Conditions on N-Doped Porous Carbon Liu, Yanming; Su, Yan; Quan, Xie ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b02165	journal	January 2018
Single‐Site Gold Catalysts on Hierarchical N‐Doped Porous Noble Carbon for Enhanced Electrochemical Reduction of Nitrogen Qin, Qing; Heil, Tobias; Antonietti, Markus Small Methods, Vol. 2, Issue 12 https://doi.org/10.1002/smtd.201800202	journal	August 2018
Electrochemical ammonia synthesis through N2 and H2O under ambient conditions: Theory, practices, and challenges for catalysts and electrolytes Xu, Hui; Ithisuphalap, Kemakorn; Li, Yi Nano Energy, Vol. 69 https://doi.org/10.1016/j.nanoen.2020.104469	journal	March 2020
Suppression of Hydrogen Evolution Reaction in Electrochemical N ₂ Reduction Using Single-Atom Catalysts: A Computational Guideline Choi, Changhyeok; Back, Seoin; Kim, Na-Young ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b00905	journal	July 2018
Atomically Dispersed Metal Catalysts for Oxygen Reduction Chen, Mengjie; He, Yanghua; Spendelow, Jacob S. ACS Energy Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsenergylett.9b00804	journal	June 2019
Ambient Electrosynthesis of Ammonia: Electrode Porosity and Composition Engineering Wang, Hong; Wang, Lu; Wang, Qiang Angewandte Chemie International Edition, Vol. 57, Issue 38 https://doi.org/10.1002/anie.201805514	journal	July 2018
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Computational Design of Active Site Structures with Improved Transition-State Scaling for Ammonia Synthesis Singh, Aayush R.; Montoya, Joseph H.; Rohr, Brian A. ACS Catalysis, Vol. 8, Issue 5 https://doi.org/10.1021/acscatal.8b00106	journal	March 2018
Achieving a Record-High Yield Rate of 120.9 μgNH3 mgcat.−1 h−1 for N ₂ Electrochemical Reduction over Ru Single-Atom Catalysts Geng, Zhigang; Liu, Yan; Kong, Xiangdong Advanced Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adma.201803498	journal	August 2018
Accurate Molecular Van Der Waals Interactions from Ground-State Electron Density and Free-Atom Reference Data Tkatchenko, Alexandre; Scheffler, Matthias Physical Review Letters, Vol. 102, Issue 7 https://doi.org/10.1103/PhysRevLett.102.073005	journal	February 2009
Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia Suryanto, Bryan H. R.; Du, Hoang-Long; Wang, Dabin Nature Catalysis, Vol. 2, Issue 4 https://doi.org/10.1038/s41929-019-0252-4	journal	March 2019
Photocatalysis and Photoelectrocatalysis Methods of Nitrogen Reduction for Sustainable Ammonia Synthesis Ithisuphalap, Kemakorn; Zhang, Hanguang; Guo, Lin Small Methods, Vol. 3, Issue 6 https://doi.org/10.1002/smtd.201800352	journal	October 2018
Nitrogen-doped porous carbon: highly efficient trifunctional electrocatalyst for oxygen reversible catalysis and nitrogen reduction reaction Yang, Xiaoxuan; Li, Ke; Cheng, Dongming Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/C8TA01078A	journal	January 2018
A physical catalyst for the electrolysis of nitrogen to ammonia Song, Yang; Johnson, Daniel; Peng, Rui Science Advances, Vol. 4, Issue 4 https://doi.org/10.1126/sciadv.1700336	journal	April 2018
Nitrogen-Doped Graphene-Rich Catalysts Derived from Heteroatom Polymers for Oxygen Reduction in Nonaqueous Lithium–O ₂ Battery Cathodes Wu, Gang; Mack, Nathan H.; Gao, Wei ACS Nano, Vol. 6, Issue 11 https://doi.org/10.1021/nn303275d	journal	October 2012
Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells Li, Jiazhan; Chen, Mengjie; Cullen, David A. Nature Catalysis, Vol. 1, Issue 12 https://doi.org/10.1038/s41929-018-0164-8	journal	October 2018
Chemical Activity of the Nitrogenase FeMo Cofactor with a Central Nitrogen Ligand: Density Functional Study Hinnemann, Berit; Nørskov, Jens K. Journal of the American Chemical Society, Vol. 126, Issue 12 https://doi.org/10.1021/ja037792s	journal	March 2004
Spectrophotometric Determination of Ammonia as Indophenol Bolleter, W. T.; Bushman, C. J.; Tidwell, P. W. Analytical Chemistry, Vol. 33, Issue 4 https://doi.org/10.1021/ac60172a034	journal	April 1961
Electronic Structure Martin, Richard M. https://doi.org/10.1017/CBO9780511805769	book	January 2004
Raman spectroscopy as a versatile tool for studying the properties of graphene Ferrari, Andrea C.; Basko, Denis M. Nature Nanotechnology, Vol. 8, Issue 4 https://doi.org/10.1038/nnano.2013.46	journal	April 2013
Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells Wu, Gang; Johnston, Christina M.; Mack, Nathan H. Journal of Materials Chemistry, Vol. 21, Issue 30 https://doi.org/10.1039/c0jm03613g	journal	January 2011
Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO ₂ electroreduction Yan, Chengcheng; Li, Haobo; Ye, Yifan Energy & Environmental Science, Vol. 11, Issue 5 https://doi.org/10.1039/C8EE00133B	journal	January 2018
The Electrolytic Conductances of Sodium Chlorate and of Lithium Chlorate in Water and in Water–Dioxane Campbell, A. N.; Kartzmark, E. M.; Oliver, B. G. Canadian Journal of Chemistry, Vol. 44, Issue 8 https://doi.org/10.1139/v66-135	journal	April 1966
Quaternary FeCoNiMn-Based Nanocarbon Electrocatalysts for Bifunctional Oxygen Reduction and Evolution: Promotional Role of Mn Doping in Stabilizing Carbon Gupta, Shiva; Zhao, Shuai; Wang, Xiao Xia ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02949	journal	November 2017
Raman spectroscopy in graphene Malard, L. M.; Pimenta, M. A.; Dresselhaus, G. Physics Reports, Vol. 473, Issue 5-6, p. 51-87 https://doi.org/10.1016/j.physrep.2009.02.003	journal	April 2009
The Conductance of Hydrochloric Acid in Aqueous Solutions from 5 to 65° Owen, Benton Brooks; Sweeton, Frederick Humphrey Journal of the American Chemical Society, Vol. 63, Issue 10 https://doi.org/10.1021/ja01855a091	journal	October 1941
Self-Consistent Equations Including Exchange and Correlation Effects Kohn, W.; Sham, L. J. Physical Review, Vol. 140, Issue 4A, p. A1133-A1138 https://doi.org/10.1103/PhysRev.140.A1133	journal	November 1965
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites Zhang, Hanguang; Chung, Hoon T.; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/C9EE00877B	journal	January 2019
Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions Zhang, Longzhou; Jia, Yi; Gao, Guoping Chem, Vol. 4, Issue 2 https://doi.org/10.1016/j.chempr.2017.12.005	journal	February 2018
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation Han, Lili; Liu, Xijun; Chen, Jinping Angewandte Chemie International Edition, Vol. 58, Issue 8 https://doi.org/10.1002/anie.201811728	journal	January 2019
Catalytic reduction of dinitrogen to ammonia at well-defined single metal sites Schrock, Richard R. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 363, Issue 1829 https://doi.org/10.1098/rsta.2004.1541	journal	April 2005
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Electrochemical synthesis of ammonia as a potential alternative to the Haber–Bosch process Soloveichik, Grigorii Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0280-0	journal	May 2019
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu Journal of the American Chemical Society, Vol. 139, Issue 40 https://doi.org/10.1021/jacs.7b06514	journal	September 2017
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Atomic-scale cation dynamics in a monolayer VO _X /α-Fe ₂ O ₃ catalyst Feng, Z.; Ma, Q.; Lu, J. RSC Advances, Vol. 5, Issue 126 https://doi.org/10.1039/C5RA18404E	journal	January 2015
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Unravelling the electrochemical mechanisms for nitrogen fixation on single transition metal atoms embedded in defective graphitic carbon nitride Chen, Xingzhu; Zhao, Xiujian; Kong, Zhouzhou Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/C8TA06497K	journal	January 2018
Thin and ultra-thin films of nickel phthalocyanine grown on highly oriented pyrolitic graphite: an XPS, UHV-AFM and air tapping-mode AFM study Ottaviano, L.; Di Nardo, S.; Lozzi, L. Surface Science, Vol. 373, Issue 2-3 https://doi.org/10.1016/S0039-6028(96)01179-X	journal	March 1997
A review of specific conductivities of potassium hydroxide solutions for various concentrations and temperatures Gilliam, R.; Graydon, J.; Kirk, D. International Journal of Hydrogen Energy, Vol. 32, Issue 3 https://doi.org/10.1016/j.ijhydene.2006.10.062	journal	March 2007
Ammonia determination based on indophenol formation with sodium salicylate Verdouw, H.; Van Echteld, C. J. A.; Dekkers, E. M. J. Water Research, Vol. 12, Issue 6 https://doi.org/10.1016/0043-1354(78)90107-0	journal	January 1978
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Ammonia Detection Methods in Photocatalytic and Electrocatalytic Experiments: How to Improve the Reliability of NH ₃ Production Rates? Zhao, Yunxuan; Shi, Run; Bian, Xuanang Advanced Science, Vol. 6, Issue 8 https://doi.org/10.1002/advs.201802109	journal	February 2019
Highly active atomically dispersed CoN ₄ fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy He, Yanghua; Hwang, Sooyeon; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/C8EE02694G	journal	January 2019
Inhomogeneous Electron Gas Hohenberg, P.; Kohn, W. Physical Review, Vol. 136, Issue 3B, p. B864-B871 https://doi.org/10.1103/PhysRev.136.B864	journal	November 1964
In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts Wang, Maoyu; Árnadóttir, Líney; Xu, Zhichuan J. Nano-Micro Letters, Vol. 11, Issue 1 https://doi.org/10.1007/s40820-019-0277-x	journal	June 2019
Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction Wu, Gang; Zelenay, Piotr Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar400011z	journal	April 2013
Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation Perdew, John P.; Chevary, J. A.; Vosko, S. H. Physical Review B, Vol. 46, Issue 11 https://doi.org/10.1103/PhysRevB.46.6671	journal	September 1992
Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction in PEM Fuel Cells: Self-Template Synthesis Approach to Enhancing Catalytic Activity and Stability He, Yanghua; Tan, Qiang; Lu, Leilei Electrochemical Energy Reviews, Vol. 2, Issue 2 https://doi.org/10.1007/s41918-019-00031-9	journal	March 2019
Conversion of Dinitrogen to Ammonia by FeN ₃ -Embedded Graphene Li, Xiao-Fei; Li, Qin-Kun; Cheng, Jin Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04778	journal	July 2016
Fabrication of Superior Single‐Atom Catalysts toward Diverse Electrochemical Reactions Zhang, Bin‐Wei; Wang, Yun‐Xiao; Chou, Shu‐Lei Small Methods, Vol. 3, Issue 9 https://doi.org/10.1002/smtd.201800497	journal	February 2019
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction Yang, Hong Bin; Hung, Sung-Fu; Liu, Song Nature Energy, Vol. 3, Issue 2 https://doi.org/10.1038/s41560-017-0078-8	journal	February 2018
Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes Mukherjee, Shreya; Cullen, David A.; Karakalos, Stavros Nano Energy, Vol. 48 https://doi.org/10.1016/j.nanoen.2018.03.059	journal	June 2018
Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin Advanced Materials, Vol. 30, Issue 11 https://doi.org/10.1002/adma.201706758	journal	January 2018
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode Nørskov, J. K.; Rossmeisl, J.; Logadottir, A. The Journal of Physical Chemistry B, Vol. 108, Issue 46 https://doi.org/10.1021/jp047349j	journal	November 2004
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst Zheng, Tingting; Jiang, Kun; Ta, Na Joule, Vol. 3, Issue 1 https://doi.org/10.1016/j.joule.2018.10.015	journal	January 2019
Understanding the Roles of Nitrogen Configurations in Hydrogen Evolution: Trace Atomic Cobalt Boosts the Activity of Planar Nitrogen-Doped Graphene Wang, Huaixin; Yang, Na; Li, Wei ACS Energy Letters, Vol. 3, Issue 6 https://doi.org/10.1021/acsenergylett.8b00522	journal	May 2018
Iron‐Free Cathode Catalysts for Proton‐Exchange‐Membrane Fuel Cells: Cobalt Catalysts and the Peroxide Mitigation Approach Wang, Xiao Xia; Prabhakaran, Venkateshkumar; He, Yanghua Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201805126	journal	December 2018
Ambient Electrosynthesis of Ammonia: Electrode Porosity and Composition Engineering Wang, Hong; Wang, Lu; Wang, Qiang Angewandte Chemie, Vol. 130, Issue 38 https://doi.org/10.1002/ange.201805514	journal	July 2018
Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN ₄ Sites for Oxygen Reduction Li, Jiazhan; Zhang, Hanguang; Samarakoon, Widitha Angewandte Chemie, Vol. 131, Issue 52 https://doi.org/10.1002/ange.201909312	journal	November 2019
Quantum dissipation driven by electron transfer within a single molecule investigated with atomic force microscopy Berger, Jan; Ondráček, Martin; Stetsovych, Oleksandr Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15054-w	journal	March 2020
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
Ultrafast X-ray Absorption Studies of the Structural Dynamics of Molecular and Biological Systems in Solution Milne, Christopher J.; Van der Veen, Renske M.; Pham, Van-Thai CHIMIA International Journal for Chemistry, Vol. 65, Issue 5 https://doi.org/10.2533/chimia.2011.303	journal	May 2011
Raman spectroscopy as a versatile tool for studying the properties of graphene. Ferrari, Andrea; Basko, Denis M. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.26732	text	January 2013
Atomically Dispersed Molybdenum Catalysts for Efficient Ambient Nitrogen Fixation Han, Lili; Liu, Xijun; Chen, Jinping Angewandte Chemie, Vol. 131, Issue 8 https://doi.org/10.1002/ange.201811728	journal	January 2019
Electronic Structure Martin, Richard M. https://doi.org/10.1017/9781108555586	book	September 2020
Ambient Electro-Synthesis of Ammonia - Electrode Porosity and Composition Engineering Wang, Hong; Wang, Lu; Wang, Qiang arXiv https://doi.org/10.48550/arxiv.1810.13007	text	January 2018

Similar Records

Atomically dispersed single Ni site catalysts for high-efficiency CO₂ electroreduction at industrial-level current densities

Journal Article · Thu Mar 31 00:00:00 EDT 2022 · Energy & Environmental Science · OSTI ID:1712715

Li, Yi; Adli, Nadia Mohd; Shan, Weitao; +9 more

Metal-organic framework-derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N₂ and H₂O in alkaline electrolytes

Journal Article · Fri Mar 23 00:00:00 EDT 2018 · Nano Energy · OSTI ID:1712715

Mukherjee, Shreya; Cullen, David A.; Karakalos, Stavros; +7 more

Atomic Molybdenum for Synthesis of Ammonia with 50% Faradic Efficiency

Journal Article · Sat Mar 12 00:00:00 EST 2022 · Small · OSTI ID:1712715

Zhang, Chenhao; Wang, Zhe; Lei, Jincheng; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
electrocatalysis
electrocatalytic NH3 synthesis
first-principle calculations
metal organic frameworks
single-atom catalysts

Title: Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N2 and H2O

Citation Formats

References (74)

Similar Records

Related Subjects

Title: Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N₂ and H₂O