Design-controlled synthesis of IrO2 sub-monolayers on Au nanoflowers: marrying plasmonic and electrocatalytic properties

de Freitas, Isabel C.; Parreira, Luanna S.; Barbosa, Eduardo M.; Novaes, Barbara A.; Mou, Tong; Alves, Tiago. V.; Quiroz, Jhon; Wang, Yi-Chi; Slater, Thomas J.; Thomas, Andrew; Wang, Bin; Haigh, Sarah J.; Camargo, Pedro C.

doi:10.1039/d0nr01875a

Title: Design-controlled synthesis of IrO₂ sub-monolayers on Au nanoflowers: marrying plasmonic and electrocatalytic properties

Journal Article · Tue Apr 14 00:00:00 EDT 2020 · Nanoscale

DOI:https://doi.org/10.1039/d0nr01875a· OSTI ID:1676421

de Freitas, Isabel C. ^[1]; Parreira, Luanna S. ^[1];

^[1]; Novaes, Barbara A. ^[1]; Mou, Tong ^[2];

^[3]; Quiroz, Jhon ^[4]; Wang, Yi-Chi ^[5]; Slater, Thomas J. ^[6];

^[5];

^[2];

^[5];

^[7]

Univ. of Sao Paulo (Brazil)
Univ. of Oklahoma, Norman, OK (United States)
Univ. Federal da Bahia Rua Barão de Jeremoabo, Salvador (Brazil)
Univ. of Helsinki (Finland)
Univ. of Manchester (United Kingdom)
Univ. of Manchester (United Kingdom); ; Science and Technology Facilities Council (STFC), Oxford (United Kingdom). Diamond Light Source, Ltd.
Univ. of Sao Paulo (Brazil); Univ. of Helsinki (Finland)

We develop herein plasmonic–catalytic Au–IrO₂ nanostructures with a morphology optimized for efficient light harvesting and catalytic surface area; the nanoparticles have a nanoflower morphology, with closely spaced Au branches all partially covered by an ultrathin (1 nm) IrO₂ shell. This nanoparticle architecture optimizes optical features due to the interactions of closely spaced plasmonic branches forming electromagnetic hot spots, and the ultra-thin IrO₂ layer maximizes efficient use of this expensive catalyst. This concept was evaluated towards the enhancement of the electrocatalytic performances towards the oxygen evolution reaction (OER) as a model transformation. The OER can play a central role in meeting future energy demands but the performance of conventional electrocatalysts in this reaction is limited by the sluggish OER kinetics. We demonstrate an improvement of the OER performance for one of the most active OER catalysts, IrO₂, by harvesting plasmonic effects from visible light illumination in multimetallic nanoparticles. We find that the OER activity for the Au–IrO₂ nanoflowers can be improved under LSPR excitation, matching best properties reported in the literature. Our simulations and electrocatalytic data demonstrate that the enhancement in OER activities can be attributed to an electronic interaction between Au and IrO₂ and to the activation of Ir–O bonds by LSPR excited hot holes, leading to a change in the reaction mechanism (rate-determinant step) under visible light illumination.

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Research Organization:: Univ. of Oklahoma, Norman, OK (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); FAPESP; Serrapilheira Institute; Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brazil (CAPES); Engineering and Physical Sciences Resource Council (EPSRC); European Research Council (ERC)

Grant/Contract Number:: SC0020300; 2015/26308-7; 2016/00819-8; 2016/17866-9; 2015/11452-5; Serra-1709-16900; EP/M010619/1; EP/P009050/1; ERC-2016-STG-EvoluTEM-715502

OSTI ID:: 1676421

Journal Information:: Nanoscale, Vol. 12, Issue 23; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Design-controlled synthesis of IrO2 sub-monolayers on Au nanoflowers: marrying plasmonic and electrocatalytic properties

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Title: Design-controlled synthesis of IrO₂ sub-monolayers on Au nanoflowers: marrying plasmonic and electrocatalytic properties