Synthesis of Metallopolymers and Direct Visualization of the Single Polymer Chain

Li, Zhikai; Li, Yiming; Zhao, Yiming; Wang, Heng; Zhang, Yuan; Song, Bo; Li, Xiaohong; Lu, Shuai; Hao, Xin-Qi; Hla, Saw-Wai; Tu, Yingfeng; Li, Xiaopeng

doi:10.1021/jacs.0c00110

Title: Synthesis of Metallopolymers and Direct Visualization of the Single Polymer Chain

Journal Article · Mon Mar 09 00:00:00 EDT 2020 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.0c00110· OSTI ID:1664386

Li, Zhikai ^[1]; Li, Yiming ^[2]; Zhao, Yiming ^[3]; Wang, Heng ^[2]; Zhang, Yuan ^[4];

^[2];

^[3]; Lu, Shuai ^[5];

^[6]; Hla, Saw-Wai ^[7];

^[3];

^[2]

Soochow Univ., Suzhou (China); Univ. of South Florida, Tampa, FL (United States)
Univ. of South Florida, Tampa, FL (United States)
Soochow Univ., Suzhou (China)
Argonne National Lab. (ANL), Argonne, IL (United States); Old Dominion Univ., Norfolk, VA (United States)
Univ. of South Florida, Tampa, FL (United States); Zhengzhou Univ. (China)
Zhengzhou Univ. (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

During the past few decades, the study of the single polymer chain has attracted considerable attention with the goal of exploring the structure-property relationship of polymers. It still, however, remains challenging due to the variability and low atomic resolution of the amorphous single polymer chain. In this study, we demonstrated a new strategy to visualize the single metallopolymer chain with a hexameric or trimeric supramolecule as a repeat unit, in which Ru(II) with strong coordination and Fe(II) with weak coordination were combined together in a stepwise manner. With the help of ultrahigh-vacuum, low-temperature scanning tunneling microscopy (UHV-LT-STM) and scanning tunneling spectroscopy (STS), we were able to directly visualize both Ru(II) and Fe(II), which act as staining reagents on the repeat units, thus providing detailed structural information for the single polymer chain. As such, the direct visualization of the single random polymer chain is realized to enhance the characterization of polymers at the single-molecule level.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Institutes of Health (NIH); National Science Foundation of China

Grant/Contract Number:: AC02-06CH11357; R01GM128037; 21774090

OSTI ID:: 1664386

Journal Information:: Journal of the American Chemical Society, Vol. 142, Issue 13; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Facile thermodynamic conversion of a linear metallopolymer into a self-assembled hexameric metallomacrocycle Li, Yiming; Jiang, Zhilong; Yuan, Jie Chemical Communications, Vol. 51, Issue 26 https://doi.org/10.1039/C4CC10361K	journal	January 2015
Combining Synthesis and Self-Assembly in One Pot To Construct Complex 2D Metallo-Supramolecules Using Terpyridine and Pyrylium Salts Wang, Heng; Li, Yiming; Yu, Hao Journal of the American Chemical Society, Vol. 141, Issue 33 https://doi.org/10.1021/jacs.9b05682	journal	July 2019
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Scanning tunneling microscopy study of the quasicrystalline 30° twisted bilayer graphene Yan, Chao; Ma, Dong-Lin; Qiao, Jia-Bin 2D Materials, Vol. 6, Issue 4 https://doi.org/10.1088/2053-1583/ab3b16	journal	September 2019
Scanning-Tunneling-Microscope Observation of the Abrikosov Flux Lattice and the Density of States near and inside a Fluxoid Hess, H. F.; Robinson, R. B.; Dynes, R. C. Physical Review Letters, Vol. 62, Issue 2 https://doi.org/10.1103/PhysRevLett.62.214	journal	January 1989

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