Thermally stable cross-linked P84 with superior membrane H2/CO2 separation properties at 100 °C

Omidvar, Maryam; Stafford, Christopher M.; Lin, Haiqing

doi:10.1016/j.memsci.2019.01.003

Title: Thermally stable cross-linked P84 with superior membrane H₂/CO₂ separation properties at 100 °C

Journal Article · Sun Jan 06 00:00:00 EST 2019 · Journal of Membrane Science

DOI:https://doi.org/10.1016/j.memsci.2019.01.003· OSTI ID:1659661

Omidvar, Maryam ^[1]; Stafford, Christopher M. ^[2]; Lin, Haiqing ^[1]

Univ. at Buffalo, NY (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)

Polymers with a strong size-sieving ability and superior H₂/CO₂ selectivity at 100 °C or above are of great interests for pre-combustion CO₂ capture. Polyimides (such as Matrimid and 6FDA-durene) have been cross-linked using diamines and show superior H₂/CO₂ selectivity. However, these cross-linked polymers cannot be used for the pre-combustion CO₂ capture because of the lack of thermal stability at 100 °C. As such, herein we demonstrate that commercial P84™ can be chemically cross-linked using 1,4-butanediamine (BuDA) to achieve robust H₂/CO₂ separation properties at 100–150 °C. The cross-linked P84 were thoroughly evaluated using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The effects of the cross-linking time on the physical properties and H₂/CO₂ separation properties at various temperatures were determined and interpreted using a free volume model. An exemplary sample based on P84 cross-linked by BuDA for 6 h exhibits a H₂ permeability of 47 Barrers (1 Barrer = 3.35 × 10^–16 mol m/m² s Pa) and H₂/CO₂ selectivity of 14 at 100 °C, which is on the Robeson's upper bound, indicating their potential for practical applications.

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Research Organization:: Univ. at Buffalo, NY (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)

Grant/Contract Number:: FE0026463; 1554236

OSTI ID:: 1659661

Journal Information:: Journal of Membrane Science, Vol. 575; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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