Anisotropic magnetocaloric effect and critical behavior in CrSbSe3

Liu, Yu; Hu, Zhixiang; Petrovic, C.

doi:10.1103/physrevb.102.014425

Title: Anisotropic magnetocaloric effect and critical behavior in CrSbSe3

Journal Article · Wed Jul 15 00:00:00 EDT 2020 · Physical Review B

DOI:https://doi.org/10.1103/physrevb.102.014425· OSTI ID:1647004

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Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.; Stony Brook Univ., NY (United States)

In this work, we report anisotropic magnetocaloric effect and critical behavior in a quasi-one-dimensional ferromagnetic ${CrSbSe}_{3}$ single crystal. The maximum magnetic entropy change $- Δ S_{M}^{\max}$ is 2.16 J ${kg}^{- 1} K^{- 1}$ for the easy $a$ axis (2.03 J ${kg}^{- 1} K^{- 1}$ for the hard $b$ axis) and the relative cooling power RCP is 163.1 J ${kg}^{- 1}$ for the easy $a$ axis (142.1 J ${kg}^{- 1}$ for the hard $b$ axis) near $T_{c}$ with a magnetic field change of 50 kOe. The magnetocrystalline anisotropy constant $K_{u}$ is estimated to be 148.5 kJ $m^{- 3}$ at 10 K, decreasing to 39.4 kJ $m^{- 3}$ at 70 K. The rescaled $Δ S_{M} (T, H)$ curves along all three axes collapse onto a universal curve, respectively, confirming the second-order ferromagnetic transition. Further critical behavior analysis around $T_{c} ~ 70 K$ gives that the critical exponents $β = 0.26 (1)$ , $γ = 1.32 (2)$ , and $δ = 6.17 (9)$ for $H ∥ a$ , while $β = 0.28 (2)$ , $γ = 1.02 (1)$ , and $δ = 4.14 (16)$ for $H ∥ b$ . The determined critical exponents suggest that the anisotropic magnetic coupling in ${CrSbSe}_{3}$ is strongly dependent on orientations of the applied magnetic field.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1647004

Report Number(s):: BNL-216245-2020-JAAM; TRN: US2202679

Journal Information:: Physical Review B, Vol. 102, Issue 1; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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