High-Pressure Synthesis of Metal–Inorganic Frameworks Hf4N20·N2, WN8·N2, and Os5N28·3 N2 with Polymeric Nitrogen Linkers

Bykov, Maxim; Chariton, Stella; Bykova, Elena; Khandarkhaeva, Saiana; Fedotenko, Timofey; Ponomareva, Alena V.; Tidholm, Johan; Tasnádi, Ferenc; Abrikosov, Igor A.; Sedmak, Pavel; Prakapenka, Vitali; Hanfland, Michael; Liermann, Hanns‐Peter; Mahmood, Mohammad; Goncharov, Alexander F.; Dubrovinskaia, Natalia; Dubrovinsky, Leonid

doi:10.1002/anie.202002487

Title: High-Pressure Synthesis of Metal–Inorganic Frameworks Hf₄N₂₀·N₂, WN₈·N₂, and Os₅N₂₈·3 N₂ with Polymeric Nitrogen Linkers

Journal Article · Tue Mar 24 00:00:00 EDT 2020 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202002487· OSTI ID:1646607

^[1]; Chariton, Stella ^[2]; Bykova, Elena ^[3]; Khandarkhaeva, Saiana ^[4]; Fedotenko, Timofey ^[5]; Ponomareva, Alena V. ^[6]; Tidholm, Johan ^[7]; Tasnádi, Ferenc ^[7]; Abrikosov, Igor A. ^[7]; Sedmak, Pavel ^[8]; Prakapenka, Vitali ^[2];

^[8]; Liermann, Hanns‐Peter ^[9]; Mahmood, Mohammad ^[10]; Goncharov, Alexander F. ^[3];

^[11];

^[4]

Howard Univ., Washington, DC (United States). Dept. of Mathematics; Univ. of Bayreuth (Germany). Bayerisches Geoinstitut; Carnegie Institution for Science, Washington, DC (United States). The Earth and Planets Lab.
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources
Carnegie Institution for Science, Washington, DC (United States). The Earth and Planets Lab.
Univ. of Bayreuth (Germany). Bayerisches Geoinstitut
Univ. of Bayreuth (Germany). Material Physics and Technology at Extreme Conditions. Lab. of Crystallography
National Univ. of Science and Technology “MISIS”, Moscow (Russian Federation). Materials Modeling and Development Lab.
Linköping Univ. (Sweden). Dept. of Physics, Chemistry and Biology
European Synchrotron Radiation Facility (ESRF), Grenoble (France)
Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany). Photon Science
Howard Univ., Washington, DC (United States). Dept. of Mathematics
Univ. of Bayreuth (Germany). Material Physics and Technology at Extreme Conditions. Lab. of Crystallography; Linköping Univ. (Sweden). Dept. of Physics, Chemistry and Biology

Polynitrides are intrinsically thermodynamically unstable at ambient conditions and require peculiar synthetic approaches. Now, a one-step synthesis of metal–inorganic frameworks Hf₄N₂₀·N₂, WN₈·N₂, and Os₅N₂₈·3 N₂ via direct reactions between elements in a diamond anvil cell at pressures exceeding 100 GPa is reported. The porous frameworks (Hf₄N₂₀, WN₈, and Os₅N₂₈) are built from transition-metal atoms linked either by polymeric polydiazenediyl (polyacetylene-like) nitrogen chains or through dinitrogen units. Triply bound dinitrogen molecules occupy channels of these frameworks. Owing to conjugated polydiazenediyl chains, these compounds exhibit metallic properties. The high-pressure reaction between Hf and N₂ also leads to a non-centrosymmetric polynitride Hf₂N₁₁ that features double-helix catena-poly[tetraz-1-ene-1,4-diyl] nitrogen chains [–N–N–N=N–]_∞.

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Research Organization:: Univ. of Chicago, IL (United States); Howard Univ., Washington, DC (United States); Univ. of Bayreuth (Germany); National Univ. of Science and Technology “MISIS”, Moscow (Russian Federation); Linköping Univ. (Sweden)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); US Army Research Office (ARO); German Research Foundation (DFG); German Federal Ministry of Education and Research (BMBF); Russian Science Foundation; Swedish Government Strategic Research Area in Materials Science on Functional Materials; Knut and Alice Wallenberg Foundation (Sweden); Swedish Research Council (VR)

Grant/Contract Number:: FG02-94ER14466; EAR-1634415; W911NF-19-2-0172; DU 954-11/1; DU 393-9/2; DU 393-13/1; 05K19WC1; 18-12-00492; 2009 00971; KAW-2018.0194; 2019-05600; 2016-05156

OSTI ID:: 1646607

Journal Information:: Angewandte Chemie (International Edition), Vol. 59, Issue 26; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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CSD 1978265: Experimental Crystal Structure Determination Maxim, Bykov,; Stella, Chariton,; Elena, Bykova, https://doi.org/10.25505/fiz.icsd.cc24dk04 The current record is supplemented by this dataset	dataset	January 2020
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Title: High-Pressure Synthesis of Metal–Inorganic Frameworks Hf4N20·N2, WN8·N2, and Os5N28·3 N2 with Polymeric Nitrogen Linkers

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