skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: New intrinsic mechanism on gum-like superelasticity of multifunctional alloys

Journal Article · · Scientific Reports
DOI:https://doi.org/10.1038/srep02156· OSTI ID:1624631
 [1];  [2];  [3];  [4];  [5];  [4];  [6];  [2];  [7];  [3];  [2];  [7];  [7];  [3]
  1. Univ. of Science and Technology, Beijing (China). State key Lab. for Advanced Metals and Materials; Beijing Inst. of Technology, Beijing (China). School of Materials Science and Engineering
  2. Univ. of Science and Technology, Beijing (China). State key Lab. for Advanced Metals and Materials
  3. Chinese Academy of Sciences (CAS), Shenyang (China). Inst. of Metal Research. Shenyang National Lab. for Materials Science
  4. The Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering; Xi'an Jiaotong Univ., Shaanxi (China). State Key lab. for Mechanical Behavior of Materials. Frontier Inst. of Science and Technology
  5. Beijing Inst. of Technology, Beijing (China). School of Materials Science and Engineering
  6. Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
  7. Univ. of Texas at Dallas, Richardson, TX (United States). Dept. of Materials Science and Engineering

Ti-Nb-based Gum Metals exhibit extraordinary superelasticity with ultralow elastic modulus, superior strength and ductility, and a peculiar dislocation-free deformation behavior, most of which challenge existing theories of crystal strength. Additionally, this kind of alloys actually displays even more anomalous mechanical properties, such as the non-linear superelastic behavior, accompanied by a pronounced tension-to-compression asymmetry, and large ductility with a low Poisson’s ratio. Two main contradictory arguments exist concerning the deformation mechanisms of those alloys, i.e., formation of reversible nanodisturbance and reversible martensitic transformation. Herein we used the in-situ synchrotron high-energy X-ray scattering technique to reveal the novel intrinsic physical origin of all anomalous mechanical properties of the Ti-24Nb-4Zr-8Sn-0.10O alloy, a typical gum-like metal. Our experiments provide direct evidence on two different kinds of interesting, stress-induced, reversible nanoscale martensitic transitions, i.e., the austenitic regions with B2 structure transform to a0 martensite and those with BCC structure transform to d martensite.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1624631
Journal Information:
Scientific Reports, Vol. 3, Issue 1; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (21)

Ductile and brittle crystals journal March 1967
Poisson's ratio and modern materials journal October 2011
Multifunctional Alloys Obtained via a Dislocation-Free Plastic Deformation Mechanism journal April 2003
Nanodisturbances in deformed Gum Metal journal May 2006
First-principles calculations for development of low elastic modulus Ti alloys journal November 2004
Study of the nanostructure of Gum Metal using energy-filtered transmission electron microscopy journal January 2009
“Ideal” Engineering Alloys journal March 2007
Evolution of deformation mechanisms of Ti–22.4Nb–0.73Ta–2Zr–1.34O alloy during straining journal April 2010
Stress-introduced α″ martensite and twinning in a multifunctional titanium alloy journal January 2008
Anomalous transformation-induced deformation in 〈110〉 textured Gum Metal journal May 2010
On the mechanism of superelasticity in Gum metal journal February 2009
Elastic properties of Ti–24Nb–4Zr–8Sn single crystals with bcc crystal structure journal May 2011
Tracing Memory in Polycrystalline Ferromagnetic Shape-Memory Alloys journal September 2006
The effect of oxygen on α″ martensite and superelasticity in Ti–24Nb–4Zr–8Sn journal January 2011
Lattice modulation and superelasticity in oxygen-added β-Ti alloys journal September 2011
From chessboard tweed to chessboard nanowire structure during pseudospinodal decomposition journal April 2009
Evidence for Strain Glass in the Ferroelastic-Martensitic System Ti 50 x Ni 50 + x journal November 2005
Coherent structural transformations in random crystalline systems journal October 1997
Three-dimensional field model and computer modeling of martensitic transformations journal February 1997
Modeling Abnormal Strain States in Ferroelastic Systems: The Role of Point Defects journal November 2010
Superfunctionalities in Nanodispersive Precipitation-Hardened Alloys journal September 2012

Cited By (4)

The Role of Nano-domains in {1–011} Twinned Martensite in Metastable Titanium Alloys journal August 2018
Tailoring superelasticity of soft magnetic materials journal October 2015
From Porous to Dense Nanostructured β-Ti alloys through High-Pressure Torsion journal October 2017
Guided Self-Assembly of Nano-Precipitates into Mesocrystals journal November 2015