Grain detachment and transport clogging during mineral dissolution in carbonate rocks with permeable grain boundaries

Liu, Min; Starchenko, Vitalii; Anovitz, Lawrence M.; Stack, Andrew G.

doi:10.1016/j.gca.2020.04.022

Title: Grain detachment and transport clogging during mineral dissolution in carbonate rocks with permeable grain boundaries

Journal Article · Mon Apr 27 00:00:00 EDT 2020 · Geochimica et Cosmochimica Acta

DOI:https://doi.org/10.1016/j.gca.2020.04.022· OSTI ID:1619024

^[1];

^[2];

^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

In this paper, we explore the effect of permeable grain boundaries on carbonate rock dissolution in order to improve our understanding of grain detachment and migration during reactive flow. To do so we investigated the effects of grain size and enhanced reactivity along grain boundaries on global dissolution kinetics. Variations of permeability and porosity were calculated, and exponential relationships were observed in fractured rocks. Our model employed a reactive transport framework based on the Darcy-Brinkman equation to simulate calcite dissolution in carbonate rocks composed of microporous grains and, included fluid transport along grain boundaries. The model includes fluid flow, solute transport by advection–diffusion, heterogeneous reaction between fluid and minerals and grain detachment with subsequent grain transport in macropores. The migration of solid particles due to dissolution was based on cluster analysis and local movement, and the results show that grain detachment can lead to significant decreases in permeability due to the clogging of transport pathways. Microporous media with smaller grain sizes (fine grains in this study) showed a higher average reaction rate than those with coarser grains. In addition, as the overall rates of geochemical processes are commonly affected by the presence of texture heterogeneities such as fractures, a single fracture (macropore) introduced into a microporous matrix composed of permeable grains and grain boundaries was modelled as a large channel connecting the inlet and outlet of the simulation domain. It was found that macropore clogging by grain detachment temporary decreased permeability, lowering the long-term global reaction rates. Lastly, we observed that increases in flow rate can reduce detachment and fracture clogging by reducing local dissolution along grain boundaries.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC05-00OR22725; 89233218CNA000001

OSTI ID:: 1619024

Alternate ID(s):: OSTI ID: 1645082; OSTI ID: 1775799

Report Number(s):: LA-UR-19-23804

Journal Information:: Geochimica et Cosmochimica Acta, Vol. 280, Issue C; ISSN 0016-7037

Publisher:: Elsevier; The Geochemical Society; The Meteoritical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 7 works

Citation information provided by
Web of Science

References (75)

Pore-Network Modeling Dedicated to the Determination of the Petrophysical-Property Changes in the Presence of Reactive Fluid Algive, Lionnel; Bekri, Samir; Vizika, Olga SPE Journal, Vol. 15, Issue 03 https://doi.org/10.2118/124305-PA	journal	September 2010
A new approach to quantification of metamorphism using ultra-small and small angle neutron scattering Anovitz, Lawrence M.; Lynn, Gary W.; Cole, David R. Geochimica et Cosmochimica Acta, Vol. 73, Issue 24, p. 7303-7324 https://doi.org/10.1016/j.gca.2009.07.040	journal	December 2009
Impact of phase saturation on wormhole formation in rock matrix acidizing Babaei, Masoud; Sedighi, Majid Chemical Engineering Science, Vol. 177 https://doi.org/10.1016/j.ces.2017.10.046	journal	February 2018
Pore-scale imaging and modelling Blunt, Martin J.; Bijeljic, Branko; Dong, Hu Advances in Water Resources, Vol. 51 https://doi.org/10.1016/j.advwatres.2012.03.003	journal	January 2013
The effect of pH, grain size, and organic ligands on biotite weathering rates Bray, Andrew W.; Oelkers, Eric H.; Bonneville, Steeve Geochimica et Cosmochimica Acta, Vol. 164 https://doi.org/10.1016/j.gca.2015.04.048	journal	September 2015
A calculation of the viscous force exerted by a flowing fluid on a dense swarm of particles Brinkman, H. C. Flow, Turbulence and Combustion, Vol. 1, Issue 1 https://doi.org/10.1007/BF02120313	journal	December 1949
The role of pe, pH, and carbonate on the solubility of UO2 and uraninite under nominally reducing conditions Casas, Ignasi; de Pablo, Joan; Giménez, Javier Geochimica et Cosmochimica Acta, Vol. 62, Issue 13 https://doi.org/10.1016/S0016-7037(98)00140-9	journal	July 1998
Porosity and pore size distribution of deeply-buried fine-grained rocks: Influence of diagenetic and metamorphic processes on shale reservoir quality and exploration Chalmers, Gareth R. L.; Bustin, R. Marc Journal of Unconventional Oil and Gas Resources, Vol. 12 https://doi.org/10.1016/j.juogr.2015.09.005	journal	December 2015
Pore-scale simulation of multicomponent multiphase reactive transport with dissolution and precipitation Chen, Li; Kang, Qinjun; Tang, Qing International Journal of Heat and Mass Transfer, Vol. 85 https://doi.org/10.1016/j.ijheatmasstransfer.2015.02.035	journal	June 2015
Wellbore Cement Porosity Evolution in Response to Mineral Alteration during CO ₂ Flooding Cheshire, Michael C.; Stack, Andrew G.; Carey, J. William Environmental Science & Technology, Vol. 51, Issue 1 https://doi.org/10.1021/acs.est.6b03290	journal	December 2016
Carbonate Acidizing: Toward a Quantitative Model of the Wormholing Phenomenon Daccord, G.; Touboul, E.; Lenormand, R. SPE Production Engineering, Vol. 4, Issue 01 https://doi.org/10.2118/16887-PA	journal	February 1989
The oxidative dissolution mechanism of uranium dioxide. I. The effect of temperature in hydrogen carbonate medium Pablo, Joan de; Casas, Ignasi; Giménez, Javier Geochimica et Cosmochimica Acta, Vol. 63, Issue 19-20, p. 3097-3103 https://doi.org/10.1016/S0016-7037(99)00237-9	journal	October 1999
Alterations of Fractures in Carbonate Rocks by CO ₂ -Acidified Brines Deng, Hang; Fitts, Jeffrey P.; Crandall, Dustin Environmental Science & Technology, Vol. 49, Issue 16 https://doi.org/10.1021/acs.est.5b01980	journal	August 2015
A 2.5D Reactive Transport Model for Fracture Alteration Simulation Deng, Hang; Molins, Sergi; Steefel, Carl Environmental Science & Technology, Vol. 50, Issue 14 https://doi.org/10.1021/acs.est.6b02184	journal	July 2016
Pore-scale numerical investigation of the impacts of surface roughness: Upscaling of reaction rates in rough fractures Deng, Hang; Molins, Sergi; Trebotich, David Geochimica et Cosmochimica Acta, Vol. 239 https://doi.org/10.1016/j.gca.2018.08.005	journal	October 2018
Fracture Evolution in Multimineral Systems: The Role of Mineral Composition, Flow Rate, and Fracture Aperture Heterogeneity Deng, Hang; Steefel, Carl; Molins, Sergi ACS Earth and Space Chemistry, Vol. 2, Issue 2 https://doi.org/10.1021/acsearthspacechem.7b00130	journal	January 2018
Alteration and Erosion of Rock Matrix Bordering a Carbonate-Rich Shale Fracture Deng, Hang; Voltolini, Marco; Molins, Sergi Environmental Science & Technology, Vol. 51, Issue 15 https://doi.org/10.1021/acs.est.7b02063	journal	July 2017
Principles of Early Development of Karst Conduits Under Natural and Man-Made Conditions Revealed by Mathematical Analysis of Numerical Models Dreybrodt, Wolfgang Water Resources Research, Vol. 32, Issue 9 https://doi.org/10.1029/96WR01332	journal	April 1996
Time-dependent shapes of a dissolving mineral grain: Comparisons of simulations with microfluidic experiments Dutka, Filip; Starchenko, Vitaliy; Osselin, Florian Chemical Geology, Vol. 540 https://doi.org/10.1016/j.chemgeo.2019.119459	journal	May 2020
Dissolution and deformation in fractured carbonates caused by flow of CO2-rich brine under reservoir conditions Elkhoury, Jean E.; Ameli, Pasha; Detwiler, Russell L. International Journal of Greenhouse Gas Control, Vol. 16 https://doi.org/10.1016/j.ijggc.2013.02.023	journal	June 2013
Mechanisms influencing micron and nanometer-scale reaction rate patterns during dolostone dissolution Emmanuel, Simon Chemical Geology, Vol. 363 https://doi.org/10.1016/j.chemgeo.2013.11.002	journal	January 2014
Effects of Coupled Chemo-Mechanical Processes on the Evolution of Pore-Size Distributions in Geological Media Emmanuel, Simon; Anovitz, Lawrence M.; Day-Stirrat, Ruarri J. Reviews in Mineralogy and Geochemistry, Vol. 80, Issue 1 https://doi.org/10.2138/rmg.2015.03	journal	January 2015
Limestone weathering rates accelerated by micron-scale grain detachment Emmanuel, Simon; Levenson, Yael Geology, Vol. 42, Issue 9 https://doi.org/10.1130/G35815.1	journal	September 2014
O and H diffusion in uraninite: Implications for fluid–uraninite interactions, nuclear waste disposal, and nuclear forensics Fayek, Mostafa; Anovitz, Lawrence M.; Cole, David R. Geochimica et Cosmochimica Acta, Vol. 75, Issue 13 https://doi.org/10.1016/j.gca.2011.03.040	journal	July 2011
Three-Dimensional Pore-Scale Modeling of Fracture Evolution in Heterogeneous Carbonate Caprock Subjected to CO ₂ -Enriched Brine Fazeli, Hossein; Patel, Ravi A.; Ellis, Brian R. Environmental Science & Technology, Vol. 53, Issue 8 https://doi.org/10.1021/acs.est.8b05653	journal	March 2019
The kinetics of calcite dissolution in acetic acid solutions Fredd, Christopher N.; Scott Fogler, H. Chemical Engineering Science, Vol. 53, Issue 22 https://doi.org/10.1016/S0009-2509(98)00192-4	journal	November 1998
Anti-correlated Porosity–Permeability Changes During the Dissolution of Carbonate Rocks: Experimental Evidences and Modeling Garing, C.; Gouze, P.; Kassab, M. Transport in Porous Media, Vol. 107, Issue 2 https://doi.org/10.1007/s11242-015-0456-2	journal	January 2015
Carbonate acidizing: Modeling, analysis, and characterization of wormhole formation and propagation Ghommem, Mehdi; Zhao, Weishu; Dyer, Steve Journal of Petroleum Science and Engineering, Vol. 131 https://doi.org/10.1016/j.petrol.2015.04.021	journal	July 2015
Mass transfer and problems of secondary porosity creation in deeply buried hydrocarbon reservoirs Giles, M. R. Marine and Petroleum Geology, Vol. 4, Issue 3 https://doi.org/10.1016/0264-8172(87)90044-4	journal	August 1987
Influence of aperture variability on dissolutional growth of fissures in Karst Formations Hanna, R. Blair; Rajaram, Harihar Water Resources Research, Vol. 34, Issue 11 https://doi.org/10.1029/98WR01528	journal	November 1998
Kinetic modeling of nitrous oxide decomposition on Fe-ZSM-5 based on parameters obtained from first-principles calculations Heyden, A.; Bell, A.; Keil, F. Journal of Catalysis, Vol. 233, Issue 1 https://doi.org/10.1016/j.jcat.2005.04.003	journal	July 2005
Percolation and cluster distribution. I. Cluster multiple labeling technique and critical concentration algorithm Hoshen, J.; Kopelman, R. Physical Review B, Vol. 14, Issue 8 https://doi.org/10.1103/PhysRevB.14.3438	journal	October 1976
Impact of grain size and rock composition on simulated rock weathering Israeli, Yoni; Emmanuel, Simon Earth Surface Dynamics, Vol. 6, Issue 2 https://doi.org/10.5194/esurf-6-319-2018	journal	January 2018
Pore-scale study of dissolution-induced changes in permeability and porosity of porous media Kang, Qinjun; Chen, Li; Valocchi, Albert J. Journal of Hydrology, Vol. 517 https://doi.org/10.1016/j.jhydrol.2014.06.045	journal	September 2014
Pore Scale Modeling of Reactive Transport Involved in Geologic CO2 Sequestration Kang, Qinjun; Lichtner, Peter C.; Viswanathan, Hari S. Transport in Porous Media, Vol. 82, Issue 1 https://doi.org/10.1007/s11242-009-9443-9	journal	July 2009
Simulation of dissolution and precipitation in porous media: DISSOLUTION AND PRECIPITATION IN POROUS MEDIA Kang, Qinjun; Zhang, Dongxiao; Chen, Shiyi Journal of Geophysical Research: Solid Earth, Vol. 108, Issue B10 https://doi.org/10.1029/2003JB002504	journal	October 2003
Lattice Boltzmann simulation of chemical dissolution in porous media Kang, Qinjun; Zhang, Dongxiao; Chen, Shiyi Physical Review E, Vol. 65, Issue 3 https://doi.org/10.1103/PhysRevE.65.036318	journal	March 2002
The structure of reactive grain-boundaries under stress containing confined fluids Koehn, D.; Malthe-Sørenssen, A.; Passchier, C. W. Chemical Geology, Vol. 230, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2006.02.026	journal	June 2006
Insights into rates of fracture growth and sealing from a model for quartz cementation in fractured sandstones Lander, R. H.; Laubach, S. E. Geological Society of America Bulletin, Vol. 127, Issue 3-4 https://doi.org/10.1130/B31092.1	journal	October 2014
Coupled reaction-flow modeling of diagenetic changes in reservoir permeability, porosity and mineral compositions Le Gallo, Y.; Bildstein, O.; Brosse, E. Journal of Hydrology, Vol. 209, Issue 1-4 https://doi.org/10.1016/S0022-1694(98)00183-8	journal	August 1998
Quantifying micron-scale grain detachment during weathering experiments on limestone Levenson, Yael; Emmanuel, Simon Geochimica et Cosmochimica Acta, Vol. 173 https://doi.org/10.1016/j.gca.2015.10.024	journal	January 2016
Pore-scale heterogeneous reaction rates on a dissolving limestone surface Levenson, Yael; Emmanuel, Simon Geochimica et Cosmochimica Acta, Vol. 119 https://doi.org/10.1016/j.gca.2013.05.024	journal	October 2013
High-resolution pore-scale simulation of dissolution in porous media Liu, Min; Mostaghimi, Peyman Chemical Engineering Science, Vol. 161 https://doi.org/10.1016/j.ces.2016.12.064	journal	April 2017
Pore-scale modelling of CO 2 storage in fractured coal Liu, Min; Mostaghimi, Peyman International Journal of Greenhouse Gas Control, Vol. 66 https://doi.org/10.1016/j.ijggc.2017.09.007	journal	November 2017
Numerical simulation of fluid-fluid-solid reactions in porous media Liu, Min; Mostaghimi, Peyman International Journal of Heat and Mass Transfer, Vol. 120 https://doi.org/10.1016/j.ijheatmasstransfer.2017.11.141	journal	May 2018
Impact of mineralogical heterogeneity on reactive transport modelling Liu, Min; Shabaninejad, Mehdi; Mostaghimi, Peyman Computers & Geosciences, Vol. 104 https://doi.org/10.1016/j.cageo.2017.03.020	journal	July 2017
Predictions of permeability, surface area and average dissolution rate during reactive transport in multi-mineral rocks Liu, Min; Shabaninejad, Mehdi; Mostaghimi, Peyman Journal of Petroleum Science and Engineering, Vol. 170 https://doi.org/10.1016/j.petrol.2018.06.010	journal	November 2018
Morphology, Genesis, and Distribution of Nanometer-Scale Pores in Siliceous Mudstones of the Mississippian Barnett Shale Loucks, R. G.; Reed, R. M.; Ruppel, S. C. Journal of Sedimentary Research, Vol. 79, Issue 12 https://doi.org/10.2110/jsr.2009.092	journal	November 2009
Experimental determination of porosity and permeability changes induced by injection of CO2 into carbonate rocks Luquot, L.; Gouze, P. Chemical Geology, Vol. 265, Issue 1-2 https://doi.org/10.1016/j.chemgeo.2009.03.028	journal	July 2009
Experimental Characterization of Porosity Structure and Transport Property Changes in Limestone Undergoing Different Dissolution Regimes Luquot, L.; Rodriguez, O.; Gouze, P. Transport in Porous Media, Vol. 101, Issue 3 https://doi.org/10.1007/s11242-013-0257-4	journal	February 2014
Dynamic reservoir-condition microtomography of reactive transport in complex carbonates: Effect of initial pore structure and initial brine pH Menke, H. P.; Bijeljic, B.; Blunt, M. J. Geochimica et Cosmochimica Acta, Vol. 204 https://doi.org/10.1016/j.gca.2017.01.053	journal	May 2017
Dynamic Three-Dimensional Pore-Scale Imaging of Reaction in a Carbonate at Reservoir Conditions Menke, Hannah P.; Bijeljic, Branko; Andrew, Matthew G. Environmental Science & Technology, Vol. 49, Issue 7 https://doi.org/10.1021/es505789f	journal	March 2015
Mineralogical and transport controls on the evolution of porous media texture using direct numerical simulation: CONTROLS ON TEXTURE EVOLUTION Molins, Sergi; Trebotich, David; Miller, Gregory H. Water Resources Research, Vol. 53, Issue 5 https://doi.org/10.1002/2016WR020323	journal	May 2017
Simulation of mineral dissolution at the pore scale with evolving fluid-solid interfaces: review of approaches and benchmark problem set Molins, Sergi; Soulaine, Cyprien; Prasianakis, Nikolaos I. Computational Geosciences https://doi.org/10.1007/s10596-019-09903-x	journal	January 2020
The dissolution kinetics of major sedimentary carbonate minerals Morse, John W.; Arvidson, Rolf S. Earth-Science Reviews, Vol. 58, Issue 1-2 https://doi.org/10.1016/S0012-8252(01)00083-6	journal	July 2002
Numerical Simulation of Reactive Transport on Micro-CT Images Mostaghimi, Peyman; Liu, Min; Arns, Christoph H. Mathematical Geosciences, Vol. 48, Issue 8 https://doi.org/10.1007/s11004-016-9640-3	journal	July 2016
Evolution of planar fractures in limestone: The role of flow rate, mineral heterogeneity and local transport processes Noiriel, Catherine; Deng, Hang Chemical Geology, Vol. 497 https://doi.org/10.1016/j.chemgeo.2018.08.026	journal	October 2018
Deciphering pore-level precipitation mechanisms Prasianakis, N. I.; Curti, E.; Kosakowski, G. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-14142-0	journal	October 2017
Pore‐scale simulation of carbonate dissolution in micro‐CT images Pereira Nunes, J. P.; Blunt, M. J.; Bijeljic, B. Journal of Geophysical Research: Solid Earth, Vol. 121, Issue 2 https://doi.org/10.1002/2015JB012117	journal	February 2016
Pervasive pressure solution transfer in a quartz sand Revil, A. Journal of Geophysical Research: Solid Earth, Vol. 106, Issue B5 https://doi.org/10.1029/2000JB900465	journal	May 2001
Multicomponent Diffusion and Reaction in Three-Dimensional Networks: General Kinetics Rieckmann, Christina; Keil, Frerich J. Industrial & Engineering Chemistry Research, Vol. 36, Issue 8 https://doi.org/10.1021/ie9605847	journal	August 1997
Mineral dissolution and wormholing from a pore-scale perspective Soulaine, Cyprien; Roman, Sophie; Kovscek, Anthony Journal of Fluid Mechanics, Vol. 827 https://doi.org/10.1017/jfm.2017.499	journal	August 2017
Three-dimensional simulations of fracture dissolution: FRACTURE DISSOLUTION IN 3-D Starchenko, Vitaliy; Marra, Cameron J.; Ladd, Anthony J. C. Journal of Geophysical Research: Solid Earth, Vol. 121, Issue 9 https://doi.org/10.1002/2016JB013321	journal	September 2016
The Development of Wormholes in Laboratory‐Scale Fractures: Perspectives From Three‐Dimensional Simulations Starchenko, Vitaliy; Ladd, Anthony J. C. Water Resources Research, Vol. 54, Issue 10 https://doi.org/10.1029/2018WR022948	journal	October 2018
Pore Scale Processes Associated with Subsurface CO2 Injection and Sequestration Steefel, C. I.; Molins, S.; Trebotich, D. Reviews in Mineralogy and Geochemistry, Vol. 77, Issue 1 https://doi.org/10.2138/rmg.2013.77.8	journal	January 2013
Micro-Continuum Approaches for Modeling Pore-Scale Geochemical Processes Steefel, Carl I.; Beckingham, Lauren E.; Landrot, Gautier Reviews in Mineralogy and Geochemistry, Vol. 80, Issue 1 https://doi.org/10.2138/rmg.2015.80.07	journal	January 2015
A network model of channel competition in fracture dissolution Szymczak, P.; Ladd, A. J. C. Geophysical Research Letters, Vol. 33, Issue 5 https://doi.org/10.1029/2005GL025334	journal	January 2006
Reactive-infiltration instabilities in rocks. Fracture dissolution Szymczak, Piotr; Ladd, Anthony J. C. Journal of Fluid Mechanics, Vol. 702 https://doi.org/10.1017/jfm.2012.174	journal	May 2012
Reactive-infiltration instabilities in rocks. Part 2. Dissolution of a porous matrix Szymczak, Piotr; Ladd, Anthony J. C. Journal of Fluid Mechanics, Vol. 738 https://doi.org/10.1017/jfm.2013.586	journal	December 2013
Numerical simulation of the effect of grain size on corrosion processes: Surface roughness oscillation and cluster detachment Taleb, A.; Stafiej, J. Corrosion Science, Vol. 53, Issue 8 https://doi.org/10.1016/j.corsci.2011.04.008	journal	August 2011
A reactive transport model of neptunium migration from the potential repository at Yucca Mountain Viswanathan, Hari S.; Robinson, Bruce A.; Valocchi, Albert J. Journal of Hydrology, Vol. 209, Issue 1-4 https://doi.org/10.1016/S0022-1694(98)00122-X	journal	August 1998
Controls of Microstructure and Chemical Reactivity on the Replacement of Limestone by Fluorite Studied Using Spatially Resolved Small Angle X-ray and Neutron Scattering Weber, Juliane; Cheshire, Michael C.; Distefano, Victoria H. ACS Earth and Space Chemistry, Vol. 3, Issue 9 https://doi.org/10.1021/acsearthspacechem.9b00085	journal	July 2019
The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field? White, Art F.; Brantley, Susan L. Chemical Geology, Vol. 202, Issue 3-4 https://doi.org/10.1016/j.chemgeo.2003.03.001	journal	December 2003
Measurement and modelling of reactive transport in geological barriers for nuclear waste containment Xiong, Qingrong; Joseph, Claudia; Schmeide, Katja Physical Chemistry Chemical Physics, Vol. 17, Issue 45 https://doi.org/10.1039/C5CP05243B	journal	January 2015
TOUGHREACT—A simulation program for non-isothermal multiphase reactive geochemical transport in variably saturated geologic media: Applications to geothermal injectivity and CO2 geological sequestration Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas Computers & Geosciences, Vol. 32, Issue 2 https://doi.org/10.1016/j.cageo.2005.06.014	journal	March 2006

Similar Records

Simulation of Coupled Processes of Flow, Transport, and Storage of CO₂ in Saline Aquifers

Technical Report · Tue Sep 30 00:00:00 EDT 2014 · OSTI ID:1619024

Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; +5 more

Application of a pore-scale reactive transport model to a natural analog for reaction-induced pore alterations

Journal Article · Thu Jan 05 00:00:00 EST 2017 · Journal of Petroleum Science and Engineering · OSTI ID:1619024

Yoon, Hongkyu; Major, Jonathan; Dewers, Thomas; +1 more

Pore and Continuum Scale Study of the Effect of Subgrid Transport Heterogeneity on Redox Reaction Rates

Journal Article · Sat Aug 01 00:00:00 EDT 2015 · Geochimica et Cosmochimica Acta, 163:140-155 · OSTI ID:1619024

Liu, Yuanyuan; Liu, Chongxuan; Zhang, Changyong; +2 more

Related Subjects

58 GEOSCIENCES
Pore-scale reactive transport
Mineral dissolution
Grain boundary
Grain detachment

Title: Grain detachment and transport clogging during mineral dissolution in carbonate rocks with permeable grain boundaries

Citation Formats

References (75)

Similar Records

Related Subjects