skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The Effect of Shot Peening on Steam Oxidation of 304H Stainless Steel

Journal Article · · Oxidation of Metals

Shot peening is currently utilized in coal-fired power plant components to mitigate scale exfoliation issues from steamside oxidation of austenitic stainless steel superheater and reheater tubing. To focus on commercially available material, this study exposed quarter-ring specimens cut from two different commercially shot peened type 304H tubes and exposed to 1 bar steam for up to 15,000 h at 550°, 600°, 625°, and 650 °C. Specimens were removed at increments to characterize the oxide thickness and microstructure. The shot peened inner surface generally retained a thin, protective Cr-rich scale with occasional Fe-rich oxide nodules at 550–625 °C. The increased oxidation resistance from shot peening began to degrade at 650 °C after as little as 5,000 h. Cut and polished faces of these specimens formed thick, Fe-rich oxides similar to polished 304H coupons. Surprisingly, the mechanically machined outer surface of the tube specimens performed similarly to the shot peened inner diameter, suggesting it had sufficient cold work to achieve a similar benefit. As a result, electron backscatter diffraction and Vickers-hardness measurements were used to characterize post-exposure changes in underlying microstructure and mechanical properties, respectively, imparted by shot peening.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1606998
Journal Information:
Oxidation of Metals, Vol. 93, Issue 1-2; ISSN 0030-770X
Publisher:
SpringerCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

References (33)

Chromium Volatilization Rates from Cr2O3 Scales into Flowing Gases Containing Water Vapor journal November 2006
Towards improved prediction of scale exfoliation from steam tubes journal December 2007
Cyclic oxidation and mechanical behaviour of slurry aluminide coatings for steam turbine components journal April 2007
Diffusion coatings of steels: Formation mechanism and microstructure of aluminized heat-resistant stainless steels journal January 1984
The oxidation behaviour of metals and alloys at high temperatures in atmospheres containing water vapour: A review journal July 2008
Internal-external transition for the oxidation of Fe-Cr-Ni austenitic stainless steels in steam journal August 1989
External corrosion in coal-fired boilers: Assessment from laboratory data journal January 1981
Effect of cold work on the oxidation of FeCr alloys in water vapour at 600°C journal January 1966
Development of Strain in Oxides Grown in Steam Tubes journal September 2008
Beneficial effect of shot peening on steamside oxidation of 300-series austenitic steels: An electrochemical study journal January 2018
Influence of Oxide Growth and Metal Creep on Strain Development in the Steam-Side Oxide in Boiler Tubes journal January 2010
Effect of Shot-peening on the Oxidation Behaviour of Boiler Steels journal April 2011
Steam oxidation of Super 304H and shot-peened Super 304H journal June 2012
Microstructural Evolution of Super304H Upon Ultrasonic Shot Peening and Subsequent Annealing journal September 2018
A review of the oxidation behaviour of structural alloys in steam journal May 2010
Effect of Shot Peening on Oxidation Behavior of SS304H Upon Long Term Steam Exposure journal September 2018
Mechanisms of Breakaway Oxidation and Application to a Chromia-Forming Steel journal January 1999
Corrosion behavior of chromized and/or aluminized Cr-1Mo steel in medium-BTU coal gasifier environments journal December 1988
The Mechanism of the High-Temperature Oxidation of Iron-Chromium Alloys in Water Vapor journal January 1964
Lessons from the past: materials-related issues in an ultra-supercritical boiler at Eddystone plant journal December 2007
Effect of Cr and Ni Contents on the Oxidation Behavior of Ferritic and Austenitic Model Alloys in Air with Water Vapor journal June 2004
Effect of cold work on the oxidation of iron from 400–650 °C journal January 1966
An investigation of pack-aluminide coating on steel journal June 1982
Japanese experience with steam oxidation of advanced heat-resistant steel tubes in power boilers journal February 2005
Relationship between the effects of velocity and alloy corrosion resistance in erosion-corrosion environments at elevated temperatures journal January 1995
Effect of water vapor on high-temperature oxidation of FeCr alloys journal July 2009
Dislocation engineering and its effect on the oxidation behaviour journal June 2012
Enhanced oxidation of the 9%Cr steel P91 in water vapour containing environments journal November 2006
High temperature corrosion of alloys and coatings in oil- and coal-fired boilers journal April 1987
Simultaneous chromizing-aluminizing coating of austenitic stainless steels journal April 1988
Effect of cold work on the oxidation resistance of $$2\tfrac{1}{4}$$ Cr-1 Mo steel journal February 1985
High-Temperature Corrosion in Fossil Fuel Power Generation: Present and Future journal June 2013
Japanese experience with steam oxidation of advanced heat-resistant steel tubes in power boilers journal January 2005