Cs 2PbI2Cl2, All-Inorganic Two-Dimensional Ruddlesden–Popper Mixed Halide Perovskite with Optoelectronic Response

Li, Jiangwei; Yu, Qin; He, Yihui; Stoumpos, Constantinos C.; Niu, Guangda; Trimarchi, Giancarlo G.; Guo, Hang; Dong, Guifang; Wang, Dong; Wang, Liduo; Kanatzidis, Mercouri G.

doi:10.1021/jacs.8b06046

Title: Cs ₂PbI₂Cl₂, All-Inorganic Two-Dimensional Ruddlesden–Popper Mixed Halide Perovskite with Optoelectronic Response

Journal Article · Tue Aug 07 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b06046· OSTI ID:1599732

^[1]; Yu, Qin ^[2];

^[3];

^[4]; Trimarchi, Giancarlo G. ^[3];

^[2]; Dong, Guifang ^[2];

^[2]; Wang, Liduo ^[2];

^[3]

Tsinghua Univ., Beijing (China); Northwestern Univ., Evanston, IL (United States)
Tsinghua Univ., Beijing (China)
Northwestern Univ., Evanston, IL (United States)
Huazhong Univ. of Science and Technology, Wuhan (China)

The two-dimensional Ruddlesden–Popper (RP) phases are a prime class of halide perovskites with versatile optoelectronic properties. So far, only organic–inorganic hybrid RP phases involving long organic spacers were reported in this class. Herein, we discuss an all-inorganic RP phase lead halide perovskite, Cs₂PbI₂Cl₂ (1, I4/mmm space group; a = 5.6385(8) Å, c = 18.879(4) Å), synthesized by a solid-state method. The compound exhibits a band gap of E_g ~ 3.04 eV and photoconductivity. We find an anomalous band gap evolution in Cs₂Pb_1–xSn_xI₂Cl₂ solid solutions. Our combined density functional theory and experimental study supports the thermodynamically stable nature of 1 as a unique ordered phase in the Cs₂PbX₄ (X = Cl, Br, I) system. The calculations suggest that 1 is a direct bandgap semiconductor with relatively small effective carrier mass along the in-plane direction, consistent with the experimentally observed in-plane UV-light photoresponse. We also demonstrate that 1 is promising for radiation detection capable of α-particle counting. Moreover, 1 shows markedly ambient and thermal stability.

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Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC); Ministry of Science and Technology of China; Chinese Scholarship Council (CSC)

Grant/Contract Number:: SC0012541; 2015CB655002

OSTI ID:: 1599732

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 35; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 122 works

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Title: Cs 2PbI2Cl2, All-Inorganic Two-Dimensional Ruddlesden–Popper Mixed Halide Perovskite with Optoelectronic Response

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Title: Cs ₂PbI₂Cl₂, All-Inorganic Two-Dimensional Ruddlesden–Popper Mixed Halide Perovskite with Optoelectronic Response