Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid

Huynh, Michael; Ozel, Tuncay; Liu, Chong; Lau, Eric C.; Nocera, Daniel G.

doi:10.1039/C7SC01239J

Title: Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid

Journal Article · Fri May 05 00:00:00 EDT 2017 · Chemical Science

DOI:https://doi.org/10.1039/C7SC01239J· OSTI ID:1599222

Huynh, Michael ^[1]; Ozel, Tuncay ^[1];

^[1]; Lau, Eric C. ^[1];

^[1]

Harvard Univ., Cambridge, MA (United States)

Oxygen evolution reaction (OER) catalysts that are earth-abundant and are active and stable in acid are unknown. Active catalysts derived from Co and Ni oxides dissolve at low pH, whereas acid stable systems such as Mn oxides (MnO_x) display poor OER activity. We now demonstrate a rational approach for the design of earth-abundant catalysts that are stable and active in acid by treating activity and stability as decoupled elements of mixed metal oxides. Manganese serves as a stabilizing structural element for catalytically active Co centers in CoMnO_x films. In acidic solutions (pH 2.5), CoMnO_x exhibits the OER activity of electrodeposited Co oxide (CoO_x) with a Tafel slope of 70–80 mV per decade while also retaining the long-term acid stability of MnO_x films for OER at 0.1 mA cm^-2. Driving OER at greater current densities in this system is not viable because at high anodic potentials, Mn oxides convert to and dissolve as permanganate. However, by exploiting the decoupled design of the catalyst, the stabilizing structural element may be optimized independently of the Co active sites. By screening potential–pH diagrams, we replaced Mn with Pb to prepare CoFePbO_x films that maintained the high OER activity of CoO_x at pH 2.5 while exhibiting long-term acid stability at higher current densities (at 1 mA cm^-2 for over 50 h at pH 2.0). Under these acidic conditions, CoFePbO_x exhibits OER activity that approaches noble metal oxides, thus establishing the viability of decoupling functionality in mixed metal catalysts for designing active, acid-stable, and earth-abundant OER catalysts.

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Research Organization:: Harvard Univ., Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation (NSF)

Grant/Contract Number:: SC0017619; ECS-0335765

OSTI ID:: 1599222

Journal Information:: Chemical Science, Vol. 8, Issue 7; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 152 works

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References (100)

On the future of global energy Nocera, Daniel G. Daedalus, Vol. 135, Issue 4 https://doi.org/10.1162/daed.2006.135.4.112	journal	October 2006
Keeping the Energy Debate Clean: How Do We Supply the World's Energy Needs? Abbott, D. Proceedings of the IEEE, Vol. 98, Issue 1 https://doi.org/10.1109/JPROC.2009.2035162	journal	January 2010
“Fast food” energy Nocera, Daniel G. Energy & Environmental Science, Vol. 3, Issue 8 https://doi.org/10.1039/c003891c	journal	January 2010
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds Cook, Timothy R.; Dogutan, Dilek K.; Reece, Steven Y. Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr100246c	journal	November 2010
Solar Fuels and Solar Chemicals Industry Nocera, Daniel G. Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00615	journal	March 2017
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities Arakawa, Hironori; Aresta, Michele; Armor, John N. Chemical Reviews, Vol. 101, Issue 4 https://doi.org/10.1021/cr000018s	journal	April 2001
Water splitting–biosynthetic system with CO ₂ reduction efficiencies exceeding photosynthesis Liu, Chong; Colón, Brendan C.; Ziesack, Marika Science, Vol. 352, Issue 6290 https://doi.org/10.1126/science.aaf5039	journal	June 2016
Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II Liu, Feng; Concepcion, Javier J.; Jurss, Jonah W. Inorganic Chemistry, Vol. 47, Issue 6 https://doi.org/10.1021/ic701249s	journal	March 2008
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis Dau, Holger; Limberg, Christian; Reier, Tobias ChemCatChem, Vol. 2, Issue 7 https://doi.org/10.1002/cctc.201000126	journal	June 2010
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co²⁺ Kanan, M. W.; Nocera, D. G. Science, Vol. 321, Issue 5892, p. 1072-1075 https://doi.org/10.1126/science.1162018	journal	August 2008
Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH Surendranath, Yogesh; Kanan, Matthew W.; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 132, Issue 46 https://doi.org/10.1021/ja106102b	journal	November 2010
Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0–14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity Gerken, James B.; McAlpin, J. Gregory; Chen, Jamie Y. C. Journal of the American Chemical Society, Vol. 133, Issue 36 https://doi.org/10.1021/ja205647m	journal	August 2011
Water Oxidation by Amorphous Cobalt-Based Oxides: Volume Activity and Proton Transfer to Electrolyte Bases Klingan, Katharina; Ringleb, Franziska; Zaharieva, Ivelina ChemSusChem, Vol. 7, Issue 5 https://doi.org/10.1002/cssc.201301019	journal	January 2014
The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin Film Nickel Oxide Electrodes Corrigan, Dennis A. Journal of The Electrochemical Society, Vol. 134, Issue 2 https://doi.org/10.1149/1.2100463	journal	January 1987
Nickel-borate oxygen-evolving catalyst that functions under benign conditions Dinca, M.; Surendranath, Y.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 107, Issue 23 https://doi.org/10.1073/pnas.1001859107	journal	May 2010
Mechanistic Studies of the Oxygen Evolution Reaction Mediated by a Nickel–Borate Thin Film Electrocatalyst Bediako, D. Kwabena; Surendranath, Yogesh; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 135, Issue 9 https://doi.org/10.1021/ja3126432	journal	February 2013
Nickel–Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts: The Role of Intentional and Incidental Iron Incorporation Trotochaud, Lena; Young, Samantha L.; Ranney, James K. Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja502379c	journal	April 2014
Electrochemical Synthesis of Photoelectrodes and Catalysts for Use in Solar Water Splitting Kang, Donghyeon; Kim, Tae Woo; Kubota, Stephen R. Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00498	journal	August 2015
First row transition metal catalysts for solar-driven water oxidation produced by electrodeposition Roger, Isolda; Symes, Mark D. Journal of Materials Chemistry A, Vol. 4, Issue 18 https://doi.org/10.1039/C5TA09423B	journal	January 2016
A Functionally Stable Manganese Oxide Oxygen Evolution Catalyst in Acid Huynh, Michael; Bediako, D. Kwabena; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja413147e	journal	April 2014
Nucleation and Growth Mechanisms of an Electrodeposited Manganese Oxide Oxygen Evolution Catalyst Huynh, Michael; Bediako, D. Kwabena; Liu, Yi The Journal of Physical Chemistry C, Vol. 118, Issue 30 https://doi.org/10.1021/jp501768n	journal	April 2014
Nature of Activated Manganese Oxide for Oxygen Evolution Huynh, Michael; Shi, Chenyang; Billinge, Simon J. L. Journal of the American Chemical Society, Vol. 137, Issue 47 https://doi.org/10.1021/jacs.5b06382	journal	November 2015
Low pH Electrolytic Water Splitting Using Earth-Abundant Metastable Catalysts That Self-Assemble in Situ Bloor, Leanne G.; Molina, Pedro I.; Symes, Mark D. Journal of the American Chemical Society, Vol. 136, Issue 8 https://doi.org/10.1021/ja5003197	journal	February 2014
Toward an Active and Stable Catalyst for Oxygen Evolution in Acidic Media: Ti-Stabilized MnO ₂ Frydendal, Rasmus; Paoli, Elisa A.; Chorkendorff, Ib Advanced Energy Materials, Vol. 5, Issue 22 https://doi.org/10.1002/aenm.201500991	journal	August 2015
Parallel Electrochemical Treatment System and Application for Identifying Acid-Stable Oxygen Evolution Electrocatalysts Jones, Ryan J. R.; Shinde, Aniketa; Guevarra, Dan ACS Combinatorial Science, Vol. 17, Issue 2 https://doi.org/10.1021/co500148p	journal	January 2015
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Will Solar-Driven Water-Splitting Devices See the Light of Day? McKone, James R.; Lewis, Nathan S.; Gray, Harry B. Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm4021518	journal	September 2013
A comprehensive review on PEM water electrolysis Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934 https://doi.org/10.1016/j.ijhydene.2013.01.151	journal	April 2013
Solar Water Splitting Cells Walter, Michael G.; Warren, Emily L.; McKone, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473 https://doi.org/10.1021/cr1002326	journal	November 2010
Proton Activity in Nafion Films: Probing Exchangeable Protons with Methylene Blue Seger, Brian; Vinodgopal, K.; Kamat, Prashant V. Langmuir, Vol. 23, Issue 10 https://doi.org/10.1021/la0636816	journal	May 2007
Interfaces between water splitting catalysts and buried silicon junctions Cox, Casandra R.; Winkler, Mark T.; Pijpers, Joep J. H. Energy Environ. Sci., Vol. 6, Issue 2 https://doi.org/10.1039/C2EE23932A	journal	January 2013
Stabilized CdSe-CoPi Composite Photoanode for Light-Assisted Water Oxidation by Transformation of a CdSe/Cobalt Metal Thin Film Costi, Ronny; Young, Elizabeth R.; Bulović, Vladimir ACS Applied Materials & Interfaces, Vol. 5, Issue 7 https://doi.org/10.1021/am400364u	journal	March 2013
High-Performance Silicon Photoanodes Passivated with Ultrathin Nickel Films for Water Oxidation Kenney, M. J.; Gong, M.; Li, Y. Science, Vol. 342, Issue 6160 https://doi.org/10.1126/science.1241327	journal	November 2013
Protection of inorganic semiconductors for sustained, efficient photoelectrochemical water oxidation Lichterman, Michael F.; Sun, Ke; Hu, Shu Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.08.017	journal	March 2016
Chemistry of Personalized Solar Energy Nocera, Daniel G. Inorganic Chemistry, Vol. 48, Issue 21 https://doi.org/10.1021/ic901328v	journal	November 2009
Hydrogen Produced from Hydrohalic Acid Solutions by a Two-Electron Mixed-Valence Photocatalyst Heyduk, A. F. Science, Vol. 293, Issue 5535 https://doi.org/10.1126/science.1062965	journal	August 2001
Photocatalytic hydrogen production Teets, Thomas S.; Nocera, Daniel G. Chemical Communications, Vol. 47, Issue 33 https://doi.org/10.1039/c1cc12390d	journal	January 2011
Halide-Bridged Binuclear HX-Splitting Catalysts Powers, David C.; Hwang, Seung Jun; Zheng, Shao-Liang Inorganic Chemistry, Vol. 53, Issue 17 https://doi.org/10.1021/ic501136m	journal	August 2014
Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges Gewirth, Andrew A.; Thorum, Matthew S. Inorganic Chemistry, Vol. 49, Issue 8 https://doi.org/10.1021/ic9022486	journal	April 2010
Nucleation, Growth, and Repair of a Cobalt-Based Oxygen Evolving Catalyst Surendranath, Yogesh; Lutterman, Daniel A.; Liu, Yi Journal of the American Chemical Society, Vol. 134, Issue 14 https://doi.org/10.1021/ja3000084	journal	March 2012
Electrodeposited lead dioxide coatings Li, Xiaohong; Pletcher, Derek; Walsh, Frank C. Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c0cs00213e	journal	January 2011
Photoactivity of Transparent Nanocrystalline Fe ₂ O ₃ Electrodes Prepared via Anodic Electrodeposition Spray, Ryan L.; Choi, Kyoung-Shin Chemistry of Materials, Vol. 21, Issue 15 https://doi.org/10.1021/cm803099k	journal	August 2009
Anodic electrodeposition of iridium oxide films Petit, Michel A.; Plichon, Vincent Journal of Electroanalytical Chemistry, Vol. 444, Issue 2 https://doi.org/10.1016/S0022-0728(97)00570-6	journal	March 1998
Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution Trotochaud, Lena; Ranney, James K.; Williams, Kerisha N. Journal of the American Chemical Society, Vol. 134, Issue 41 https://doi.org/10.1021/ja307507a	journal	October 2012
Anodic Deposition of Colloidal Iridium Oxide Thin Films from Hexahydroxyiridate(IV) Solutions Zhao, Yixin; Vargas-Barbosa, Nella M.; Hernandez-Pagan, Emil A. Small, Vol. 7, Issue 14 https://doi.org/10.1002/smll.201100485	journal	June 2011
Dependence of the phase composition of the anodic layer on oxygen evolution and anodic corrosion of lead electrode in lead dioxide potential region Pavlov, D.; Rogachev, T. Electrochimica Acta, Vol. 23, Issue 11 https://doi.org/10.1016/0013-4686(78)85079-8	journal	November 1978
Cobalt–Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism Burke, Michaela S.; Kast, Matthew G.; Trotochaud, Lena Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/jacs.5b00281	journal	March 2015
Effects of Fe Electrolyte Impurities on Ni(OH) ₂ /NiOOH Structure and Oxygen Evolution Activity Klaus, Shannon; Cai, Yun; Louie, Mary W. The Journal of Physical Chemistry C, Vol. 119, Issue 13 https://doi.org/10.1021/acs.jpcc.5b00105	journal	March 2015
Electrocatalytic effect of metal ions on lead and lead dioxide electrode reactions Sánchez, H.; Meas, Y. Reaction Kinetics & Catalysis Letters, Vol. 45, Issue 1 https://doi.org/10.1007/BF02078610	journal	September 1991
Nature of the use of adventitious carbon as a binding energy standard Barr, Tery L.; Seal, Sudipta Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3 https://doi.org/10.1116/1.579868	journal	May 1995
Surface composition and structure of Co3O4(110) and the effect of impurity segregation Petitto, S. C.; Langell, M. A. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 22, Issue 4 https://doi.org/10.1116/1.1763899	journal	July 2004
Investigation of the oxidation of polycrystalline lead by XPS and SIMS Hewitt, R. W.; Winograd, Nicholas Surface Science, Vol. 78, Issue 1 https://doi.org/10.1016/0039-6028(78)90205-4	journal	November 1978
On the relative dissolution rates of some oxide and orthosilicate minerals Casey, William H. Journal of Colloid and Interface Science, Vol. 146, Issue 2 https://doi.org/10.1016/0021-9797(91)90225-W	journal	October 1991
Reactivity at the mineral-water interface: dissolution and inhibition Stumm, Werner Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 120, Issue 1-3 https://doi.org/10.1016/S0927-7757(96)03866-6	journal	February 1997
Electrochemical investigation of electrocatalysts for the oxygen evolution reaction in PEM water electrolyzers Song, Shidong; Zhang, Huamin; Ma, Xiaoping International Journal of Hydrogen Energy, Vol. 33, Issue 19 https://doi.org/10.1016/j.ijhydene.2008.06.039	journal	October 2008
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs3003098	journal	July 2012
Combinatorial Search for Improved Metal Oxide Oxygen Evolution Electrocatalysts in Acidic Electrolytes Seley, David; Ayers, Katherine; Parkinson, B. A. ACS Combinatorial Science, Vol. 15, Issue 2 https://doi.org/10.1021/co300086h	journal	January 2013
Efficient multi-metallic anode catalysts in a PEM water electrolyzer Kokoh, K. B.; Mayousse, E.; Napporn, T. W. International Journal of Hydrogen Energy, Vol. 39, Issue 5 https://doi.org/10.1016/j.ijhydene.2013.11.076	journal	February 2014
Ir-Surface Enriched Porous Ir–Co Oxide Hierarchical Architecture for High Performance Water Oxidation in Acidic Media Hu, Wei; Zhong, Huawei; Liang, Wei ACS Applied Materials & Interfaces, Vol. 6, Issue 15 https://doi.org/10.1021/am5027192	journal	July 2014
Influence of iron doping on tetravalent nickel content in catalytic oxygen evolving films Li, Nancy; Bediako, D. Kwabena; Hadt, Ryan G. Proceedings of the National Academy of Sciences, Vol. 114, Issue 7 https://doi.org/10.1073/pnas.1620787114	journal	January 2017
Combinatorial Discovery and Optimization of a Complex Oxide with Water Photoelectrolysis Activity Woodhouse, Michael; Parkinson, B. A. Chemistry of Materials, Vol. 20, Issue 7 https://doi.org/10.1021/cm703099j	journal	April 2008
Development of an O ₂ -Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation Gerken, James B.; Chen, Jamie Y. C.; Massé, Robert C. Angewandte Chemie International Edition, Vol. 51, Issue 27 https://doi.org/10.1002/anie.201201999	journal	May 2012
Ordered Mesoporous Cobalt Oxide as Highly Efficient Oxygen Evolution Catalyst Rosen, Jonathan; Hutchings, Gregory S.; Jiao, Feng Journal of the American Chemical Society, Vol. 135, Issue 11 https://doi.org/10.1021/ja400555q	journal	March 2013
Catalytic Oxygen Evolution by Cobalt Oxido Thin Films Bediako, D. Kwabena; Ullman, Andrew M.; Nocera, Daniel G. Topics in Current Chemistry https://doi.org/10.1007/128_2015_649	book	January 2015
A Self-Healing Oxygen-Evolving Catalyst Lutterman, Daniel A.; Surendranath, Yogesh; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 131, Issue 11 https://doi.org/10.1021/ja900023k	journal	March 2009
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
High-Throughput Screening for Acid-Stable Oxygen Evolution Electrocatalysts in the (Mn–Co–Ta–Sb)O x Composition Space Shinde, Aniketa; Jones, Ryan J. R.; Guevarra, Dan Electrocatalysis, Vol. 6, Issue 2 https://doi.org/10.1007/s12678-014-0237-7	journal	November 2014
Real surface area measurements in electrochemistry Trasatti, S.; Petrii, O. A. Journal of Electroanalytical Chemistry, Vol. 327, Issue 1-2 https://doi.org/10.1016/0022-0728(92)80162-W	journal	June 1992
Electrosynthesis, functional, and structural characterization of a water-oxidizing manganese oxide Zaharieva, Ivelina; Chernev, Petko; Risch, Marcel Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21191b	journal	January 2012
Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis Robinson, David M.; Go, Yong Bok; Mui, Michelle Journal of the American Chemical Society, Vol. 135, Issue 9 https://doi.org/10.1021/ja310286h	journal	February 2013
In Situ X-ray Absorption Spectroscopy Investigation of a Bifunctional Manganese Oxide Catalyst with High Activity for Electrochemical Water Oxidation and Oxygen Reduction Gorlin, Yelena; Lassalle-Kaiser, Benedikt; Benck, Jesse D. Journal of the American Chemical Society, Vol. 135, Issue 23 https://doi.org/10.1021/ja3104632	journal	June 2013
Electrolyte-Dependent Electrosynthesis and Activity of Cobalt-Based Water Oxidation Catalysts Surendranath, Yogesh; Dincǎ, Mircea; Nocera, Daniel G. Journal of the American Chemical Society, Vol. 131, Issue 7 https://doi.org/10.1021/ja807769r	journal	February 2009
The electrochemical characteristics of binary manganese–cobalt oxides prepared by anodic deposition Chuang, Po-Yao; Hu, Chi-Chang Materials Chemistry and Physics, Vol. 92, Issue 1 https://doi.org/10.1016/j.matchemphys.2005.01.004	journal	July 2005
Sol–gel preparation of cobalt manganese mixed oxides for their use as electrode materials in lithium cells Lavela, P.; Tirado, J. L.; Vidal-Abarca, C. Electrochimica Acta, Vol. 52, Issue 28 https://doi.org/10.1016/j.electacta.2007.06.066	journal	November 2007
Effects of Additional Elements on Electrocatalytic Properties of Thermally Decomposed Manganese Oxide Electrodes for Oxygen Evolution from Seawater Izumiya, K.; Akiyama, E.; Habazaki, H. Materials Transactions, JIM, Vol. 38, Issue 10 https://doi.org/10.2320/matertrans1989.38.899	journal	January 1997
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst Song, Fang; Hu, Xile Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja5096733	journal	November 2014
High Surface Area Metal Carbide and Metal Nitride Electrodes Wixom, M. R.; Tarnowski, D. J.; Parker, J. M. MRS Proceedings, Vol. 496 https://doi.org/10.1557/PROC-496-643	journal	January 1997
A review of gas diffusion layer in PEM fuel cells: Materials and designs Park, Sehkyu; Lee, Jong-Won; Popov, Branko N. International Journal of Hydrogen Energy, Vol. 37, Issue 7 https://doi.org/10.1016/j.ijhydene.2011.12.148	journal	April 2012
High Surface Area Transparent Conducting Oxide Electrodes with a Customizable Device Architecture Forman, Arnold J.; Chen, Zhebo; Chakthranont, Pongkarn Chemistry of Materials, Vol. 26, Issue 2 https://doi.org/10.1021/cm402551m	journal	December 2013
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
Why is lead dioxide metallic? Payne, David J.; Egdell, Russell G.; Hao, Wang Chemical Physics Letters, Vol. 411, Issue 1-3 https://doi.org/10.1016/j.cplett.2005.06.023	journal	August 2005
Nature of the Band Gap and Origin of the Conductivity of ${PbO}_{2}$ Revealed by Theory and Experiment Scanlon, David O.; Kehoe, Aoife B.; Watson, Graeme W. Physical Review Letters, Vol. 107, Issue 24 https://doi.org/10.1103/PhysRevLett.107.246402	journal	December 2011
The behaviour of the lead dioxide electrode. Part 3.—Overvoltage during oxygen evolution in H ₂ SO ₄ Jones, P.; Lind, R.; Wynne-Jones, W. F. K. Trans. Faraday Soc., Vol. 50, Issue 0 https://doi.org/10.1039/TF9545000972	journal	January 1954
Electrodeposition of Co-doped lead dioxide and its physicochemical properties Velichenko, A. B.; Amadelli, R.; Baranova, E. A. Journal of Electroanalytical Chemistry, Vol. 527, Issue 1-2 https://doi.org/10.1016/S0022-0728(02)00828-8	journal	May 2002
Electrodeposition of lead–cobalt composite coatings electrocatalytic for oxygen evolution and the properties of composite coated anodes for copper electrowinning Barmi, Maryam Jozegholami; Nikoloski, Aleksandar N. Hydrometallurgy, Vol. 129-130 https://doi.org/10.1016/j.hydromet.2012.08.005	journal	November 2012
The influence of alloying elements on the electrochemistry of lead anodes for electrowinning of metals: A review Clancy, M.; Bettles, C. J.; Stuart, A. Hydrometallurgy, Vol. 131-132 https://doi.org/10.1016/j.hydromet.2012.11.001	journal	January 2013
Lead dioxide electrode Carr, J. P.; Hampson, N. A. Chemical Reviews, Vol. 72, Issue 6 https://doi.org/10.1021/cr60280a003	journal	December 1972
The electronic conductivity of compact lead dioxide samples with various stoichiometric compositions Pohl, J. P.; Schendler, W. Journal of Power Sources, Vol. 6, Issue 3 https://doi.org/10.1016/0378-7753(81)80029-8	journal	December 1981
Synthesis and Characterization of Co₃O₄ Thin Film Patil, Vikas; Joshi, Pradeep; Chougule, Manik Soft Nanoscience Letters, Vol. 02, Issue 01 https://doi.org/10.4236/snl.2012.21001	journal	January 2012
Electrical Resistivity Measurements on Manganese Oxides with Layer and Tunnel Structures: Birnessites, Todorokites, and Cryptomelanes De Guzman, Roberto N.; Awaluddin, Amir; Shen, Yan-Fei Chemistry of Materials, Vol. 7, Issue 7 https://doi.org/10.1021/cm00055a003	journal	July 1995
Electrical conductivity and seebeck voltage of Fe2O3, pure and doped, as a function of temperature and oxygen pressure Warnes, B.; Aplan, F.; Simkovich, G. Solid State Ionics, Vol. 12 https://doi.org/10.1016/0167-2738(84)90156-5	journal	March 1984
Electrical conductivity as a defect property of γ-FeOOH Kaneko, Katsumi; Inouye, Katsuya Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 72, Issue 0 https://doi.org/10.1039/f19767201258	journal	January 1976
A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites Betley, Theodore A.; Surendranath, Yogesh; Childress, Montana V. Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 363, Issue 1494 https://doi.org/10.1098/rstb.2007.2226	journal	October 2007
An Introduction to Surface Analysis by XPS and AES Watts, John F.; Wolstenholme, John Wiley https://doi.org/10.1002/0470867930	book	March 2003
Photocatalytic Hydrogen Production Luca Chiarello, Gian; Selli, Elena Recent Patents on Engineering, Vol. 4, Issue 3 https://doi.org/10.2174/187221210794578600	journal	November 2010
Real surface area measurements in electrochemistry Trasatti, S.; Petrii, O. A. Pure and Applied Chemistry, Vol. 63, Issue 5 https://doi.org/10.1351/pac199163050711	journal	January 1991
An Introduction to Surface Analysis by XPS and AES Watts, John F.; Wolstenholme, John https://doi.org/10.1002/9781119417651	journal	January 2019
Development of an O ₂ -Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation Gerken, James B.; Chen, Jamie Y. C.; Massé, Robert C. Angewandte Chemie, Vol. 124, Issue 27 https://doi.org/10.1002/ange.201201999	journal	May 2012

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Recent Progress in Decoupled H ₂ and O ₂ Production from Electrolytic Water Splitting Liu, Xuan; Chi, Jingqi; Dong, Bin ChemElectroChem, Vol. 6, Issue 8 https://doi.org/10.1002/celc.201801671	journal	February 2019
Solar‐Driven Production of Hydrogen Peroxide from Water and Dioxygen Fukuzumi, Shunichi; Lee, Yong‐Min; Nam, Wonwoo Chemistry – A European Journal, Vol. 24, Issue 20 https://doi.org/10.1002/chem.201704512	journal	February 2018
Electrolysis of Natural Waters Contaminated with Transition-Metal Ions: Identification of A Metastable FePb-Based Oxygen-Evolution Catalyst Operating in Weakly Acidic Solutions Bonke, Shannon A.; Abel, Ken L.; Hoogeveen, Dijon A. ChemPlusChem, Vol. 83, Issue 7 https://doi.org/10.1002/cplu.201800020	journal	April 2018
Nitrogen-doped tungsten carbide nanoarray as an efficient bifunctional electrocatalyst for water splitting in acid Han, Nana; Yang, Ke R.; Lu, Zhiyi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03429-z	journal	March 2018
Intrinsically stable in situ generated electrocatalyst for long-term oxidation of acidic water at up to 80 °C Chatti, Manjunath; Gardiner, James L.; Fournier, Maxime Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0277-8	journal	May 2019
Nickel oxide–polypyrrole nanocomposite electrode materials for electrocatalytic water oxidation Morales, Daniela V.; Astudillo, Catalina N.; Lattach, Youssef Catalysis Science & Technology, Vol. 8, Issue 16 https://doi.org/10.1039/c7cy01949a	journal	January 2018
Trends in activity for the oxygen evolution reaction on transition metal (M = Fe, Co, Ni) phosphide pre-catalysts Xu, Junyuan; Li, Junjie; Xiong, Dehua Chemical Science, Vol. 9, Issue 14 https://doi.org/10.1039/c7sc05033j	journal	January 2018
Quasi-single-crystalline CoO hexagrams with abundant defects for highly efficient electrocatalytic water oxidation Liang, Zuozhong; Huang, Zhehao; Yuan, Haitao Chemical Science, Vol. 9, Issue 34 https://doi.org/10.1039/c8sc02294a	journal	January 2018
Cobalt-doped hematite thin films for electrocatalytic water oxidation in highly acidic media Kwong, Wai Ling; Lee, Cheng Choo; Shchukarev, Andrey Chemical Communications, Vol. 55, Issue 34 https://doi.org/10.1039/c9cc01369e	journal	January 2019
Photoelectrochemical cell for P–H/C–H cross-coupling with hydrogen evolution Wang, Jing-Hao; Li, Xu-Bing; Li, Jian Chemical Communications, Vol. 55, Issue 70 https://doi.org/10.1039/c9cc05375a	journal	January 2019
Fabricating Cu, Cu ₂ O and hybrid Cu-Cu ₂ O nanoparticles in carbon matrix and exploring catalytic activity of oxygen and hydrogen evolution and green A ³ -coupling reaction Muthukumar, Pandi; Kumar, P. Suresh; Anthony, Savarimuthu Philip Materials Research Express, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1591/aaf204	journal	November 2018
Electrochemical characterization of manganese oxides as a water oxidation catalyst in proton exchange membrane electrolysers Hayashi, Toru; Bonnet-Mercier, Nadège; Yamaguchi, Akira Royal Society Open Science, Vol. 6, Issue 5 https://doi.org/10.1098/rsos.190122	journal	May 2019
FeNxC Based Catalysts Prepared by the Calcination of Iron-Ethylenediamine@Polyaniline as the Cathode-Catalyst of Proton Exchange Membrane Fuel Cell Wang, Yen-Zen; Huang, Wen-Yao; Hsieh, Tar-Hwa Polymers, Vol. 11, Issue 8 https://doi.org/10.3390/polym11081368	journal	August 2019
Design of Multi‐Metallic‐Based Electrocatalysts for Enhanced Water Oxidation Bo, Xin; Dastafkan, Kamran; Zhao, Chuan ChemPhysChem, Vol. 20, Issue 22 https://doi.org/10.1002/cphc.201900507	journal	May 2019
Efficient oxygen evolution electrocatalysis in acid by a perovskite with face-sharing IrO6 octahedral dimers Yang, Lan; Yu, Guangtao; Ai, Xuan Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07678-w	journal	December 2018
Stable Potential Windows for Long‐Term Electrocatalysis by Manganese Oxides Under Acidic Conditions Li, Ailong; Ooka, Hideshi; Bonnet, Nadège Angewandte Chemie, Vol. 131, Issue 15 https://doi.org/10.1002/ange.201813361	journal	March 2019
Noble-Metal-Free Electrocatalysts for Oxygen Evolution Lyu, Fenglei; Wang, Qingfa; Choi, Sung Mook Small, Vol. 15, Issue 1 https://doi.org/10.1002/smll.201804201	journal	November 2018

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