Direct Observation of Infrared Plasmonic Fano Antiresonances by a Nanoscale Electron Probe

Smith, Kevin C; Olafsson, Agust; Hu, Xuan; Quillin, Steven C; Idrobo, Juan Carlos; Collette, Robyn; Rack, Philip D; Camden, Jon P; Masiello, David J

doi:10.1103/PhysRevLett.123.177401

Title: Direct Observation of Infrared Plasmonic Fano Antiresonances by a Nanoscale Electron Probe

Journal Article · Mon Oct 21 00:00:00 EDT 2019 · Physical Review Letters

DOI:https://doi.org/10.1103/PhysRevLett.123.177401· OSTI ID:1597420

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Univ. of Washington, Seattle, WA (United States); Dept. of Physics
Univ. of Notre Dame, IN (United States). Dept. of Chemistry and Biochemistry
Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Univ. of Tennessee, Knoxville, TN (United States) Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS) Dept. of Materials Science and Engineering
Univ. of Notre Dame, IN (United States). Dept. of Chemistry and Biochemistry; Univ. of Tennessee, Knoxville, TN (United States) Dept of Materials Science and Engineering

In this report, we exploit recent breakthroughs in monochromated aberration-corrected scanning transmission electron microscopy (STEM) to resolve infrared plasmonic Fano antiresonances in individual nanofabricated disk-rod dimers. Using a combination of electron energy-loss spectroscopy and theoretical modeling, we investigate and characterize a subspace of the weak coupling regime between quasi-discrete and quasi-continuum localized surface plasmon resonances where infrared plasmonic Fano antiresonances appear. Our research illustrates the capability of STEM instrumentation to experimentally observe nanoscale plasmonic responses that were previously the domain only of higher-resolution infrared spectroscopies.

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Research Organization:: Univ. of Washington, Seattle, WA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: SC0018040; AC05-00OR22725; SC0018169

OSTI ID:: 1597420

Alternate ID(s):: OSTI ID: 1907178

Journal Information:: Physical Review Letters, Vol. 123, Issue 17; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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References (61)

A subwavelength plasmonic metamolecule exhibiting magnetic-based optical Fano resonance Shafiei, Farbod; Monticone, Francesco; Le, Khai Q. Nature Nanotechnology, Vol. 8, Issue 2 https://doi.org/10.1038/nnano.2012.249	journal	January 2013
Mechanisms of Fano Resonances in Coupled Plasmonic Systems Lovera, Andrea; Gallinet, Benjamin; Nordlander, Peter ACS Nano, Vol. 7, Issue 5 https://doi.org/10.1021/nn401175j	journal	April 2013
Sculpting Fano Resonances To Control Photonic–Plasmonic Hybridization Thakkar, Niket; Rea, Morgan T.; Smith, Kevin C. Nano Letters, Vol. 17, Issue 11 https://doi.org/10.1021/acs.nanolett.7b03332	journal	October 2017
Fano Resonances in Electronic Transport through a Single Electron Transistor Goeres, J.; Goldhaber-Gordon, D.; Heemeyer, S. arXiv https://doi.org/10.48550/arxiv.cond-mat/9912419	text	January 1999
Combined Tight-Binding and Numerical Electrodynamics Understanding of the STEM/EELS Magneto-optical Responses of Aromatic Plasmon-Supporting Metal Oligomers Cherqui, Charles; Bigelow, Nicholas W.; Vaschillo, Alex ACS Photonics, Vol. 1, Issue 10 https://doi.org/10.1021/ph5002268	journal	September 2014
Plasmonic Response of Bent Silver Nanowires for Nanophotonic Subwavelength Waveguiding Rossouw, David; Botton, Gianluigi A. Physical Review Letters, Vol. 110, Issue 6 https://doi.org/10.1103/PhysRevLett.110.066801	journal	February 2013
Observation of Quantum Tunneling between Two Plasmonic Nanoparticles Scholl, Jonathan A.; García-Etxarri, Aitzol; Koh, Ai Leen Nano Letters, Vol. 13, Issue 2 https://doi.org/10.1021/nl304078v	journal	January 2013
Plasmonic nanosensor based on Fano resonance in waveguide-coupled resonators Lu, Hua; Liu, Xueming; Mao, Dong Optics Letters, Vol. 37, Issue 18 https://doi.org/10.1364/OL.37.003780	journal	January 2012
Diskrete Energieverluste schneller Elektronen in Festk�rpern Ruthemann, G. Die Naturwissenschaften, Vol. 29, Issue 42-43 https://doi.org/10.1007/BF01485870	journal	October 1941
Optical microresonators as single-particle absorption spectrometers Heylman, Kevin D.; Thakkar, Niket; Horak, Erik H. Nature Photonics, Vol. 10, Issue 12 https://doi.org/10.1038/nphoton.2016.217	journal	November 2016
Surface plasmon modes of a single silver nanorod: an electron energy loss study Nicoletti, Olivia; Wubs, Martijn; Mortensen, N. Asger Optics Express, Vol. 19, Issue 16 https://doi.org/10.1364/OE.19.015371	journal	January 2011
A Subwavelength Plasmonic Metamolecule Exhibiting Magnetic-Based Optical Fano Resonance Shafiei, Farbod; Monticone, Francescon; Le, Khai Q. CLEO: QELS_Fundamental Science, CLEO: 2013 https://doi.org/10.1364/cleo_qels.2013.qth1a.7	conference	January 2013
Optical excitations in electron microscopy de Abajo, F. J. Garcia arXiv https://doi.org/10.48550/arxiv.0903.1669	text	January 2009
Fano resonances in nanoscale structures Miroshnichenko, Andrey E.; Flach, Sergej; Kivshar, Yuri S. Reviews of Modern Physics, Vol. 82, Issue 3 https://doi.org/10.1103/RevModPhys.82.2257	journal	August 2010
Spatially Mapping Energy Transfer from Single Plasmonic Particles to Semiconductor Substrates via STEM/EELS Li, Guoliang; Cherqui, Charles; Bigelow, Nicholas W. Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/acs.nanolett.5b00802	journal	April 2015
Excitation dependent Fano-like interference effects in plasmonic silver nanorods Collins, Sean M.; Nicoletti, Olivia; Rossouw, David Physical Review B, Vol. 90, Issue 15 https://doi.org/10.1103/PhysRevB.90.155419	journal	October 2014
Toroidal Plasmonic Eigenmodes in Oligomer Nanocavities for the Visible Ögüt, Burcu; Talebi, Nahid; Vogelgesang, Ralf Nano Letters, Vol. 12, Issue 10 https://doi.org/10.1021/nl302418n	journal	September 2012
Self-Assembled Plasmonic Nanoparticle Clusters Fan, Jonathan; Wu, Chihhui; Bao, Kui Quantum Electronics and Laser Science Conference, Conference on Lasers and Electro-Optics 2010 https://doi.org/10.1364/qels.2010.qfc3	conference	January 2010
Mapping plasmons at the nanometer scale in an electron microscope Kociak, Mathieu; Stéphan, Odile Chemical Society Reviews, Vol. 43, Issue 11 https://doi.org/10.1039/c3cs60478k	journal	January 2014
High-Resolution Imaging and Spectroscopy of Multipolar Plasmonic Resonances in Aluminum Nanoantennas Martin, Jérôme; Kociak, Mathieu; Mahfoud, Zackaria Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl501850m	journal	September 2014
Fano-like interference of plasmon resonances at a single rod-shaped nanoantenna López-Tejeira, F.; Paniagua-Domínguez, R.; Rodríguez-Oliveros, R. New Journal of Physics, Vol. 14, Issue 2 https://doi.org/10.1088/1367-2630/14/2/023035	journal	February 2012
Probing Nanoparticle Plasmons with Electron Energy Loss Spectroscopy Wu, Yueying; Li, Guoliang; Camden, Jon P. Chemical Reviews, Vol. 118, Issue 6 https://doi.org/10.1021/acs.chemrev.7b00354	journal	December 2017
Imaging Energy Transfer in Pt-Decorated Au Nanoprisms via Electron Energy-Loss Spectroscopy Griffin, Sarah; Montoni, Nicholas P.; Li, Guoliang The Journal of Physical Chemistry Letters, Vol. 7, Issue 19 https://doi.org/10.1021/acs.jpclett.6b01878	journal	September 2016
Imaging Plasmon Hybridization of Fano Resonances via Hot-Electron-Mediated Absorption Mapping Simoncelli, Sabrina; Li, Yi; Cortés, Emiliano Nano Letters, Vol. 18, Issue 6 https://doi.org/10.1021/acs.nanolett.8b00302	journal	May 2018
Inelastic scattering of electrons by helium Callaway, Joseph Physics Letters A, Vol. 82, Issue 9 https://doi.org/10.1016/0375-9601(81)90276-0	journal	April 1981
Single Particle Plasmon Spectroscopy of Silver Nanowires and Gold Nanorods NʼGom, Moussa; Ringnalda, Jan; Mansfield, John F. Nano Letters, Vol. 8, Issue 10 https://doi.org/10.1021/nl801504v	journal	October 2008
Plasma Losses by Fast Electrons in Thin Films Ritchie, R. H. Physical Review, Vol. 106, Issue 5 https://doi.org/10.1103/PhysRev.106.874	journal	June 1957
Fano resonances in photonics Limonov, Mikhail F.; Rybin, Mikhail V.; Poddubny, Alexander N. Nature Photonics, Vol. 11, Issue 9 https://doi.org/10.1038/nphoton.2017.142	journal	September 2017
Probing decoherence through Fano resonances Bärnthaler, A.; Gehler, S.; Rotter, S. Mesoscopic Physics in Complex Media https://doi.org/10.1051/iesc/2010mpcm03008	conference	December 2010
Collision Cross-Section Studies on Molecular Gases and the Dissociation of Oxygen and Water Lassettre, Edwin N. Radiation Research Supplement, Vol. 1 https://doi.org/10.2307/3583664	journal	January 1959
High-Resolution Mapping of Electron-Beam-Excited Plasmon Modes in Lithographically Defined Gold Nanostructures Koh, Ai Leen; Fernández-Domínguez, Antonio I.; McComb, David W. Nano Letters, Vol. 11, Issue 3 https://doi.org/10.1021/nl104410t	journal	March 2011
Characterization of the Electron- and Photon-Driven Plasmonic Excitations of Metal Nanorods Bigelow, Nicholas W.; Vaschillo, Alex; Iberi, Vighter ACS Nano, Vol. 6, Issue 8 https://doi.org/10.1021/nn302980u	journal	July 2012
Signatures of Fano Interferences in the Electron Energy Loss Spectroscopy and Cathodoluminescence of Symmetry-Broken Nanorod Dimers Bigelow, Nicholas W.; Vaschillo, Alex; Camden, Jon P. ACS Nano, Vol. 7, Issue 5 https://doi.org/10.1021/nn401161n	journal	April 2013
Self-Assembled Plasmonic Nanoparticle Clusters Fan, J. A.; Wu, C.; Bao, K. Science, Vol. 328, Issue 5982 https://doi.org/10.1126/science.1187949	journal	May 2010
Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes Lourenço-Martins, Hugo; Kociak, Mathieu Physical Review X, Vol. 7, Issue 4 https://doi.org/10.1103/PhysRevX.7.041059	journal	December 2017
Tunable Fano Resonance and Plasmon-Exciton Coupling in Single Au Nanotriangles on Monolayer WS ₂ at Room Temperature Wang, Mingsong; Krasnok, Alex; Zhang, Tianyi Advanced Materials, Vol. 30, Issue 22 https://doi.org/10.1002/adma.201705779	journal	April 2018
Vibrational spectroscopy in the electron microscope Krivanek, Ondrej L.; Lovejoy, Tracy C.; Dellby, Niklas Nature, Vol. 514, Issue 7521 https://doi.org/10.1038/nature13870	journal	October 2014
Real-Space Mapping of Fano Interference in Plasmonic Metamolecules Alonso-Gonzalez, Pablo; Schnell, Martin; Sarriugarte, Paulo Nano Letters, Vol. 11, Issue 9 https://doi.org/10.1021/nl2021366	journal	September 2011
STEM/EELS Imaging of Magnetic Hybridization in Symmetric and Symmetry-Broken Plasmon Oligomer Dimers and All-Magnetic Fano Interference Cherqui, Charles; Wu, Yueying; Li, Guoliang Nano Letters, Vol. 16, Issue 10 https://doi.org/10.1021/acs.nanolett.6b03504	journal	September 2016
Probing Decoherence through Fano Resonances Bärnthaler, Andreas; Rotter, Stefan; Libisch, Florian Physical Review Letters, Vol. 105, Issue 5 https://doi.org/10.1103/PhysRevLett.105.056801	journal	July 2010
Link between Cathodoluminescence and Electron Energy Loss Spectroscopy and the Radiative and Full Electromagnetic Local Density of States Losquin, Arthur; Kociak, Mathieu ACS Photonics, Vol. 2, Issue 11 https://doi.org/10.1021/acsphotonics.5b00416	journal	October 2015
Monochromated STEM with a 30 meV-wide, atom-sized electron probe Krivanek, Ondrej L.; Lovejoy, Tracy C.; Dellby, Niklas Microscopy, Vol. 62, Issue 1 https://doi.org/10.1093/jmicro/dfs089	journal	January 2013
Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H ₂ on Au Mukherjee, Shaunak; Libisch, Florian; Large, Nicolas Nano Letters, Vol. 13, Issue 1 https://doi.org/10.1021/nl303940z	journal	December 2012
Fano resonances in nanoscale structures Miroshnichenko, Andrey E.; Flach, Sergej; Kivshar, Yuri S. arXiv https://doi.org/10.48550/arxiv.0902.3014	text	January 2009
Characterizing localized surface plasmons using electron energy-loss spectroscopy Cherqui, Charles; Thakkar, Niket; Li, Guoliang arXiv https://doi.org/10.48550/arxiv.1509.08430	text	January 2015
Tunable Spectral Ordering of Magnetic Plasmon Resonances in Noble Metal Nanoclusters Montoni, Nicholas P.; Quillin, Steven C.; Cherqui, Charles ACS Photonics, Vol. 5, Issue 8 https://doi.org/10.1021/acsphotonics.8b00519	journal	May 2018
Tunable Fano resonances in transport through microwave billiards Rotter, S.; Libisch, F.; Burgdörfer, J. Physical Review E, Vol. 69, Issue 4 https://doi.org/10.1103/PhysRevE.69.046208	journal	April 2004
Multipolar Plasmonic Resonances in Silver Nanowire Antennas Imaged with a Subnanometer Electron Probe Rossouw, D.; Couillard, M.; Vickery, J. Nano Letters, Vol. 11, Issue 4 https://doi.org/10.1021/nl200634w	journal	April 2011
Effects of Configuration Interaction on Intensities and Phase Shifts Fano, U. Physical Review, Vol. 124, Issue 6 https://doi.org/10.1103/PhysRev.124.1866	journal	December 1961
Symmetry Breaking in Plasmonic Nanocavities: Subradiant LSPR Sensing and a Tunable Fano Resonance Hao, Feng; Sonnefraud, Yannick; Dorpe, Pol Van Nano Letters, Vol. 8, Issue 11 https://doi.org/10.1021/nl802509r	journal	November 2008
Characterizing Localized Surface Plasmons Using Electron Energy-Loss Spectroscopy Cherqui, Charles; Thakkar, Niket; Li, Guoliang Annual Review of Physical Chemistry, Vol. 67, Issue 1 https://doi.org/10.1146/annurev-physchem-040214-121612	journal	May 2016
Strong coupling, energy splitting, and level crossings: A classical perspective Novotny, Lukas American Journal of Physics, Vol. 78, Issue 11 https://doi.org/10.1119/1.3471177	journal	November 2010
Electromagnetically induced transparency in optical microcavities Liu, Yong-Chun; Li, Bei-Bei; Xiao, Yun-Feng Nanophotonics, Vol. 6, Issue 5 https://doi.org/10.1515/nanoph-2016-0168	journal	March 2017
Optical excitations in electron microscopy García de Abajo, F. J. Reviews of Modern Physics, Vol. 82, Issue 1 https://doi.org/10.1103/RevModPhys.82.209	journal	February 2010
Switching from Visibility to Invisibility via Fano Resonances: Theory and Experiment Rybin, Mikhail V.; Filonov, Dmitry S.; Belov, Pavel A. Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep08774	journal	March 2015
Classical and quantum distinctions between weak and strong coupling Rodriguez, Said Rahimzadeh-Kalaleh European Journal of Physics, Vol. 37, Issue 2 https://doi.org/10.1088/0143-0807/37/2/025802	journal	January 2016
Fano resonances in electronic transport through a single-electron transistor Göres, J.; Goldhaber-Gordon, D.; Heemeyer, S. Physical Review B, Vol. 62, Issue 3 https://doi.org/10.1103/PhysRevB.62.2188	journal	July 2000
Nanoplasmonics: Classical down to the Nanometer Scale Duan, Huigao; Fernández-Domínguez, Antonio I.; Bosman, Michel Nano Letters, Vol. 12, Issue 3 https://doi.org/10.1021/nl3001309	journal	February 2012
Inelastic Scattering of Electrons by Helium Lassettre, E. N.; Krasnow, M. E.; Silverman, S. The Journal of Chemical Physics, Vol. 40, Issue 5 https://doi.org/10.1063/1.1725303	journal	March 1964
Mapping vibrational surface and bulk modes in a single nanocube Lagos, Maureen J.; Trügler, Andreas; Hohenester, Ulrich Nature, Vol. 543, Issue 7646 https://doi.org/10.1038/nature21699	journal	March 2017
Mode Parity-Controlled Fano- and Lorentz-like Line Shapes Arising in Plasmonic Nanorods Verellen, Niels; López-Tejeira, Fernando; Paniagua-Domínguez, Ramón Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl404670x	journal	April 2014

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FIG. 3(p. 8)

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Title: Direct Observation of Infrared Plasmonic Fano Antiresonances by a Nanoscale Electron Probe

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