RE3Mo14O30 and RE2Mo 9O19, Two Reduced Rare-Earth Molybdates with Honeycomb-Related Structures (RE = La–Pr)

Forbes, Scott; Kong, Tai; Cava, Robert J.

doi:10.1021/acs.inorgchem.7b03197

Title: RE₃Mo₁₄O₃₀ and RE₂Mo ₉O₁₉, Two Reduced Rare-Earth Molybdates with Honeycomb-Related Structures (RE = La–Pr)

Journal Article · Thu Mar 22 00:00:00 EDT 2018 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.7b03197· OSTI ID:1595087

^[1]; Kong, Tai ^[1]; Cava, Robert J. ^[1]

Princeton Univ., NJ (United States). Dept. of Chemistry

The previously unreported RE₃Mo₁₄O₃₀ and RE₂Mo₉O₁₉ phases were synthesized in vacuo from rare-earth oxides, molybdenum oxide, and molybdenum metal using halide fluxes at 875-1000 °C. Both phases adopt structures in the triclinic $$P\overline1$$ space group albeit with several notable differences. The structures display an ordering of layers along the a direction of the unit cell, forming distinct honeycomb-related lattice arrangements composed of MoO₆ octahedra and vacancies. Mo-Mo bonding and clusters are present; the RE₃Mo₁₄O₃₀ structure contains Mo dimers and rhomboid tetramers, while the RE₂Mo₉O₁₉ structure contains rhomboid tetramers and an unusual arrangement of planar tetramers, pentamers, and hexamers. The magnetic measurements found the RE₂Mo₉O₁₉phases to be simple paramagnets, while La₃Mo₁₄O₃₀ was observed to order antiferromagnetically at 18 K. Finally, electrical resistivity measurements confirmed all of the samples to behave as nondegenerate semiconductors.

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Research Organization:: Princeton Univ., NJ (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-98ER45706

OSTI ID:: 1595087

Journal Information:: Inorganic Chemistry, Vol. 57, Issue 7; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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CSD 1815541: Experimental Crystal Structure Determination Scott, Forbes,; Tai, Kong,; J., Cava, Robert https://doi.org/10.5517/ccdc.csd.cc1yy6vy The current record is supplemented by this dataset	dataset	January 2018
CSD 1815543: Experimental Crystal Structure Determination Scott, Forbes,; Tai, Kong,; J., Cava, Robert https://doi.org/10.5517/ccdc.csd.cc1yy6x0 The current record is supplemented by this dataset	dataset	January 2018
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Title: RE3Mo14O30 and RE2Mo 9O19, Two Reduced Rare-Earth Molybdates with Honeycomb-Related Structures (RE = La–Pr)

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