Carbon dioxide reduction in tandem with light-alkane dehydrogenation

Gomez, Elaine; Yan, Binhang; Kattel, Shyam; Chen, Jingguang G.

doi:10.1038/s41570-019-0128-9

Title: Carbon dioxide reduction in tandem with light-alkane dehydrogenation

Journal Article · Tue Sep 10 00:00:00 EDT 2019 · Nature Reviews Chemistry

DOI:https://doi.org/10.1038/s41570-019-0128-9· OSTI ID:1580234

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Columbia Univ., New York, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Tsinghua Univ., Beijing (China)
Columbia Univ., New York, NY (United States); Florida A & M University, Tallahassee, FL (United States)
Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

A greenhouse gas and mild oxidant, CO₂ can effect the oxidative dehydrogenation (CO₂-ODH) of light alkanes over heterogeneous catalysts. These catalysts are bifunctional in that they mediate CO₂ reduction while oxidizing the alkanes, most notably the C₂–C₄ components in shale gas. In this way, one obtains CO and alkenes as value-added products. Although desirable, this transformation has proven challenging in terms of catalyst design, with most catalysts for the CO₂-ODH being metal oxides that typically undergo rapid deactivation. More recently, bimetallic catalysts have been identified as promising systems to activate alkanes by either selectively cleaving C–H bonds to produce alkenes or breaking all the C–C and C–H bonds to produce the dry reforming products CO and H₂. This Review describes general trends in the CO₂-ODH of light alkanes. Furthermore, we will outline how to use a combined approach involving flow reactor experiments, in operando characterization and density functional theory to determine whether a catalyst is intrinsically active for CO₂-ODH or dry reforming.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: SC0012704

OSTI ID:: 1580234

Report Number(s):: BNL-212449-2019-JAAM

Journal Information:: Nature Reviews Chemistry, Vol. 3, Issue 11; ISSN 2397-3358

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 96 works

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Atomic Layer Deposition for Preparing Isolated Co Sites on SiO2 for Ethane Dehydrogenation Catalysis Huang, Renjing; Cheng, Yuan; Ji, Yichen Nanomaterials, Vol. 10, Issue 2 https://doi.org/10.3390/nano10020244	journal	January 2020

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