Introduction of nitrogen with controllable configuration into graphene via vacancies and edges

Wang, Bin; Tsetseris, Leonidas; Pantelides, Sokrates T.

doi:10.1039/c3ta13610h

Title: Introduction of nitrogen with controllable configuration into graphene via vacancies and edges

Journal Article · Fri Oct 11 00:00:00 EDT 2013 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c3ta13610h· OSTI ID:1564996

Wang, Bin ^[1]; Tsetseris, Leonidas ^[2]; Pantelides, Sokrates T. ^[3]

Vanderbilt Univ., Nashville, TN (United States). Dept. of Physics and Astronomy
Vanderbilt Univ., Nashville, TN (United States). Dept. of Physics and Astronomy; National Technical Univ. of Athens, Athens (Greece). Dept. of Physics
Vanderbilt Univ., Nashville, TN (United States). Dept. of Physics and Astronomy, and Dept. of Electrical Engineering and Computer Science; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Doping with nitrogen in controllable configurations is very valuable to tailor the properties of graphene. Here we report density-functional theory calculations of chemical reactions of ammonia, a widely used nitrogen source, at vacancies and edges of graphene, through which we explore strategies to achieve N-doped graphene with optimized properties. Here, we show that at different defects, ammonia reacts to form nitrogen impurities in distinct configurations, i.e. graphitic-N at single vacancies, pyridinic- or pyrrolic-N at divacancies, pyrrolic-N at armchair edges, and N in a four-member ring at zigzag edges. Moreover, different nitrogen-related defect configurations introduce distinct changes in the electronic structure of graphene. By calculating the core level shift of C_1s electrons, we find configuration-dependent redistribution of electrons around the N-dopant. A discussion of how to achieve optimized doping and enhanced chemical reactivity in experiments is included.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)

Sponsoring Organization:: USDOE Office of Science (SC)

OSTI ID:: 1564996

Journal Information:: Journal of Materials Chemistry. A, Vol. 1, Issue 47; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 36 works

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References (79)

Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction Liu, Ruili; Wu, Dongqing; Feng, Xinliang Angewandte Chemie International Edition, Vol. 49, Issue 14, p. 2565-2569 https://doi.org/10.1002/anie.200907289	journal	March 2010
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Catalyst-Free Synthesis of Nitrogen-Doped Graphene via Thermal Annealing Graphite Oxide with Melamine and Its Excellent Electrocatalysis Sheng, Zhen-Huan; Shao, Lin; Chen, Jing-Jing ACS Nano, Vol. 5, Issue 6 https://doi.org/10.1021/nn103584t	journal	May 2011
Nitrogen-Doped Graphene: Efficient Growth, Structure, and Electronic Properties Usachov, D.; Vilkov, O.; Grüneis, A. Nano Letters, Vol. 11, Issue 12 https://doi.org/10.1021/nl2031037	journal	December 2011
Theory of nitrogen doping of carbon nanoribbons: Edge effects Jiang, Jie; Turnbull, Joseph; Lu, Wenchang The Journal of Chemical Physics, Vol. 136, Issue 1 https://doi.org/10.1063/1.3673441	journal	January 2012
Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction Gong, K.; Du, F.; Xia, Z. Science, Vol. 323, Issue 5915, p. 760-764 https://doi.org/10.1126/science.1168049	journal	February 2009
Controlled Formation of Sharp Zigzag and Armchair Edges in Graphitic Nanoribbons Jia, X.; Hofmann, M.; Meunier, V. Science, Vol. 323, Issue 5922 https://doi.org/10.1126/science.1166862	journal	March 2009
Connecting Dopant Bond Type with Electronic Structure in N-Doped Graphene Schiros, Theanne; Nordlund, Dennis; Pálová, Lucia Nano Letters, Vol. 12, Issue 8 https://doi.org/10.1021/nl301409h	journal	July 2012
Electronic and optical properties of nitrogen-doped multiwalled carbon nanotubes Lim, S. H.; Elim, H. I.; Gao, X. Y. Physical Review B, Vol. 73, Issue 4 https://doi.org/10.1103/PhysRevB.73.045402	journal	January 2006
Identification of the nitrogen species on N-doped graphene layers and Pt/NG composite catalyst for direct methanol fuel cell Zhang, Le-Sheng; Liang, Xian-Qing; Song, Wei-Guo Physical Chemistry Chemical Physics, Vol. 12, Issue 38 https://doi.org/10.1039/c0cp00789g	journal	January 2010
Magnetic moment of a single vacancy in graphene and semiconducting nanoribbons Wang, Bin; Pantelides, Sokrates T. Physical Review B, Vol. 86, Issue 16 https://doi.org/10.1103/PhysRevB.86.165438	journal	October 2012
Biological and chemical sensors based on graphene materials Liu, Yuxin; Dong, Xiaochen; Chen, Peng Chem. Soc. Rev., Vol. 41, Issue 6 https://doi.org/10.1039/C1CS15270J	journal	January 2012
Visualizing Individual Nitrogen Dopants in Monolayer Graphene Zhao, L.; He, R.; Rim, K. T. Science, Vol. 333, Issue 6045 https://doi.org/10.1126/science.1208759	journal	August 2011
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Pyridinic N doped graphene: synthesis, electronic structure, and electrocatalytic property Luo, Zhiqiang; Lim, Sanhua; Tian, Zhiqun Journal of Materials Chemistry, Vol. 21, Issue 22 https://doi.org/10.1039/c1jm10845j	journal	January 2011
Toward N-Doped Graphene via Solvothermal Synthesis Deng, Dehui; Pan, Xiulian; Yu, Liang Chemistry of Materials, Vol. 23, Issue 5 https://doi.org/10.1021/cm102666r	journal	March 2011
Simultaneous Nitrogen Doping and Reduction of Graphene Oxide Li, Xiaolin; Wang, Hailiang; Robinson, Joshua T. Journal of the American Chemical Society, Vol. 131, Issue 43 https://doi.org/10.1021/ja907098f	journal	November 2009
First principle calculations of the electronic properties of nitrogen-doped carbon nanoribbons with zigzag edges Yu, S. S.; Zheng, W. T.; Wen, Q. B. Carbon, Vol. 46, Issue 3 https://doi.org/10.1016/j.carbon.2008.01.006	journal	March 2008
Nitrogen-doped graphene: beyond single substitution and enhanced molecular sensing Lv, Ruitao; Li, Qing; Botello-Méndez, Andrés R. Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00586	journal	August 2012
Structural, magnetic, and transport properties of substitutionally doped graphene nanoribbons from first principles Cruz-Silva, E.; Barnett, Z. M.; Sumpter, B. G. Physical Review B, Vol. 83, Issue 15 https://doi.org/10.1103/PhysRevB.83.155445	journal	April 2011
Graphene: Electronic and Photonic Properties and Devices Avouris, Phaedon Nano Letters, Vol. 10, Issue 11, p. 4285-4294 https://doi.org/10.1021/nl102824h	journal	November 2010
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
Atomistic simulations of the implantation of low-energy boron and nitrogen ions into graphene Åhlgren, E. H.; Kotakoski, J.; Krasheninnikov, A. V. Physical Review B, Vol. 83, Issue 11 https://doi.org/10.1103/PhysRevB.83.115424	journal	March 2011
Two-Step Boron and Nitrogen Doping in Graphene for Enhanced Synergistic Catalysis Zheng, Yao; Jiao, Yan; Ge, Lei Angewandte Chemie International Edition, Vol. 52, Issue 11 https://doi.org/10.1002/anie.201209548	journal	January 2013
Edge-functionalized and substitutionally doped graphene nanoribbons: Electronic and spin properties Cervantes-Sodi, F.; Csányi, G.; Piscanec, S. Physical Review B, Vol. 77, Issue 16 https://doi.org/10.1103/PhysRevB.77.165427	journal	April 2008
Nitrogen-Doped Colloidal Graphene Quantum Dots and Their Size-Dependent Electrocatalytic Activity for the Oxygen Reduction Reaction Li, Qiqi; Zhang, Sheng; Dai, Liming Journal of the American Chemical Society, Vol. 134, Issue 46 https://doi.org/10.1021/ja309270h	journal	November 2012
Molecular doping of graphene with ammonium groups Tsetseris, L.; Pantelides, S. T. Physical Review B, Vol. 85, Issue 15 https://doi.org/10.1103/PhysRevB.85.155446	journal	April 2012
Controllable N-Doping of Graphene Guo, Beidou; Liu, Qian; Chen, Erdan Nano Letters, Vol. 10, Issue 12 https://doi.org/10.1021/nl103079j	journal	December 2010
Controllable graphene N-doping with ammonia plasma Lin, Yung-Chang; Lin, Chih-Yueh; Chiu, Po-Wen Applied Physics Letters, Vol. 96, Issue 13 https://doi.org/10.1063/1.3368697	journal	March 2010
From Point Defects in Graphene to Two-Dimensional Amorphous Carbon Kotakoski, J.; Krasheninnikov, A. V.; Kaiser, U. Physical Review Letters, Vol. 106, Issue 10 https://doi.org/10.1103/PhysRevLett.106.105505	journal	March 2011
Atomic Covalent Functionalization of Graphene Johns, James E.; Hersam, Mark C. Accounts of Chemical Research, Vol. 46, Issue 1 https://doi.org/10.1021/ar300143e	journal	September 2012
Nitrogen-Doped Graphene and Its Application in Electrochemical Biosensing Wang, Ying; Shao, Yuyan; Matson, Dean W. ACS Nano, Vol. 4, Issue 4 https://doi.org/10.1021/nn100315s	journal	March 2010
Structural Defects in Graphene Banhart, Florian; Kotakoski, Jani; Krasheninnikov, Arkady V. ACS Nano, Vol. 5, Issue 1 https://doi.org/10.1021/nn102598m	journal	November 2010
Experimental analysis of charge redistribution due to chemical bonding by high-resolution transmission electron microscopy Meyer, Jannik C.; Kurasch, Simon; Park, Hye Jin Nature Materials, Vol. 10, Issue 3 https://doi.org/10.1038/nmat2941	journal	January 2011
Review on Recent Progress in Nitrogen-Doped Graphene: Synthesis, Characterization, and Its Potential Applications Wang, Haibo; Maiyalagan, Thandavarayan; Wang, Xin ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs200652y	journal	April 2012
Functionalization of Graphene: Covalent and Non-Covalent Approaches, Derivatives and Applications Georgakilas, Vasilios; Otyepka, Michal; Bourlinos, Athanasios B. Chemical Reviews, Vol. 112, Issue 11 https://doi.org/10.1021/cr3000412	journal	September 2012
Ion Implantation of Graphene—Toward IC Compatible Technologies Bangert, U.; Pierce, W.; Kepaptsoglou, D. M. Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl402812y	journal	September 2013
B, N- and P, N-doped graphene as highly active catalysts for oxygen reduction reactions in acidic media Choi, Chang Hyuck; Chung, Min Wook; Kwon, Han Chang Journal of Materials Chemistry A, Vol. 1, Issue 11 https://doi.org/10.1039/c3ta01648j	journal	January 2013
Extraordinary supercapacitor performance of heavily nitrogenated graphene oxide obtained by microwave synthesis Gopalakrishnan, K.; Govindaraj, A.; Rao, C. N. R. Journal of Materials Chemistry A, Vol. 1, Issue 26 https://doi.org/10.1039/c3ta11385j	journal	January 2013
Electronic and structural characterization of divacancies in irradiated graphene Ugeda, Miguel M.; Brihuega, Iván; Hiebel, Fanny Physical Review B, Vol. 85, Issue 12 https://doi.org/10.1103/PhysRevB.85.121402	journal	March 2012
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells Qu, Liangti; Liu, Yong; Baek, Jong-Beom ACS Nano, Vol. 4, Issue 3, p. 1321-1326 https://doi.org/10.1021/nn901850u	journal	February 2010
High-performance electrochemical pseudo-capacitor based on MnO2 nanowires/Ni foam as electrode with a novel Li-ion quasi-ionic liquid as electrolyte Deng, Ming-Jay; Chang, Jeng-Kuei; Wang, Cheng-Chia Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01603b	journal	January 2011
Electronic and Transport Properties of Unbalanced Sublattice N-Doping in Graphene Lherbier, Aurélien; Botello-Méndez, Andrés Rafael; Charlier, Jean-Christophe Nano Letters, Vol. 13, Issue 4 https://doi.org/10.1021/nl304351z	journal	March 2013
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Co₃O₄ nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction Liang, Yongye; Li, Yanguang; Wang, Hailiang Nature Materials, Vol. 10, Issue 10, p. 780-786 https://doi.org/10.1038/nmat3087	journal	August 2011
Nitrogen-Doped Graphene for High-Performance Ultracapacitors and the Importance of Nitrogen-Doped Sites at Basal Planes Jeong, Hyung Mo; Lee, Jung Woo; Shin, Weon Ho Nano Letters, Vol. 11, Issue 6 https://doi.org/10.1021/nl2009058	journal	June 2011
Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties Wei, Dacheng; Liu, Yunqi; Wang, Yu Nano Letters, Vol. 9, Issue 5 https://doi.org/10.1021/nl803279t	journal	May 2009
Core-level shifts in complex metallic systems from first principle Olovsson, Weine; Göransson, Christian; Marten, Tobias physica status solidi (b), Vol. 243, Issue 11 https://doi.org/10.1002/pssb.200642165	journal	September 2006
Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells Zhang, Lipeng; Xia, Zhenhai The Journal of Physical Chemistry C, Vol. 115, Issue 22 https://doi.org/10.1021/jp201991j	journal	May 2011
Doped Graphene Sheets As Anode Materials with Superhigh Rate and Large Capacity for Lithium Ion Batteries Wu, Zhong-Shuai; Ren, Wencai; Xu, Li ACS Nano, Vol. 5, Issue 7 https://doi.org/10.1021/nn2006249	journal	June 2011
Workfunction-Tunable, N-Doped Reduced Graphene Transparent Electrodes for High-Performance Polymer Light-Emitting Diodes Hwang, Jin Ok; Park, Ji Sun; Choi, Dong Sung ACS Nano, Vol. 6, Issue 1 https://doi.org/10.1021/nn203176u	journal	December 2011
Anomalous Doping Effects on Charge Transport in Graphene Nanoribbons Biel, Blanca; Blase, X.; Triozon, François Physical Review Letters, Vol. 102, Issue 9 https://doi.org/10.1103/PhysRevLett.102.096803	journal	March 2009
Missing Atom as a Source of Carbon Magnetism Ugeda, M. M.; Brihuega, I.; Guinea, F. Physical Review Letters, Vol. 104, Issue 9 https://doi.org/10.1103/PhysRevLett.104.096804	journal	March 2010
Pyrrolic-structure enriched nitrogen doped graphene for highly efficient next generation supercapacitors Hassan, Fathy M.; Chabot, Victor; Li, Jingde Journal of Materials Chemistry A, Vol. 1, Issue 8 https://doi.org/10.1039/c2ta01064j	journal	January 2013
Ion and electron irradiation-induced effects in nanostructured materials Krasheninnikov, A. V.; Nordlund, K. Journal of Applied Physics, Vol. 107, Issue 7 https://doi.org/10.1063/1.3318261	journal	April 2010
A roadmap for graphene Novoselov, K. S.; Fal′ko, V. I.; Colombo, L. Nature, Vol. 490, Issue 7419 https://doi.org/10.1038/nature11458	journal	October 2012
Graphene-Based Materials for Energy Conversion Sahoo, Nanda Gopal; Pan, Yongzheng; Li, Lin Advanced Materials, Vol. 24, Issue 30 https://doi.org/10.1002/adma.201104971	journal	May 2012
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism Vanderbilt, David Physical Review B, Vol. 41, Issue 11, p. 7892-7895 https://doi.org/10.1103/PhysRevB.41.7892	journal	April 1990
Carbon Monoxide-Tolerant Platinum Nanoparticle Catalysts on Defect-Engineered Graphene Kim, Gyubong; Jhi, Seung-Hoon ACS Nano, Vol. 5, Issue 2 https://doi.org/10.1021/nn1017395	journal	January 2011
The edges of graphene Zhang, Xiuyun; Xin, John; Ding, Feng Nanoscale, Vol. 5, Issue 7 https://doi.org/10.1039/c3nr34009k	journal	January 2013
Atomistic Description of Electron Beam Damage in Nitrogen-Doped Graphene and Single-Walled Carbon Nanotubes Susi, Toma; Kotakoski, Jani; Arenal, Raul ACS Nano, Vol. 6, Issue 10 https://doi.org/10.1021/nn303944f	journal	September 2012
Nitrogen-doped graphene and its electrochemical applications Shao, Yuyan; Zhang, Sheng; Engelhard, Mark H. Journal of Materials Chemistry, Vol. 20, Issue 35 https://doi.org/10.1039/c0jm00782j	journal	January 2010
Graphene at the Edge: Stability and Dynamics Girit, C. O.; Meyer, J. C.; Erni, R. Science, Vol. 323, Issue 5922 https://doi.org/10.1126/science.1166999	journal	March 2009
Critical analysis of vacancy-induced magnetism in monolayer and bilayer graphene Palacios, J. J.; Ynduráin, F. Physical Review B, Vol. 85, Issue 24 https://doi.org/10.1103/PhysRevB.85.245443	journal	June 2012
Embedding Transition-Metal Atoms in Graphene: Structure, Bonding, and Magnetism Krasheninnikov, A. V.; Lehtinen, P. O.; Foster, A. S. Physical Review Letters, Vol. 102, Issue 12 https://doi.org/10.1103/PhysRevLett.102.126807	journal	March 2009
Defects and doping and their role in functionalizing graphene Pantelides, Sokrates T.; Puzyrev, Yevgeniy; Tsetseris, Leonidas MRS Bulletin, Vol. 37, Issue 12 https://doi.org/10.1557/mrs.2012.187	journal	November 2012
X-ray absorption analysis of nitrogen contribution to oxygen reduction reaction in carbon alloy cathode catalysts for polymer electrolyte fuel cells Niwa, Hideharu; Horiba, Koji; Harada, Yoshihisa Journal of Power Sources, Vol. 187, Issue 1, p. 93-97 https://doi.org/10.1016/j.jpowsour.2008.10.064	journal	February 2009
N-Doping of Graphene Through Electrothermal Reactions with Ammonia Wang, Xinran; Li, Xiaolin; Zhang, Li Science, Vol. 324, Issue 5928, p. 768-771 https://doi.org/10.1126/science.1170335	journal	May 2009
Graphene Photonics, Plasmonics, and Broadband Optoelectronic Devices Bao, Qiaoliang; Loh, Kian Ping ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn300989g	journal	May 2012
Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method Li, Nan; Wang, Zhiyong; Zhao, Keke Carbon, Vol. 48, Issue 1 https://doi.org/10.1016/j.carbon.2009.09.013	journal	January 2010
Controllable healing of defects and nitrogen doping of graphene by CO and NO molecules Wang, B.; Pantelides, S. T. Physical Review B, Vol. 83, Issue 24 https://doi.org/10.1103/PhysRevB.83.245403	journal	June 2011
Charge Transport in Chemically Doped 2D Graphene Lherbier, Aurélien; Blase, X.; Niquet, Yann-Michel Physical Review Letters, Vol. 101, Issue 3 https://doi.org/10.1103/PhysRevLett.101.036808	journal	July 2008
Nitrogen-Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction Liu, Ruili; Wu, Dongqing; Feng, Xinliang Angewandte Chemie, Vol. 122, Issue 14, p. 2619-2623 https://doi.org/10.1002/ange.200907289	journal	March 2010
Two-Step Boron and Nitrogen Doping in Graphene for Enhanced Synergistic Catalysis Zheng, Yao; Jiao, Yan; Ge, Lei Angewandte Chemie, Vol. 125, Issue 11 https://doi.org/10.1002/ange.201209548	journal	January 2013
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
Pyrrolic-Structure Enriched Nitrogen Doped Graphene for Highly Efficient Next Generation Supercapacitors Yu, Aiping; Chabot, Victor; Hassan, Fathy Mohamed ECS Meeting Abstracts, Vol. MA2013-01, Issue 11 https://doi.org/10.1149/ma2013-01/11/554	journal	March 2013
Anomalous Doping Effects on Charge Transport in Graphene Nanoribbons Biel, Blanca; Blase, X.; Triozon, François arXiv https://doi.org/10.48550/arxiv.0902.2730	text	January 2009
Visualizing Individual Nitrogen Dopants in Monolayer Graphene Zhao, Liuyan; He, Rui; Rim, Kwang Taeg arXiv https://doi.org/10.48550/arxiv.1108.4026	text	January 2011
A critical analysis of vacancy-induced magnetism in mono and bilayer graphene Palacios, J. J.; Yndurain, F. arXiv https://doi.org/10.48550/arxiv.1203.6485	text	January 2012

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