Influence of a Pre-organized N-Donor Group on the Coordination of Trivalent Actinides and Lanthanides by an Aminopolycarboxylate Complexant

Heathman, Colt R.; Grimes, Travis S.; Jansone-Popova, Santa; Roy, Santanu; Bryantsev, Vyacheslav S.; Zalupski, Peter R.

doi:10.1002/chem.201804723

Title: Influence of a Pre-organized N-Donor Group on the Coordination of Trivalent Actinides and Lanthanides by an Aminopolycarboxylate Complexant

Journal Article · Mon Jan 21 00:00:00 EST 2019 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201804723· OSTI ID:1564104

^[1];

^[2];

^[1]

Idaho National Lab. (INL), Idaho Falls, ID (United States). Aqueous Separations and Radiochemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Thermodynamic influence of a pre-organized N-donor group on the coordination of trivalent actinides and lanthanides by aminopolycarboxylate aqueous complexant was investigated. The synthesized complexant N-2-methylpicolinate-ethylenediamine-N,N',N'-triacetic acid, EDTA-Mpic, resembles ethylenediamine-N,N,N',N'-tetraacetic acid, EDTA, with single acetate pendant arm replaced by 6-carboxypyridin-2-yl-methyl group. The rigidified N-donor picolinate functionality shows profound impact on the ligand protonation, and trivalent f-element complexation equilibria as demonstrated using potentiometric, spectroscopic, liquid-liquid metal partitioning studies and molecular dynamics calculations. While the coordination pocket of EDTA-Mpic is somewhat hardened by the N-methylpicolinate the substantial amplification of its total acidity offers the advantage of sustaining metal complexation in aqueous mixtures of unprecedented acidity for this class of reagents. As a result the EDTA-Mpic complexant may be considered the best option for efficient f-element recovery and An3+/Ln3+ differentiation in acidic media.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC05-00OR22725; DE-AC07-05ID14517

OSTI ID:: 1564104

Alternate ID(s):: OSTI ID: 1596093; OSTI ID: 1635428

Report Number(s):: INL/JOU-18-51606-Rev001; TRN: US2000855

Journal Information:: Chemistry - A European Journal, Vol. 25, Issue 10; ISSN 0947-6539

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 8 works

Citation information provided by
Web of Science

References (85)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
A new heptadentate picolinate-based ligand and its corresponding Gd( iii ) complex: the effect of pendant picolinate versus acetate on complex properties Phukan, Bedika; Mukherjee, Chandan; Varshney, Raunak Dalton Transactions, Vol. 47, Issue 1 https://doi.org/10.1039/C7DT04150K	journal	January 2018
Actinide Lanthanide Separation Process—ALSEP Gelis, Artem V.; Lumetta, Gregg J. Industrial & Engineering Chemistry Research, Vol. 53, Issue 4 https://doi.org/10.1021/ie403569e	journal	January 2014
Lanthanide and Actinide Chemistry Cotton, Simon Wiley https://doi.org/10.1002/0470010088	book	January 2006
A half-century of lanthanide aminopolycarboxylates Choppin, Gregory R. Journal of Alloys and Compounds, Vol. 192, Issue 1-2 https://doi.org/10.1016/0925-8388(93)90243-G	journal	February 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Complexation kinetics of f-elements and polydentate ligands Choppin, Gregory R. Journal of Alloys and Compounds, Vol. 225, Issue 1-2 https://doi.org/10.1016/0925-8388(94)07068-7	journal	July 1995
Complexation of Actinide(III) and Lanthanide(III) with H ₄ TPAEN for a Separation of Americium from Curium and Lanthanides Boubals, Nathalie; Wagner, Christoph; Dumas, Thomas Inorganic Chemistry, Vol. 56, Issue 14 https://doi.org/10.1021/acs.inorgchem.7b00603	journal	June 2017
The absorption spectrum of aqueous curium (III) Carnall, W. T.; Fields, P. R.; Stewart, D. C. Journal of Inorganic and Nuclear Chemistry, Vol. 6, Issue 3 https://doi.org/10.1016/0022-1902(58)80150-5	journal	June 1958
Kinetics and Mechanism of the Interfacial Mass Transfer of Eu(III) in the System: Bis(2-ethylhexyl)phosphoric Acid, n -Dodecane-NaCl, Lactic Acid, Polyaminocarboxylic Acid, Water Danesi, P. R.; Cianetti, C. Separation Science and Technology, Vol. 17, Issue 7 https://doi.org/10.1080/01496398208082107	journal	May 1982
A spectrophotometric study of Am( iii ) complexation with nitrate in aqueous solution at elevated temperatures Tian, Guoxin; Shuh, David K. Dalton Trans., Vol. 43, Issue 39 https://doi.org/10.1039/C4DT01183J	journal	January 2014
H ₄ octapa: synthesis, solution equilibria and complexes with useful radiopharmaceutical metal ions Jaraquemada-Peláez, María de Guadalupe; Wang, Xiaozhu; Clough, Thomas J. Dalton Transactions, Vol. 46, Issue 42 https://doi.org/10.1039/C7DT02343J	journal	January 2017
Potentiometric titrations using Gran plots: A textbook omission Rossotti, F. J. C.; Rossotti, Hazel Journal of Chemical Education, Vol. 42, Issue 7 https://doi.org/10.1021/ed042p375	journal	July 1965
Chelate ring size and metal ion selection. The basis of selectivity for metal ions in open-chain ligands and macrocycles Hancock, Robert D. Journal of Chemical Education, Vol. 69, Issue 8 https://doi.org/10.1021/ed069p615	journal	August 1992
The Chemistry of TALSPEAK: A Review of the Science Nash, Kenneth L. Solvent Extraction and Ion Exchange, Vol. 33, Issue 1 https://doi.org/10.1080/07366299.2014.985912	journal	December 2014
Reaction Rate Theory in Coordination Number Space: An Application to Ion Solvation Roy, Santanu; Baer, Marcel D.; Mundy, Christopher J. The Journal of Physical Chemistry C, Vol. 120, Issue 14 https://doi.org/10.1021/acs.jpcc.6b00443	journal	March 2016
Equilibrium and NMR studies on Gd ^III , Y ^III , Cu ^II and Zn ^II complexes of various DTPA–N,N″-bis(amide) ligands. Kinetic stabilities of the gadolinium( iii ) complexes Jászberényi, Zoltán; Bányai, István; Brücher, Ernö Dalton Trans., Issue 8 https://doi.org/10.1039/B514173G	journal	January 2006
Stability, Water Exchange, and Anion Binding Studies on Lanthanide(III) Complexes with a Macrocyclic Ligand Based on 1,7-Diaza-12-crown-4: Extremely Fast Water Exchange on the Gd ³⁺ Complex Pálinkás, Zoltán; Roca-Sabio, Adrián; Mato-Iglesias, Marta Inorganic Chemistry, Vol. 48, Issue 18 https://doi.org/10.1021/ic9011197	journal	September 2009
Complexation thermodynamics and structural aspects of actinide–aminopolycarboxylates Choppin, G.; Thakur, P.; Mathur, J. Coordination Chemistry Reviews, Vol. 250, Issue 7-8 https://doi.org/10.1016/j.ccr.2006.02.003	journal	April 2006
Optical properties of Cm(III) in crystals and solutions and their application to Cm(III) speciation Edelstein, Norman M.; Klenza, Reinhardt; Fanghanel, Thomas Coordination Chemistry Reviews, Vol. 250, Issue 7-8, p. 948-973 https://doi.org/10.1016/j.ccr.2006.02.004	journal	April 2006
Lanthanide dota-like Complexes Containing a Picolinate Pendant: Structural Entry for the Design of Ln ^III -Based Luminescent Probes Regueiro-Figueroa, Martín; Bensenane, Bachir; Ruscsák, Erika Inorganic Chemistry, Vol. 50, Issue 9 https://doi.org/10.1021/ic2001915	journal	May 2011
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
A critical review on solvent extraction of rare earths from aqueous solutions Xie, Feng; Zhang, Ting An; Dreisinger, David Minerals Engineering, Vol. 56 https://doi.org/10.1016/j.mineng.2013.10.021	journal	February 2014
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Determination of the Equivalent Point in Potentiometric Titrations. Gran, Gunnar; Dahlenborg, Hans; Laurell, S. Acta Chemica Scandinavica, Vol. 4 https://doi.org/10.3891/acta.chem.scand.04-0559	journal	January 1950
Differentiating between Trivalent Lanthanides and Actinides Polinski, Matthew J.; Grant, Daniel J.; Wang, Shuao Journal of the American Chemical Society, Vol. 134, Issue 25 https://doi.org/10.1021/ja303804r	journal	June 2012
Luminescent lanthanide sensors for pH, pO2 and selected anions Parker, D. Coordination Chemistry Reviews, Vol. 205, Issue 1 https://doi.org/10.1016/S0010-8545(00)00241-1	journal	August 2000
Luminescence study on determination of the hydration number of Cm(III) Kimura, Takaumi; Choppin, Gregory R. Journal of Alloys and Compounds, Vol. 213-214 https://doi.org/10.1016/0925-8388(94)90921-0	journal	October 1994
Using lanthanide ions in molecular bioimaging Amoroso, Angelo J.; Pope, Simon J. A. Chemical Society Reviews, Vol. 44, Issue 14 https://doi.org/10.1039/C4CS00293H	journal	January 2015
Solution Structures of Europium(Iii) Complexes of Ethylenediaminetetraacetic acid Latva, Martti; Kankare, Jouko; Haapakka, Keijo Journal of Coordination Chemistry, Vol. 38, Issue 1-2 https://doi.org/10.1080/00958979608022693	journal	April 1996
Covalency in f-element complexes Neidig, Michael L.; Clark, David L.; Martin, Richard L. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.04.029	journal	January 2013
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals Zhao, Yan; Truhlar, Donald G. Theoretical Chemistry Accounts, Vol. 120, Issue 1-3 https://doi.org/10.1007/s00214-007-0310-x	journal	July 2007
Coordination Modes in the Formation of the Ternary Am(III), Cm(III), and Eu(III) Complexes with EDTA and NTA: TRLFS, ¹³ C NMR, EXAFS, and Thermodynamics of the Complexation Mathur, J. N.; Thakur, P.; Dodge, C. J. Inorganic Chemistry, Vol. 45, Issue 20 https://doi.org/10.1021/ic052166c	journal	October 2006
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning Kaltsoyannis, Nikolas Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic3006025	journal	June 2012
Stable Mn ²⁺ , Cu ²⁺ and Ln ³⁺ complexes with cyclen-based ligands functionalized with picolinate pendant arms Rodríguez-Rodríguez, Aurora; Garda, Zoltán; Ruscsák, Erika Dalton Transactions, Vol. 44, Issue 11 https://doi.org/10.1039/C4DT02985B	journal	January 2015
An Ion-exchange Study of Possible Hybridized 5f Bonding in the Actinides ¹ Diamond, R. M.; Street, K.; Seaborg, G. T. Journal of the American Chemical Society, Vol. 76, Issue 6 https://doi.org/10.1021/ja01635a001	journal	March 1954
The selectivity of diglycolamide (TODGA) and bis-triazine-bipyridine (BTBP) ligands in actinide/lanthanide complexation and solvent extraction separation – a theoretical approach Narbutt, Jerzy; Wodyński, Artur; Pecul, Magdalena Dalton Transactions, Vol. 44, Issue 6 https://doi.org/10.1039/C4DT02657H	journal	January 2015
Luminescence study on determination of the hydration number of Sm(III) and Dy(III) Kimura, Takaumi; Kato, Yoshiharu Journal of Alloys and Compounds, Vol. 225, Issue 1-2 https://doi.org/10.1016/0925-8388(94)07084-9	journal	July 1995
Synthesis and complexation properties of DTPA-N,N″-bis[bis(n-butyl)]-N′-methyl-tris(amide). Kinetic stability and water exchange of its Gd ³⁺ complex Jászberényi, Z.; Tóth, É.; Kálai, T. Dalton Trans., Issue 4 https://doi.org/10.1039/B417272H	journal	January 2005
On the Origin of Covalent Bonding in Heavy Actinides Kelley, Morgan P.; Su, Jing; Urban, Matthew Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b03251	journal	July 2017
Lanthanide ion probes of structure in biology. Laser-induced luminescence decay constants provide a direct measure of the number of metal-coordinated water molecules Horrocks, William DeW.; Sudnick, Daniel R. Journal of the American Chemical Society, Vol. 101, Issue 2 https://doi.org/10.1021/ja00496a010	journal	January 1979
Acid Dissociation Constants and Rare Earth Stability Constants for DTPA Grimes, Travis S.; Nash, Kenneth L. Journal of Solution Chemistry, Vol. 43, Issue 2 https://doi.org/10.1007/s10953-014-0139-6	journal	February 2014
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Pyridine-Based Lanthanide Complexes Combining MRI and NIR Luminescence Activities Bonnet, Célia S.; Buron, Frédéric; Caillé, Fabien Chemistry - A European Journal, Vol. 18, Issue 5 https://doi.org/10.1002/chem.201102310	journal	December 2011
Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids Weaver, Boyd; Kappelmann, F. A. Journal of Inorganic and Nuclear Chemistry, Vol. 30, Issue 1 https://doi.org/10.1016/0022-1902(68)80089-2	journal	January 1968
Convergence acceleration of iterative sequences. the case of scf iteration Pulay, Péter Chemical Physics Letters, Vol. 73, Issue 2 https://doi.org/10.1016/0009-2614(80)80396-4	journal	July 1980
Trans‐Lanthanide Extraction Studies in the TALSPEAK System: Investigating the Effect of Acidity and Temperature Nilsson, Mikael; Nash, Kenneth L. Solvent Extraction and Ion Exchange, Vol. 27, Issue 3 https://doi.org/10.1080/07366290902821164	journal	April 2009
Thermodynamic and Spectroscopic Studies of Trivalent f -element Complexation with Ethylenediamine- N,N ′-di(acetylglycine)- N,N ′-diacetic Acid Heathman, Colt R.; Grimes, Travis S.; Zalupski, Peter R. Inorganic Chemistry, Vol. 55, Issue 6 https://doi.org/10.1021/acs.inorgchem.5b02865	journal	March 2016
[Gd(CyPic3A)(H2O)2]−: a stable, bis(aquated) and high-relaxivity Gd(iii) complex Gale, Eric M.; Kenton, Nathaniel; Caravan, Peter Chemical Communications, Vol. 49, Issue 73 https://doi.org/10.1039/c3cc44116d	journal	January 2013
Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 78, Issue 7 https://doi.org/10.1103/PhysRevLett.78.1396	journal	February 1997
Ab Initio Calculations on Small Molecule Analogs of Polycarbonates Sun, H.; Mumby, S. J.; Maple, J. R. The Journal of Physical Chemistry, Vol. 99, Issue 16 https://doi.org/10.1021/j100016a022	journal	April 1995
Investigation of equilibria in solution. Determination of equilibrium constants with the HYPERQUAD suite of programs Gans, P.; Sabatini, A.; Vacca, A. Talanta, Vol. 43, Issue 10 https://doi.org/10.1016/0039-9140(96)01958-3	journal	October 1996
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
GROMACS: A message-passing parallel molecular dynamics implementation Berendsen, H. J. C.; van der Spoel, D.; van Drunen, R. Computer Physics Communications, Vol. 91, Issue 1-3 https://doi.org/10.1016/0010-4655(95)00042-E	journal	September 1995
Optical Absorption Intensities of Rare-Earth Ions Judd, B. R. Physical Review, Vol. 127, Issue 3 https://doi.org/10.1103/PhysRev.127.750	journal	August 1962
Lanthanide Probes for Bioresponsive Imaging Heffern, Marie C.; Matosziuk, Lauren M.; Meade, Thomas J. Chemical Reviews, Vol. 114, Issue 8 https://doi.org/10.1021/cr400477t	journal	December 2013
Determination of the equivalence point in potentiometric titrations. Part II Gran, Gunnar The Analyst, Vol. 77, Issue 920 https://doi.org/10.1039/an9527700661	journal	January 1952
Gadolinium(III) Chelates as MRI Contrast Agents: Structure, Dynamics, and Applications Caravan, Peter; Ellison, Jeffrey J.; McMurry, Thomas J. Chemical Reviews, Vol. 99, Issue 9 https://doi.org/10.1021/cr980440x	journal	September 1999
Lanthanide Luminescence for Biomedical Analyses and Imaging Bünzli, Jean-Claude G. Chemical Reviews, Vol. 110, Issue 5 https://doi.org/10.1021/cr900362e	journal	May 2010
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Matching chelators to radiometals for radiopharmaceuticals Price, Eric W.; Orvig, Chris Chem. Soc. Rev., Vol. 43, Issue 1 https://doi.org/10.1039/C3CS60304K	journal	January 2014
Syntheses, Characterization and Structural Determination of Nine Coordinated N2H5[Ce(edta)(H2O)3]·4H2O and N2H5[Eu(edta)(H2O)3]·4H2O Ragul, R.; Sivasankar, B. N. Journal of Chemical Crystallography, Vol. 41, Issue 9 https://doi.org/10.1007/s10870-011-0087-6	journal	May 2011
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Synthesis and characterization of a novel aminopolycarboxylate complexant for efficient trivalent f-element differentiation: N -butyl-2-acetamide-diethylenetriamine- N , N ′, N ′′, N ′′-tetraacetic acid Heathman, Colt R.; Grimes, Travis S.; Jansone-Popova, Santa Dalton Transactions, Vol. 47, Issue 4 https://doi.org/10.1039/C7DT04104G	journal	January 2018
Thermodynamic, Spectroscopic, and Computational Studies of Lanthanide Complexation with Diethylenetriaminepentaacetic Acid: Temperature Effect and Coordination Modes Tian, Guoxin; Martin, Leigh R.; Zhang, Zhiyong Inorganic Chemistry, Vol. 50, Issue 7 https://doi.org/10.1021/ic200025s	journal	April 2011
Trefoil-Shaped Outer-Sphere Ion Clusters Mediate Lanthanide(III) Ion Transport with Diglycolamide Ligands Brigham, Derek M.; Ivanov, Alexander S.; Moyer, Bruce A. Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b07318	journal	November 2017
Optical Absorption Characteristics For 7F0'→5L6' and 7F0'→ 7F6' Transitions of Trivalent Americium Ion in Aqueous Electrolyte Mixtures Zalupski, Peter R.; Grimes, Travis S.; Heathman, Colt R. Applied Spectroscopy, Vol. 71, Issue 12 https://doi.org/10.1177/0003702817721528	journal	July 2017
Electronic energy level and intensity correlations in the spectra of the trivalent actinide aquo ions. II. Cm ³⁺ Carnall, W. T.; Rajnak, K. The Journal of Chemical Physics, Vol. 63, Issue 8 https://doi.org/10.1063/1.431789	journal	October 1975
Luminescence study on hydration states of lanthanide(III)–polyaminopolycarboxylate complexes in aqueous solution Kimura, Takaumi; Kato, Yoshiharu Journal of Alloys and Compounds, Vol. 275-277 https://doi.org/10.1016/S0925-8388(98)00446-0	journal	July 1998
Trivalent Lanthanide/Actinide Separation Using Aqueous-Modified TALSPEAK Chemistry Grimes, Travis S.; Tillotson, Richard D.; Martin, Leigh R. Solvent Extraction and Ion Exchange, Vol. 32, Issue 4 https://doi.org/10.1080/07366299.2013.877754	journal	May 2014
Synthesis, equilibrium and NMR studies of lanthanide(III) complexes of the N-mono(methylamide) and N ′-mono(methylamide) derivatives of diethylenetriamine-N,N,N ′,N ″,N ″-pentaacetic acid† Sarka, Lajos; Bányai, István; Brücher, Ernő Journal of the Chemical Society, Dalton Transactions, Issue 20 https://doi.org/10.1039/b005298l	journal	January 2000
Lanthanide Complexes of a Picolinate Ligand Derived from 1,4,7-Triazacyclononane with Potential Application in Magnetic Resonance Imaging and Time-Resolved Luminescence Imaging Nonat, Aline; Gateau, Christelle; Fries, Pascal H. Chemistry - A European Journal, Vol. 12, Issue 27 https://doi.org/10.1002/chem.200501390	journal	September 2006
Complexation of Curium(III) with DTPA at 10–70 °C: Comparison with Eu(III)–DTPA in Thermodynamics, Luminescence, and Coordination Modes Tian, Guoxin; Zhang, Zhiyong; Martin, Leigh R. Inorganic Chemistry, Vol. 54, Issue 4 https://doi.org/10.1021/ic5016934	journal	January 2015
H ₄ octapa: Highly Stable Complexation of Lanthanide(III) Ions and Copper(II) Kálmán, Ferenc Krisztián; Végh, Andrea; Regueiro-Figueroa, Martín Inorganic Chemistry, Vol. 54, Issue 5 https://doi.org/10.1021/ic502966m	journal	February 2015
Coordination Chemistry and f-Element Complexation by Diethylenetriamine- N , N ″-bis(acetylglycine)- N , N ′, N ″-triacetic Acid Heathman, Colt R.; Grimes, Travis S.; Zalupski, Peter R. Inorganic Chemistry, Vol. 55, Issue 21 https://doi.org/10.1021/acs.inorgchem.6b02158	journal	October 2016
The complexation of lanthanides by aminocarboxylate ligands—I Gritmon, T. F.; Goedken, M. P.; Choppin, G. R. Journal of Inorganic and Nuclear Chemistry, Vol. 39, Issue 11 https://doi.org/10.1016/0022-1902(77)80538-1	journal	January 1977
VMD: Visual molecular dynamics Humphrey, William; Dalke, Andrew; Schulten, Klaus Journal of Molecular Graphics, Vol. 14, Issue 1 https://doi.org/10.1016/0263-7855(96)00018-5	journal	February 1996
Critical stability constants, enthalpies and entropies for the formation of metal complexes of aminopolycarboxylic acids and carboxylic acids Smith, Robert M.; Martell, Arthur E. Science of The Total Environment, Vol. 64, Issue 1-2 https://doi.org/10.1016/0048-9697(87)90127-6	journal	June 1987
The effect of pyridinecarboxylate chelating groups on the stability and electronic relaxation of gadolinium complexes Chatterton, Nicholas; Gateau, Christelle; Mazzanti, Marinella Dalton Trans., Issue 6 https://doi.org/10.1039/B416150E	journal	January 2005
Hydrothermal investigation of the lanthanide (Ln=La, Ce, Pr, Nd, Sm) 2,6-pyridinedicarboxylate system Brouca-Cabarrecq, C.; Fernandes, A.; Jaud, J. Inorganica Chimica Acta, Vol. 332, Issue 1 https://doi.org/10.1016/S0020-1693(01)00811-8	journal	April 2002
Two-Dimensional and Three-Dimensional Lanthanide Coordination Polymers Built from 4-Hydroxypyridine-2,6-dicarboxylic Acid Ligand Sun, Ya-Guang; Rong, Shu-Ting; Yu, Wan Zeitschrift für anorganische und allgemeine Chemie https://doi.org/10.1002/zaac.200900110	journal	July 2009
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets Chen, Ruyi; Cui, Qirui; Liao, Liyang Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-23414-3	journal	May 2021
High-resolution X-ray luminescence extension imaging Ou, Xiangyu; Qin, Xian; Huang, Bolong Nature, Vol. 590, Issue 7846 https://doi.org/10.1038/s41586-021-03251-6	journal	February 2021
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-58835-5	journal	February 2020

Similar Records

Synthesis and characterization of a novel aminopolycarboxylate complexant for efficient trivalent f-element differentiation: N-butyl-2-acetamide-diethylenetriamine-N,N',N",N"-tetraacetic acid

Journal Article · Thu Dec 14 00:00:00 EST 2017 · Dalton Transactions · OSTI ID:1564104

Heathman, Colt R.; Grimes, Travis S.; Jansone-Popova, Santa; +3 more

Influence of a Heterocyclic Nitrogen-Donor Group on the Coordination of Trivalent Actinides and Lanthanides by Aminopolycarboxylate Complexants

Journal Article · Fri Jan 05 00:00:00 EST 2018 · Inorganic Chemistry · OSTI ID:1564104

Grimes, Travis S.; Heathman, Colt R.; Jansone-Popova, Santa; +4 more