All-solid-state supercapacitors from natural lignin-based composite film by laser direct writing

Wang, Shutong; Yu, Yongchao; Luo, Si; Cheng, Xiaopeng; Feng, Guoying; Zhang, Yuefei; Wu, Zili; Compagnini, Giuseppe; Pooran, Joshi; Hu, Anming

doi:10.1063/1.5118340

Title: All-solid-state supercapacitors from natural lignin-based composite film by laser direct writing

Journal Article · Wed Aug 21 00:00:00 EDT 2019 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.5118340· OSTI ID:1560420

Wang, Shutong ^[1]; Yu, Yongchao ^[2];

^[3]; Cheng, Xiaopeng ^[4]; Feng, Guoying ^[5]; Zhang, Yuefei ^[4];

^[3]; Compagnini, Giuseppe ^[6];

^[3]; Hu, Anming ^[7]

Sichuan Univ., Chengdu (China); Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Beijing Univ. of Technology (China)
Sichuan Univ., Chengdu (China)
Università di Catania (Italy)
Univ. of Tennessee, Knoxville, TN (United States); Beijing Univ. of Technology (China)

Lignin as a renewable natural resource has been the aim of numerical interest in applications ranging from pitch to porous carbon material. In this work, a facile method is reported to transform lignin into porous conductive carbon structures and interdigitated circuits for supercapacitor devices using femtosecond laser direct writing. Comparative studies revealed that the laser irradiation induced tetrahedral amorphous carbon while only graphitic carbon was obtained through pyrolysis. At the same time, the composite membrane was easily prepared to further optimize the capacities by mixing functional materials (MoS₂) into the lignin/polyacrylonitrile (PAN) composite polymers. A MoS2 decorated porous carbon network material could be fabricated through focused femtosecond pulsed laser irradiation of the corresponding composite membranes. The microstructure and spectroscopic features of these laser induced hybrid carbon materials have been deeply investigated. The supercapacitor based on lignin/PAN has high areal specific capacitances of 6.7 mF cm^–2 (0.9 F cm^–3) at 10 mV s^–1. Moreover, doped microsupercapacitors with MoS2 demonstrated enhanced areal capacitances up to 16 mF cm^–2 (2.2 F cm^–3) and at 10 mV s^–1, respectively. The relatively high areal capacitances indicate that the introduced method is potential for innovative manufacturing energy storage devices based on natural lignin.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China (NSFC); China Scholarship Council; Beijing Municipal Natural Science Foundation

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1560420

Journal Information:: Applied Physics Letters, Vol. 115, Issue 8; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 34 works

Citation information provided by
Web of Science

References (46)

Synthesis, characterization, and hydrogen storage capacities of hierarchical porous carbide derived carbon monolith Wang, Jiacheng; Oschatz, Martin; Biemelt, Tim Journal of Materials Chemistry, Vol. 22, Issue 45 https://doi.org/10.1039/c2jm34472f	journal	January 2012
KOH activated lignin based nanostructured carbon exhibiting high hydrogen electrosorption Babeł, K.; Jurewicz, K. Carbon, Vol. 46, Issue 14 https://doi.org/10.1016/j.carbon.2008.08.005	journal	November 2008
Flexible micro-supercapacitors Sung, Joo-Hwan; Kim, Se-Joon; Jeong, Soo-Hwan Journal of Power Sources, Vol. 162, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.07.073	journal	November 2006
Engineered nanomembranes for smart energy storage devices Wang, Xianfu; Chen, Yu; Schmidt, Oliver G. Chemical Society Reviews, Vol. 45, Issue 5 https://doi.org/10.1039/C5CS00708A	journal	January 2016
Spectroelectrochemical investigation of redox states in a polypyrrole/lignin composite electrode material Ajjan, F. N.; Jafari, M. J.; Rębiś, T. Journal of Materials Chemistry A, Vol. 3, Issue 24 https://doi.org/10.1039/C5TA00788G	journal	January 2015
In situ MoS ₂ Decoration of Laser-Induced Graphene as Flexible Supercapacitor Electrodes Clerici, Francesca; Fontana, Marco; Bianco, Stefano ACS Applied Materials & Interfaces, Vol. 8, Issue 16 https://doi.org/10.1021/acsami.6b00808	journal	April 2016
Carbon-based materials as supercapacitor electrodes Zhang, Li Li; Zhao, X. S. Chemical Society Reviews, Vol. 38, Issue 9 https://doi.org/10.1039/b813846j	journal	January 2009
Porous 3D graphene-based bulk materials with exceptional high surface area and excellent conductivity for supercapacitors Zhang, Long; Zhang, Fan; Yang, Xi Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01408	journal	March 2013
Recycled waste paper—A new source of raw material for electric double-layer capacitors Kalpana, D.; Cho, S. H.; Lee, S. B. Journal of Power Sources, Vol. 190, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.01.058	journal	May 2009
Lignin Laser Lithography: A Direct-Write Method for Fabricating 3D Graphene Electrodes for Microsupercapacitors Zhang, Wenli; Lei, Yongjiu; Ming, Fangwang Advanced Energy Materials, Vol. 8, Issue 27 https://doi.org/10.1002/aenm.201801840	journal	August 2018
Structure and Thermal Properties of Lignins: Characterization by Infrared Spectroscopy and Differential Scanning Calorimetry Lisperguer, Justo; Perez, Patricio; Urizar, Silvio Journal of the Chilean Chemical Society, Vol. 54, Issue 4 https://doi.org/10.4067/S0717-97072009000400030	journal	January 2009
Simultaneous Production of High-Performance Flexible Textile Electrodes and Fiber Electrodes for Wearable Energy Storage Dong, Liubing; Xu, Chengjun; Li, Yang Advanced Materials, Vol. 28, Issue 8 https://doi.org/10.1002/adma.201504747	journal	December 2015
Bisphenol A Sensors on Polyimide Fabricated by Laser Direct Writing for Onsite River Water Monitoring at Attomolar Concentration Cheng, Cheng; Wang, Shutong; Wu, Jayne ACS Applied Materials & Interfaces, Vol. 8, Issue 28 https://doi.org/10.1021/acsami.6b03743	journal	July 2016
Carbon nanofibers/nanosheets hybrid derived from cornstalks as a sustainable anode for Li-ion batteries Wang, Shengbin; Xiao, Changlei; Xing, Yalan Journal of Materials Chemistry A, Vol. 3, Issue 13 https://doi.org/10.1039/C5TA00050E	journal	January 2015
Elaboration of a microstructured inkjet-printed carbon electrochemical capacitor Pech, David; Brunet, Magali; Taberna, Pierre-Louis Journal of Power Sources, Vol. 195, Issue 4, p. 1266-1269 https://doi.org/10.1016/j.jpowsour.2009.08.085	journal	February 2010
A Hollow Spherical Carbon Derived from the Spray Drying of Corncob Lignin for High-Rate-Performance Supercapacitors Pan, Zheng-Ze; Dong, Liubing; Lv, Wei Chemistry - An Asian Journal, Vol. 12, Issue 5 https://doi.org/10.1002/asia.201601724	journal	February 2017
Filled and Hollow Carbon Nanofibers by Coaxial Electrospinning of Alcell Lignin without Binder Polymers Lallave, M.; Bedia, J.; Ruiz-Rosas, R. Advanced Materials, Vol. 19, Issue 23 https://doi.org/10.1002/adma.200700963	journal	December 2007
High-performance stacked in-plane supercapacitors and supercapacitor array fabricated by femtosecond laser 3D direct writing on polyimide sheets Wang, Shutong; Yu, Yongchao; Li, Ruozhou Electrochimica Acta, Vol. 241 https://doi.org/10.1016/j.electacta.2017.04.138	journal	July 2017
Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
Carbons and Electrolytes for Advanced Supercapacitors Béguin, François; Presser, Volker; Balducci, Andrea Advanced Materials, Vol. 26, Issue 14, p. 2219-2251 https://doi.org/10.1002/adma.201304137	journal	February 2014
Facile fabrication of flexible all solid-state micro-supercapacitor by direct laser writing of porous carbon in polyimide In, Jung Bin; Hsia, Ben; Yoo, Jae-Hyuck Carbon, Vol. 83 https://doi.org/10.1016/j.carbon.2014.11.017	journal	March 2015
What Are Batteries, Fuel Cells, and Supercapacitors? Winter, Martin; Brodd, Ralph J. Chemical Reviews, Vol. 104, Issue 10, p. 4245-4270 https://doi.org/10.1021/cr020730k	journal	October 2004
Solid-State Supercapacitor Based on Activated Carbon Cloths Exhibits Excellent Rate Capability Wang, Gongming; Wang, Hanyu; Lu, Xihong Advanced Materials, Vol. 26, Issue 17 https://doi.org/10.1002/adma.201304756	journal	February 2014
Electrochemical capacitors: Technical challenges and prognosis for future markets Shukla, A. K.; Banerjee, A.; Ravikumar, M. K. Electrochimica Acta, Vol. 84 https://doi.org/10.1016/j.electacta.2012.03.059	journal	December 2012
Laser-Induced Graphene Formation on Wood Ye, Ruquan; Chyan, Yieu; Zhang, Jibo Advanced Materials, Vol. 29, Issue 37 https://doi.org/10.1002/adma.201702211	journal	July 2017
Cryogenic graphitization of submicrometer grains embedded in nanostructured tetrahedral amorphous carbon films Hu, A.; Alkhesho, I.; Duley, W. W. Journal of Applied Physics, Vol. 100, Issue 8 https://doi.org/10.1063/1.2360386	journal	October 2006
Breathable and Wearable Energy Storage Based on Highly Flexible Paper Electrodes Dong, Liubing; Xu, Chengjun; Li, Yang Advanced Materials, Vol. 28, Issue 42 https://doi.org/10.1002/adma.201602541	journal	August 2016
Sulfur-Doped Laser-Induced Porous Graphene Derived from Polysulfone-Class Polymers and Membranes Singh, Swatantra P.; Li, Yilun; Zhang, Jibo ACS Nano, Vol. 12, Issue 1 https://doi.org/10.1021/acsnano.7b06263	journal	December 2017
Processing and characterization of low-cost electrospun carbon fibers from organosolv lignin/polyacrylonitrile blends Ding, Rui; Wu, Hongchao; Thunga, Mahendra Carbon, Vol. 100 https://doi.org/10.1016/j.carbon.2015.12.078	journal	April 2016
Direct laser writing of graphene films from a polyether ether ketone precursor Zhu, Chenguang; Zhao, Dongmei; Wang, Kedian Journal of Materials Science, Vol. 54, Issue 5 https://doi.org/10.1007/s10853-018-3123-5	journal	November 2018
Methodical study of the chemical activation of Kraft lignin with KOH and NaOH Fierro, V.; Torné-Fernández, V.; Celzard, A. Microporous and Mesoporous Materials, Vol. 101, Issue 3 https://doi.org/10.1016/j.micromeso.2006.12.004	journal	April 2007
High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes Li, R. -Z.; Peng, Rui; Kihm, K. D. Energy & Environmental Science, Vol. 9, Issue 4 https://doi.org/10.1039/C5EE03637B	journal	January 2016
Resonant Raman scattering from polyacetylene and poly(p-phenylene vinylene) chains included into hydrogenated amorphous carbon Rybachuk, M.; Hu, A.; Bell, J. M. Applied Physics Letters, Vol. 93, Issue 5 https://doi.org/10.1063/1.2965458	journal	August 2008
Direct laser writing for creating porous graphitic structures and their use for flexible and highly sensitive sensor and sensor arrays Luo, Sida; Hoang, Phong Tran; Liu, Tao Carbon, Vol. 96 https://doi.org/10.1016/j.carbon.2015.09.076	journal	January 2016
Laser-Induced Conversion of Teflon into Fluorinated Nanodiamonds or Fluorinated Graphene Ye, Ruquan; Han, Xiao; Kosynkin, Dmitry V. ACS Nano, Vol. 12, Issue 2 https://doi.org/10.1021/acsnano.7b05877	journal	January 2018
Determination of bonding in diamond-like carbon by Raman spectroscopy Ferrari, Andrea Carlo Diamond and Related Materials, Vol. 11, Issue 3-6 https://doi.org/10.1016/S0925-9635(01)00730-0	journal	March 2002
Laser-induced porous graphene films from commercial polymers Lin, Jian; Peng, Zhiwei; Liu, Yuanyue Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6714	journal	December 2014
Simple technique for measurements of pulsed Gaussian-beam spot sizes Liu, J. M. Optics Letters, Vol. 7, Issue 5 https://doi.org/10.1364/OL.7.000196	journal	January 1982
Electrochemical Characterization of Liquid Phase Exfoliated Two-Dimensional Layers of Molybdenum Disulfide Winchester, Andrew; Ghosh, Sujoy; Feng, Simin ACS Applied Materials & Interfaces, Vol. 6, Issue 3 https://doi.org/10.1021/am4051316	journal	January 2014
Stacking up layers of polyaniline/carbon nanotube networks inside papers as highly flexible electrodes with large areal capacitance and superior rate capability Dong, Liubing; Liang, Gemeng; Xu, Chengjun Journal of Materials Chemistry A, Vol. 5, Issue 37 https://doi.org/10.1039/C7TA06135H	journal	January 2017
Direct Laser-Patterned Micro-Supercapacitors from Paintable MoS ₂ Films Cao, Liujun; Yang, Shubin; Gao, Wei Small, Vol. 9, Issue 17 https://doi.org/10.1002/smll.201203164	journal	April 2013
Spectroscopic characterization of carbon chains in nanostructured tetrahedral carbon films synthesized by femtosecond pulsed laser deposition Hu, A.; Lu, Q. -B.; Duley, W. W. The Journal of Chemical Physics, Vol. 126, Issue 15 https://doi.org/10.1063/1.2727450	journal	April 2007
Multi hierarchical construction-induced superior capacitive performances of flexible electrodes for wearable energy storage Dong, Liubing; Liang, Gemeng; Xu, Chengjun Nano Energy, Vol. 34 https://doi.org/10.1016/j.nanoen.2017.02.031	journal	April 2017
Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials Acerce, Muharrem; Voiry, Damien; Chhowalla, Manish Nature Nanotechnology, Vol. 10, Issue 4 https://doi.org/10.1038/nnano.2015.40	journal	March 2015
What Are Batteries, Fuel Cells, and Supercapacitors? Winter, Martin; Brodd, Ralph J. ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450265	journal	December 2004
Resonant Raman scattering from polyacetylene and poly(p-phenylene vinylene) chains included into hydrogenated amorphous carbon Rybachuk*, M.; Hu, A.; Bell, J. M. arXiv https://doi.org/10.48550/arxiv.1004.4865	text	January 2010

Similar Records

Synthesis of nickel selenide thin films for high performance all-solid-state asymmetric supercapacitors

Journal Article · Wed Mar 04 00:00:00 EST 2020 · Chinese Chemical Letters · OSTI ID:1560420

Li, Hao; Gong, Jiangfeng; Li, Jing-Chang; +4 more

Keratin-derived functional carbon with superior charge storage and transport for high-performance supercapacitors

Journal Article · Sat Jul 18 00:00:00 EDT 2020 · Carbon · OSTI ID:1560420

Sinha, Prerna; Yadav, Amit; Tyagi, Alekha; +5 more

Facile synthesis of nitrogen-doped porous carbon as robust electrode for supercapacitors

Journal Article · Tue May 15 00:00:00 EDT 2018 · Materials Research Bulletin · OSTI ID:1560420

Mao, Zuxing; Zhao, Shaobin; Wang, Jing; +3 more

Related Subjects

36 MATERIALS SCIENCE

Title: All-solid-state supercapacitors from natural lignin-based composite film by laser direct writing

Citation Formats

References (46)

Similar Records

Related Subjects