In situ, operando studies on the size and structure of supported Pt catalysts under supercritical conditions by simultaneous synchrotron-based X-ray techniques

Lee, Sungwon; Lee, Sungsik; Gerceker, Duygu; Kumbhalkar, Mrunmayi D.; Wiaderek, Kamila M.; Ball, Madelyn R.; Mavrikakis, Manos; Dumesic, James A.; Winans, Randall E.

doi:10.1039/C9CP00347A

Title: In situ, operando studies on the size and structure of supported Pt catalysts under supercritical conditions by simultaneous synchrotron-based X-ray techniques

Journal Article · Wed May 15 00:00:00 EDT 2019 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C9CP00347A· OSTI ID:1559532

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^[2]; Kumbhalkar, Mrunmayi D. ^[2]; Wiaderek, Kamila M. ^[1];

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Argonne National Lab. (ANL), Lemont, IL (United States)
Univ. of Wisconsin, Madison, WI (United States)

To control the size and structure of supported Pt catalysts, the influence of additional metal particles and the effect of supports were elucidated during the cracking reaction of n-dodecane under supercritical reaction conditions. The dynamical changes in nanocatalysts and catalytic activity are studied under realistic reaction conditions by using a combination of simultaneous temperature-programmed heating, in situ Small Angle X-ray Scattering (SAXS) and X-ray Absorption Near Edge Structure (XANES). In situ SAXS results indicate that the stability of the catalysts increases with Sn concentration. In situ XANES analysis reveals that the degree of oxidation and the electronic states of catalysts are dependent on the amount of Sn. Carbonaceous deposits over spent catalysts were characterized by Raman spectroscopy, suggesting that the highest Sn loading inhibits the formation of disordered graphitic lattices, which leads to an increased catalytic activity. SiO₂, γ-Al₂O₃ and Mg(Al)Ox were employed as supports to investigate the support effect on the stability of Pt catalysts. In situ SAXS and XANES findings clearly reflect the improved stability of catalysts on γ-Al₂O₃ and Mg(Al)Ox supports compared to Pt catalysts on SiO₂ and the electronic states of catalysts are strongly influenced by support materials.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC); Air Force Research Laboratory (AFRL); US Air Force Office of Scientific Research (AFOSR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1559532

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 21, Issue 22; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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References (48)

CO oxidation on PtSn nanoparticle catalysts occurs at the interface of Pt and Sn oxide domains formed under reaction conditions Michalak, William D.; Krier, James M.; Alayoglu, Selim Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.005	journal	April 2014
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Active coke: Carbonaceous materials as catalysts for alkane dehydrogenation McGregor, James; Huang, Zhenyu; Parrott, Edward P. J. Journal of Catalysis, Vol. 269, Issue 2 https://doi.org/10.1016/j.jcat.2009.11.016	journal	February 2010
Inhibition Effect of APCVD Titanium Nitride Coating on Coke Growth during n -Hexane Thermal Cracking under Supercritical Conditions Tang, Shiyun; Gao, Shuang; Hu, Shengwang Industrial & Engineering Chemistry Research, Vol. 53, Issue 13 https://doi.org/10.1021/ie401889p	journal	March 2014
Cracking and Deposition Behavior of Supercritical Hydrocarbon Aviation Fuels Edwards*, Tim Combustion Science and Technology, Vol. 178, Issue 1-3 https://doi.org/10.1080/00102200500294346	journal	January 2006
Effect of hydrothermal treatment on catalytic properties of PtSnNa/ZSM-5 catalyst for propane dehydrogenation Zhang, Yiwei; Zhou, Yuming; Yang, Kangzhen Microporous and Mesoporous Materials, Vol. 96, Issue 1-3 https://doi.org/10.1016/j.micromeso.2006.07.003	journal	November 2006
Platinum-Catalyzed Asymmetric Hydrogenation: Spectroscopic Evidence for an O-H-O Hydrogen-Bond Interaction between Substrate and Modifier Meemken, Fabian; Maeda, Nobutaka; Hungerbühler, Konrad Angewandte Chemie International Edition, Vol. 51, Issue 33 https://doi.org/10.1002/anie.201203007	journal	June 2012
A combined in situ time-resolved UV–Vis, Raman and high-energy resolution X-ray absorption spectroscopy study on the deactivation behavior of Pt and PtSn propane dehydrogenation catalysts under industrial reaction conditions Iglesias-Juez, Ana; Beale, Andrew M.; Maaijen, Karin Journal of Catalysis, Vol. 276, Issue 2 https://doi.org/10.1016/j.jcat.2010.09.018	journal	December 2010
In situ time-resolved XAFS study on the structural transformation and phase separation of Pt3Sn and PtSn alloy nanoparticles on carbon in the oxidation process Uemura, Y.; Inada, Y.; Bando, K. K. Physical Chemistry Chemical Physics, Vol. 13, Issue 35 https://doi.org/10.1039/c1cp20994a	journal	January 2011
Propane Dehydrogenation over Supported Pt and Pt–Sn Catalysts: Catalyst Preparation, Characterization, and Activity Measurements Bariås, Odd A.; Holmen, Anders; Blekkan, Edd A. Journal of Catalysis, Vol. 158, Issue 1 https://doi.org/10.1006/jcat.1996.0001	journal	January 1996
The effects of calcination temperature of support on PtIn/Mg(Al)O catalysts for propane dehydrogenation reaction Shen, Li-Ling; Xia, Ke; Lang, Wan-Zhong Chemical Engineering Journal, Vol. 324 https://doi.org/10.1016/j.cej.2017.05.058	journal	September 2017
Effect of Particle Size and Adsorbates on the L3, L2 and L1 X-ray Absorption Near Edge Structure of Supported Pt Nanoparticles Lei, Yu; Jelic, Jelena; Nitsche, Ludwig C. Topics in Catalysis, Vol. 54, Issue 5-7 https://doi.org/10.1007/s11244-011-9662-5	journal	February 2011
Methane Conversion to Ethylene and Aromatics on PtSn Catalysts Gerceker, Duygu; Motagamwala, Ali Hussain; Rivera-Dones, Keishla R. ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b02724	journal	February 2017
Sn surface-enriched Pt–Sn bimetallic nanoparticles as a selective and stable catalyst for propane dehydrogenation Zhu, Haibo; Anjum, Dalaver H.; Wang, Qingxiao Journal of Catalysis, Vol. 320 https://doi.org/10.1016/j.jcat.2014.09.013	journal	December 2014
Characterization, synthesis and catalysis of hydrotalcite-related materials for highly efficient materials transformations Nishimura, Shun; Takagaki, Atsushi; Ebitani, Kohki Green Chemistry, Vol. 15, Issue 8 https://doi.org/10.1039/c3gc40405f	journal	January 2013
Raman spectroscopy of carbon materials: structural basis of observed spectra Wang, Yan; Alsmeyer, Daniel C.; McCreery, Richard L. Chemistry of Materials, Vol. 2, Issue 5 https://doi.org/10.1021/cm00011a018	journal	September 1990
Subnanometer-sized Pt/Sn alloy cluster catalysts for the dehydrogenation of linear alkanes Hauser, Andreas W.; Gomes, Joseph; Bajdich, Michal Physical Chemistry Chemical Physics, Vol. 15, Issue 47 https://doi.org/10.1039/c3cp53796j	journal	January 2013
New Method of Quantitative Determination of the Carbon Source in Blast Furnace Flue Dust Yu, Jie; Sun, Lushi; Xiang, Jun Energy & Fuels, Vol. 28, Issue 11 https://doi.org/10.1021/ef501863r	journal	October 2014
Advantages of MgAlO _x over γ-Al ₂ O ₃ as a Support Material for Potassium-Based High-Temperature Lean NO _x Traps Luo, Jinyong; Gao, Feng; Karim, Ayman M. ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b00542	journal	July 2015
Isopentane dehydrogenation on Pt-Sn catalysts supported on Al-Mg-O mixed oxides: effect of Al/Mg atomic ratio Armendáriz, H.; Guzmán, A.; Toledo, J. A. Applied Catalysis A: General, Vol. 211, Issue 1 https://doi.org/10.1016/S0926-860X(00)00836-X	journal	March 2001
Operando Raman spectroscopy study on the deactivation of Pt/Al2O3 and Pt–Sn/Al2O3 propane dehydrogenation catalysts Sattler, Jesper J. H. B.; Beale, Andrew M.; Weckhuysen, Bert M. Physical Chemistry Chemical Physics, Vol. 15, Issue 29 https://doi.org/10.1039/c3cp50646k	journal	January 2013
Dehydrogenation and oxydehydrogenation of paraffins to olefins Bhasin, M. M.; McCain, J. H.; Vora, B. V. Applied Catalysis A: General, Vol. 221, Issue 1-2, p. 397-419 https://doi.org/10.1016/S0926-860X(01)00816-X	journal	November 2001
Formaldehyde oxidation on silica-supported Pt catalysts: The influence of thermal pretreatments on particle formation and on oxidation mechanism Wu, Hung-Chi; Chen, Tse-Ching; Chen, Yan-Chu Journal of Catalysis, Vol. 355 https://doi.org/10.1016/j.jcat.2017.08.029	journal	November 2017
Supercritical Thermal Cracking of N -Dodecane in Presence of Several Initiative Additives: Products Distribution and Kinetics Liu, Guozhu; Han, Yongjin; Wang, Li Energy & Fuels, Vol. 22, Issue 6 https://doi.org/10.1021/ef800323d	journal	November 2008
Effect of Particle Size upon Pt/SiO ₂ Catalytic Cracking of n -Dodecane under Supercritical Conditions: In situ SAXS and XANES Studies Lee, Sungwon; Lee, Sungsik; Kumbhalkar, Mrunmayi D. ChemCatChem, Vol. 9, Issue 1 https://doi.org/10.1002/cctc.201600829	journal	November 2016
PtSn/SiO2 catalysts prepared by surface controlled reactions for the selective hydrogenation of cinnamaldehyde Merlo, Andrea B.; Machado, Bruno F.; Vetere, Virginia Applied Catalysis A: General, Vol. 383, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.05.020	journal	July 2010
Importance of Automobile Exhaust Catalyst Emissions for the Deposition of Platinum, Palladium, and Rhodium in the Northern Hemisphere Rauch, Sebastien; Hemond, Harold F.; Barbante, Carlo Environmental Science & Technology, Vol. 39, Issue 21 https://doi.org/10.1021/es050784m	journal	November 2005
Glycolysis of Poly(ethylene terephthalate) over Mg–Al Mixed Oxides Catalysts Derived from Hydrotalcites Chen, Feifei; Wang, Guanghui; Li, Wei Industrial & Engineering Chemistry Research, Vol. 52, Issue 2 https://doi.org/10.1021/ie302091j	journal	December 2012
Characterization of Bimetallic Pt–Sn/Al2O3Catalysts: Relationship between Particle Size and Structure Merlen, E.; Beccat, P.; Bertolini, J. C. Journal of Catalysis, Vol. 159, Issue 1 https://doi.org/10.1006/jcat.1996.0077	journal	March 1996
Influence of Sn content on PtSn/C catalysts for electrooxidation of C1–C3 alcohols: Synthesis, characterization, and electrocatalytic activity Kim, Jae Hong; Choi, Sung Mook; Nam, Sang Hoon Applied Catalysis B: Environmental, Vol. 82, Issue 1-2 https://doi.org/10.1016/j.apcatb.2008.01.011	journal	July 2008
Dehydrogenation of long chain paraffins over supported Pt-Sn-K/Al2O3 catalysts: A study of the alumina support effect He, Songbo; Sun, Chenglin; Bai, Ziwu Applied Catalysis A: General, Vol. 356, Issue 1 https://doi.org/10.1016/j.apcata.2008.12.024	journal	March 2009
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
A comparative study on different regeneration processes of Pt-Sn/γ-Al2O3 catalysts for propane dehydrogenation Sun, Changyong; Luo, Junyin; Cao, Mingjin Journal of Energy Chemistry, Vol. 27, Issue 1 https://doi.org/10.1016/j.jechem.2017.09.035	journal	January 2018
Density functional theory studies of the adsorption of ethylene and oxygen on Pt(111) and Pt[sub 3]Sn(111) Watwe, Ramchandra M.; Cortright, Randy D.; Mavrikakis, Manos The Journal of Chemical Physics, Vol. 114, Issue 10 https://doi.org/10.1063/1.1346685	journal	January 2001
Effects of endothermic hydrocarbon fuel composition on the pyrolysis and anti-coking performance under supercritical conditions Sun, Daoan; Li, Chunying; Du, Yongmei Fuel, Vol. 239 https://doi.org/10.1016/j.fuel.2018.11.003	journal	March 2019
Solid Deposits from Thermal Stressing of n -Dodecane and Chinese RP-3 Jet Fuel in the Presence of Several Initiators Liu, Guozhu; Han, Yongjin; Wang, Li Energy & Fuels, Vol. 23, Issue 1 https://doi.org/10.1021/ef800657z	journal	January 2009
In-situ X-Ray Absorption Near Edge Structure Spectroscopy of a Solid Catalyst using a Laboratory-Based Set-up Moya-Cancino, José G.; Honkanen, Ari-Pekka; van der Eerden, Ad M. J. ChemCatChem, Vol. 11, Issue 3 https://doi.org/10.1002/cctc.201801822	journal	January 2019
High Heat Sink Jet Fuels. Part 1. Development of Potential Oxidative and Pyrolytic Additives for JP-8 Beaver, Bruce D.; Clifford, Caroline Burgess; Fedak, Mitchel G. Energy & Fuels, Vol. 20, Issue 4 https://doi.org/10.1021/ef050352x	journal	July 2006
Study of Pt/MgAlO x catalysts in n-decane dehydrogenation Belskaya, O. B.; Stepanova, L. N.; Gulyaeva, T. I. Kinetics and Catalysis, Vol. 56, Issue 5 https://doi.org/10.1134/S0023158415050018	journal	September 2015
Propane dehydrogenation over Pt–Cu bimetallic catalysts: the nature of coke deposition and the role of copper Han, Zhiping; Li, Shuirong; Jiang, Feng Nanoscale, Vol. 6, Issue 17 https://doi.org/10.1039/C4NR02143F	journal	January 2014
Validation of Transient Cooling Modeling for Hypersonic Application Gascoin, Nicolas; Gillard, Philippe; Dufour, Emmanuel Journal of Thermophysics and Heat Transfer, Vol. 21, Issue 1 https://doi.org/10.2514/1.26022	journal	January 2007
Dehydrogenation of alkane to light olefin over PtSn/θ-Al2O3 catalyst: Effects of Sn loading Lee, Mi-Hyun; Nagaraja, Bhari Mallanna; Lee, Kwan Young Catalysis Today, Vol. 232 https://doi.org/10.1016/j.cattod.2013.10.011	journal	September 2014
Dehydrogenation of n-dodecane over Pt Sn/Mg Al O catalysts: Investigating the catalyst performance while monitoring the products Lai, Yulong; He, Songbo; Li, Xianru Applied Catalysis A: General, Vol. 469 https://doi.org/10.1016/j.apcata.2013.09.042	journal	January 2014
Preparation of highly dispersed catalytic metals Platinum supported on silica gel Benesi, H.; Curtis, R.; Studer, H. Journal of Catalysis, Vol. 10, Issue 4, p. 328-335 https://doi.org/10.1016/0021-9517(68)90147-4	journal	April 1968
Effects of composition and metal particle size on ethane dehydrogenation over PtxSn100−x/Mg(Al)O (70⩽x⩽100) Wu, Jason; Peng, Zhenmeng; Bell, Alexis T. Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.11.017	journal	March 2014
Performance of Ethane Dehydrogenation over PtSn Loaded onto a Calcined Mg(Al)O LDH with Three Mg:Al Molar Ratios Using a Novel Method Fang, Shuqi; Bi, Kang; Zhang, Qiao Catalysts, Vol. 8, Issue 8 https://doi.org/10.3390/catal8080296	journal	July 2018
Electronic Structure Engineering in Heterogeneous Catalysis: Identifying Novel Alloy Catalysts Based on Rapid Screening for Materials with Desired Electronic Properties Xin, Hongliang; Holewinski, Adam; Schweitzer, Neil Topics in Catalysis, Vol. 55, Issue 5-6 https://doi.org/10.1007/s11244-012-9794-2	journal	April 2012
Catalytic Cracking of RP-3 Jet Fuel over Pt/CeO ₂ –Al ₂ O ₃ by Adding Cu/ZSM-5 Jiao, Yi; Wang, Jianli; Zhu, Quan Energy & Fuels, Vol. 28, Issue 8 https://doi.org/10.1021/ef500374c	journal	July 2014

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