Aqueous Electrochemical Energy Storage with a Mediator-Ion Solid Electrolyte

Yu, Xingwen; Gross, Martha M.; Wang, Shaofei; Manthiram, Arumugam

doi:10.1002/aenm.201602454

Title: Aqueous Electrochemical Energy Storage with a Mediator-Ion Solid Electrolyte

Journal Article · Fri Jan 06 00:00:00 EST 2017 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201602454· OSTI ID:1533075

Yu, Xingwen ^[1]; Gross, Martha M. ^[1]; Wang, Shaofei ^[1]; Manthiram, Arumugam ^[1]

Univ. of Texas, Austin, TX (United States)

This study presents a battery concept with a “mediator‐ion” solid electrolyte for the development of next‐generation electrochemical energy storage technologies. The active anode and cathode materials in a single cell can be in the solid, liquid, or gaseous form, which are separated by a sodium‐ion solid‐electrolyte separator. The uniqueness of this mediator‐ion strategy is that the redox reactions at the anode and the cathode are sustained by a shuttling of a mediator sodium ion between the anolyte and the catholyte through the solid‐state electrolyte. Use of the solid‐electrolyte separator circumvents the chemical‐crossover problem between the anode and the cathode, overcomes the dendrite‐problem when employing metal‐anodes, and offers the possibility of using different liquid electrolytes at the anode and the cathode in a single cell. The battery concept is demonstrated with two low‐cost metal anodes (zinc and iron), two liquid cathodes (bromine and potassium ferricyanide), and one gaseous cathode (air/O ₂ ) with a sodium‐ion solid electrolyte. This novel battery strategy with a mediator‐ion solid electrolyte is applicable to a wide range of electrochemical energy storage systems with a variety of cathodes, anodes, and mediator‐ion solid electrolytes.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0005397; DE‐SC0005397

OSTI ID:: 1533075

Alternate ID(s):: OSTI ID: 1400601

Journal Information:: Advanced Energy Materials, Vol. 7, Issue 11; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 20 works

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Title: Aqueous Electrochemical Energy Storage with a Mediator-Ion Solid Electrolyte

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