Ultrafast photodissociation dynamics and nonadiabatic coupling between excited electronic states of methanol probed by time-resolved photoelectron spectroscopy

Champenois, Elio G.; Greenman, Loren; Shivaram, Niranjan; Cryan, James P.; Larsen, Kirk A.; Rescigno, Thomas N.; McCurdy, C. William; Belkacem, Ali; Slaughter, Daniel S.

doi:10.1063/1.5079549

Title: Ultrafast photodissociation dynamics and nonadiabatic coupling between excited electronic states of methanol probed by time-resolved photoelectron spectroscopy

Journal Article · Thu Mar 21 00:00:00 EDT 2019 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.5079549· OSTI ID:1528785

Champenois, Elio G. ^[1]; Greenman, Loren ^[2];

^[3]; Cryan, James P. ^[4]; Larsen, Kirk A. ^[1]; Rescigno, Thomas N. ^[5];

^[6]; Belkacem, Ali ^[5];

^[5]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Davis, CA (United States); Kansas State Univ., Manhattan, KS (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States). Photon Ultrafast Laser Science and Engineering Inst. (PULSE)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Davis, CA (United States)

The electronic and nuclear dynamics in methanol, following 156 nm photoexcitation, are investigated by combining a detailed analysis of time-resolved photoelectron spectroscopy experiments with electronic structure calculations. The photoexcitation pump pulse is followed by a delayed 260 nm photoionization probe pulse to produce photoelectrons that are analyzed by velocity map imaging. The yields of mass-resolved ions, measured with similar experimental conditions, are found to exhibit the same time-dependence as specific photoelectron spectral features. Energy-resolved signal onset and decay times are extracted from the measured photoelectron spectra to achieve high temporal resolution, beyond the 20 fs pump and probe pulse durations. When combined with ab initio calculations of selected cuts through the excited state potential energy surfaces, this information allows the dynamics of the transient excited molecule, which exhibits multiple nuclear and electronic degrees of freedom, to be tracked on its intrinsic few-femtosecond time scale. Within 15 fs of photoexcitation, we observe nuclear motion on the initially bound photoexcited 2¹A" (S₂) electronic state, through a conical intersection with the 1¹A' (S3) state, which reveals paths to photodissociation following C–O stretch and C–O–H angle opening.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; US Army Research Office (ARO)

Grant/Contract Number:: AC02-76SF00515; W911NF-14-1-0383; AC02-05CH11231

OSTI ID:: 1528785

Alternate ID(s):: OSTI ID: 1542954; OSTI ID: 1634043

Journal Information:: Journal of Chemical Physics, Vol. 150, Issue 11; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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References (72)

Local treatment of electron excitations in the EOM-CCSD method Korona, Tatiana; Werner, Hans-Joachim The Journal of Chemical Physics, Vol. 118, Issue 7 https://doi.org/10.1063/1.1537718	journal	February 2003
The equation-of-motion coupled-cluster method. Applications to open- and closed-shell reference states Comeau, Donald C.; Bartlett, Rodney J. Chemical Physics Letters, Vol. 207, Issue 4-6 https://doi.org/10.1016/0009-2614(93)89023-b	journal	May 1993
Focal overlap gating in velocity map imaging to achieve high signal-to-noise ratio in photo-ion pump-probe experiments Shivaram, Niranjan; Champenois, Elio G.; Cryan, James P. Applied Physics Letters, Vol. 109, Issue 25 https://doi.org/10.1063/1.4972343	journal	December 2016
Product selectivity of vibrationally mediated photofragmentation of methanol Marston, C. C.; Weide, K.; Schinke, R. The Journal of Chemical Physics, Vol. 98, Issue 6 https://doi.org/10.1063/1.464976	journal	March 1993
Conversion of CO ₂ from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst Kothandaraman, Jotheeswari; Goeppert, Alain; Czaun, Miklos Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b12354	journal	January 2016
Reassignment of the low lying cationic states in gas phase adenine and 9-methyl adenine Satzger, Helmut; Townsend, Dave; Stolow, Albert Chemical Physics Letters, Vol. 430, Issue 1-3 https://doi.org/10.1016/j.cplett.2006.08.122	journal	October 2006
Coherent Electron Hole Dynamics Near a Conical Intersection Timmers, Henry; Li, Zheng; Shivaram, Niranjan Physical Review Letters, Vol. 113, Issue 11 https://doi.org/10.1103/physrevlett.113.113003	journal	September 2014
Molpro: a general-purpose quantum chemistry program package: Molpro Werner, Hans-Joachim; Knowles, Peter J.; Knizia, Gerald Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 2 https://doi.org/10.1002/wcms.82	journal	July 2011
High-resolution photoelectron spectroscopy of methanol and its deuterated derivatives: Internal rotation in the ground ionic state Macneil, K. A. G.; Dixon, R. N. Journal of Electron Spectroscopy and Related Phenomena, Vol. 11, Issue 3 https://doi.org/10.1016/0368-2048(77)80007-8	journal	January 1977
Full observation of ultrafast cascaded radiationless transitions from S ₂ (ππ ^∗ ) state of pyrazine using vacuum ultraviolet photoelectron imaging Horio, Takuya; Spesyvtsev, Roman; Nagashima, Kazuki The Journal of Chemical Physics, Vol. 145, Issue 4 https://doi.org/10.1063/1.4955296	journal	July 2016
Sub-10-fs control of dissociation pathways in the hydrogen molecular ion with a few-pulse attosecond pulse train Nabekawa, Yasuo; Furukawa, Yusuke; Okino, Tomoya Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12835	journal	September 2016
Coupled cluster theory for high spin, open shell reference wave functions Knowles, Peter J.; Hampel, Claudia; Werner, Hans‐Joachim The Journal of Chemical Physics, Vol. 99, Issue 7 https://doi.org/10.1063/1.465990	journal	October 1993
Ultrafast photodynamics of pyrazine in the vacuum ultraviolet region studied by time-resolved photoelectron imaging using 7.8-eV pulses Horio, Takuya; Suzuki, Yoshi-ichi; Suzuki, Toshinori The Journal of Chemical Physics, Vol. 145, Issue 4 https://doi.org/10.1063/1.4955298	journal	July 2016
Photodissociation Dynamics of Methanol at 157 nm Harich, S.; Lin, J. J.; Lee, Y. T. The Journal of Physical Chemistry A, Vol. 103, Issue 49 https://doi.org/10.1021/jp991987y	journal	December 1999
T IME -R ESOLVED P HOTOELECTRON S PECTROSCOPY OF M OLECULES AND C LUSTERS Neumark, Daniel M. Annual Review of Physical Chemistry, Vol. 52, Issue 1 https://doi.org/10.1146/annurev.physchem.52.1.255	journal	October 2001
Time-Resolved Molecular Frame Dynamics of Fixed-in-Space CS2 Molecules Bisgaard, C. Z.; Clarkin, O. J.; Wu, G. Science, Vol. 323, Issue 5920 https://doi.org/10.1126/science.1169183	journal	March 2009
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen Dunning, Thom H. The Journal of Chemical Physics, Vol. 90, Issue 2 https://doi.org/10.1063/1.456153	journal	January 1989
Isomerization Through Conical Intersections Levine, Benjamin G.; Martínez, Todd J. Annual Review of Physical Chemistry, Vol. 58, Issue 1 https://doi.org/10.1146/annurev.physchem.57.032905.104612	journal	May 2007
Isotope effect on hydrated electron relaxation dynamics studied with time-resolved liquid jet photoelectron spectroscopy Elkins, Madeline H.; Williams, Holly L.; Neumark, Daniel M. The Journal of Chemical Physics, Vol. 144, Issue 18 https://doi.org/10.1063/1.4948546	journal	May 2016
Two-dimensional charged particle image inversion using a polar basis function expansion Garcia, Gustavo A.; Nahon, Laurent; Powis, Ivan Review of Scientific Instruments, Vol. 75, Issue 11 https://doi.org/10.1063/1.1807578	journal	November 2004
Strong Field Molecular Ionization in the Impulsive Limit: Freezing Vibrations with Short Pulses Sándor, Péter; Tagliamonti, Vincent; Zhao, Arthur Physical Review Letters, Vol. 116, Issue 6 https://doi.org/10.1103/physrevlett.116.063002	journal	February 2016
Molecular Applications of Coupled Cluster and Many-Body Perturbation Methods Bartlett, Rodney J.; Purvis, George D. Physica Scripta, Vol. 21, Issue 3-4 https://doi.org/10.1088/0031-8949/21/3-4/007	journal	January 1980
Product pair correlation in CH ₃ OH photodissociation at 157 nm: the OH + CH ₃ channel Chen, Zhichao; Eppink, Andre T. J. B.; Jiang, Bo Phys. Chem. Chem. Phys., Vol. 13, Issue 6 https://doi.org/10.1039/c0cp01794a	journal	January 2011
Photodissociation Dynamics of Methanol and Ethanol at 157 nm Yuan, Kai-jun; Cheng, Yuan; Wang, Feng-yan Chinese Journal of Chemical Physics, Vol. 21, Issue 4 https://doi.org/10.1088/1674-0068/21/04/301-307	journal	August 2008
Many-body perturbation theory, coupled-pair many-electron theory, and the importance of quadruple excitations for the correlation problem Bartlett, Rodney J.; Purvis, George D. International Journal of Quantum Chemistry, Vol. 14, Issue 5 https://doi.org/10.1002/qua.560140504	journal	November 1978
Velocity Map Imaging Study of the Photodissociation of CH3SH: Internal Energy Distribution of the SH Fragment Izquierdo, Jesús G.; Amaral, Gabriel A.; Ausfelder, Florian ChemPhysChem, Vol. 7, Issue 8 https://doi.org/10.1002/cphc.200600232	journal	August 2006
On the role of conical intersections of two potential energy surfaces of the same symmetry in photodissociation. I. CH ₃ SH→CH ₃ S+H and CH ₃ +SH Yarkony, David R. The Journal of Chemical Physics, Vol. 100, Issue 5 https://doi.org/10.1063/1.466351	journal	March 1994
NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations Valiev, M.; Bylaska, E. J.; Govind, N. Computer Physics Communications, Vol. 181, Issue 9, p. 1477-1489 https://doi.org/10.1016/j.cpc.2010.04.018	journal	September 2010
A second order multiconfiguration SCF procedure with optimum convergence Werner, Hans‐Joachim; Knowles, Peter J. The Journal of Chemical Physics, Vol. 82, Issue 11 https://doi.org/10.1063/1.448627	journal	June 1985
B21(Σu+1) excited state decay dynamics in CS2 Townsend, Dave; Satzger, Helmut; Ejdrup, Tine The Journal of Chemical Physics, Vol. 125, Issue 23 https://doi.org/10.1063/1.2403137	journal	December 2006
Ultrafast Deactivation of the ππ*( V ) State of Ethylene Studied Using Sub-20 fs Time-Resolved Photoelectron Imaging Kobayashi, Takufumi; Horio, Takuya; Suzuki, Toshinori The Journal of Physical Chemistry A, Vol. 119, Issue 36 https://doi.org/10.1021/acs.jpca.5b06094	journal	August 2015
Ultrafast electron dynamics in phenylalanine initiated by attosecond pulses Calegari, F.; Ayuso, D.; Trabattoni, A. Science, Vol. 346, Issue 6207 https://doi.org/10.1126/science.1254061	journal	October 2014
Spatiotemporal Imaging of Ultrafast Molecular Motion: Collapse and Revival of the $D_{2}^{+}$ Nuclear Wave Packet Ergler, Th.; Rudenko, A.; Feuerstein, B. Physical Review Letters, Vol. 97, Issue 19 https://doi.org/10.1103/physrevlett.97.193001	journal	November 2006
Third-order multireference perturbation theory The CASPT3 method Werner, Hans-Joachim Molecular Physics, Vol. 89, Issue 2 https://doi.org/10.1080/00268979609482499	journal	October 1996
An efficient second-order MC SCF method for long configuration expansions Knowles, Peter J.; Werner, Hans-Joachim Chemical Physics Letters, Vol. 115, Issue 3 https://doi.org/10.1016/0009-2614(85)80025-7	journal	April 1985
Beyond Oil and Gas: The Methanol Economy Olah, George A. Angewandte Chemie International Edition, Vol. 44, Issue 18 https://doi.org/10.1002/anie.200462121	journal	April 2005
Erratum: “Coupled cluster theory for high spin, open shell reference wave functions” [ J. Chem. Phys. 99 , 5219 (1993)] Knowles, Peter J.; Hampel, Claudia; Werner, Hans-Joachim The Journal of Chemical Physics, Vol. 112, Issue 6 https://doi.org/10.1063/1.480886	journal	February 2000
Electron Dynamics upon Ionization of Polyatomic Molecules: Coupling to Quantum Nuclear Motion and Decoherence Vacher, Morgane; Bearpark, Michael J.; Robb, Michael A. Physical Review Letters, Vol. 118, Issue 8 https://doi.org/10.1103/physrevlett.118.083001	journal	February 2017
Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene Champenois, Elio G.; Shivaram, Niranjan H.; Wright, Travis W. The Journal of Chemical Physics, Vol. 144, Issue 1 https://doi.org/10.1063/1.4939220	journal	January 2016
Ultrafast 25-fs relaxation in highly excited states of methyl azide mediated by strong nonadiabatic coupling Peters, William K.; Couch, David E.; Mignolet, Benoit Proceedings of the National Academy of Sciences, Vol. 114, Issue 52 https://doi.org/10.1073/pnas.1712566114	journal	November 2017
Photochemical Dynamics of Ethylene Cation C ₂ H ₄ ⁺ Joalland, Baptiste; Mori, Toshifumi; Martínez, Todd J. The Journal of Physical Chemistry Letters, Vol. 5, Issue 8 https://doi.org/10.1021/jz500352x	journal	March 2014
Few-femtosecond passage of conical intersections in the benzene cation Galbraith, M. C. E.; Scheit, S.; Golubev, N. V. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01133-y	journal	October 2017
Multireference perturbation theory for large restricted and selected active space reference wave functions Celani, Paolo; Werner, Hans-Joachim The Journal of Chemical Physics, Vol. 112, Issue 13 https://doi.org/10.1063/1.481132	journal	April 2000
Time-resolved photoelectron imaging of S ₂ → S ₁ internal conversion in benzene and toluene Suzuki, Yoshi-Ichi; Horio, Takuya; Fuji, Takao The Journal of Chemical Physics, Vol. 134, Issue 18 https://doi.org/10.1063/1.3586809	journal	May 2011
Femtosecond Time-Resolved Photoelectron Spectroscopy Stolow, Albert; Bragg, Arthur E.; Neumark, Daniel M. Chemical Reviews, Vol. 104, Issue 4 https://doi.org/10.1021/cr020683w	journal	April 2004
An adiabatic model for the photodissociation of CH ₃ SH in the first ultraviolet absorption band Stevens, Jonathan E.; Jang, Hyo Weon; Butler, Laurie J. The Journal of Chemical Physics, Vol. 102, Issue 18 https://doi.org/10.1063/1.469099	journal	May 1995
Correlation diagram approach to the dissociative ionization mechanisms of methanol Momigny, J.; Wankenne, H.; Krier, C. International Journal of Mass Spectrometry and Ion Physics, Vol. 35, Issue 1-2 https://doi.org/10.1016/0020-7381(80)85037-6	journal	August 1980
Laser Femtochemistry Zewail, A. H. Science, Vol. 242, Issue 4886 https://doi.org/10.1126/science.242.4886.1645	journal	December 1988
Experimental and theoretical studies on vacuum ultraviolet absorption cross sections and photodissociation of CH3OH, CH3OD, CD3OH, and CD3OD Cheng, Bing-Ming; Bahou, Mohammed; Chen, Wei-Cheng The Journal of Chemical Physics, Vol. 117, Issue 4 https://doi.org/10.1063/1.1485769	journal	July 2002
Resonance-enhanced multiphoton ionization spectra of jet-cooled methanol and ethanol Philis, John G. Chemical Physics Letters, Vol. 449, Issue 4-6 https://doi.org/10.1016/j.cplett.2007.10.089	journal	December 2007
F EMTOSECOND T IME -R ESOLVED P HOTOELECTRON S PECTROSCOPY OF P OLYATOMIC M OLECULES Stolow, Albert Annual Review of Physical Chemistry, Vol. 54, Issue 1 https://doi.org/10.1146/annurev.physchem.54.011002.103809	journal	October 2003
Calculation of properties with the coupled-cluster method Monkhorst, Hendrik J. International Journal of Quantum Chemistry, Vol. 12, Issue S11 https://doi.org/10.1002/qua.560120850	journal	January 1977
Probing ultrafast dynamics during and after passing through conical intersections Adachi, Shunsuke; Schatteburg, Tom; Humeniuk, Alexander Physical Chemistry Chemical Physics, Vol. 21, Issue 26 https://doi.org/10.1039/C8CP04426K	journal	January 2019
On the interpretation of decay associated spectra in the presence of time dependent spectral shifts Marciniak, Henning; Lochbrunner, Stefan Chemical Physics Letters, Vol. 609 https://doi.org/10.1016/j.cplett.2014.05.006	journal	August 2014
Competing atomic and molecular hydrogen pathways in the photodissociation of methanol at 157 nm Harich, S.; Lin, J. J.; Lee, Y. T. The Journal of Chemical Physics, Vol. 111, Issue 1 https://doi.org/10.1063/1.479249	journal	July 1999
Symbolic Algebra in Quantum Chemistry Hirata, So Theoretical Chemistry Accounts, Vol. 116, Issue 1-3 https://doi.org/10.1007/s00214-005-0029-5	journal	January 2006
Ultrafast Relaxation Dynamics of the Ethylene Cation C ₂ H ₄ ⁺ Ludwig, André; Liberatore, Elisa; Herrmann, Jens The Journal of Physical Chemistry Letters, Vol. 7, Issue 10 https://doi.org/10.1021/acs.jpclett.6b00646	journal	May 2016
Excited-State Dynamics of CS2 Studied by Photoelectron Imaging with a Time Resolution of 22 fs Fuji, Takao; Suzuki, Yoshi-Ichi; Horio, Takuya Chemistry - An Asian Journal, Vol. 6, Issue 11 https://doi.org/10.1002/asia.201100458	journal	October 2011
A Simplex Method for Function Minimization Nelder, J. A.; Mead, R. The Computer Journal, Vol. 7, Issue 4 https://doi.org/10.1093/comjnl/7.4.308	journal	January 1965
Photolysis of methanol at 185 nm. Quantum-mechanical calculations and product study Buenker, R. J.; Olbrich, G.; Schuchmann, H. P. Journal of the American Chemical Society, Vol. 106, Issue 16 https://doi.org/10.1021/ja00328a011	journal	August 1984
Probing ultrafast dynamics with time-resolved multi-dimensional coincidence imaging: butadiene Hockett, Paul; Ripani, Enrico; Rytwinski, Andrew Journal of Modern Optics, Vol. 60, Issue 17 https://doi.org/10.1080/09500340.2013.801525	journal	October 2013
XUV-induced reactions in benzene on sub-10 fs timescale: nonadiabatic relaxation and proton migration Galbraith, M. C. E.; Smeenk, C. T. L.; Reitsma, G. Physical Chemistry Chemical Physics, Vol. 19, Issue 30 https://doi.org/10.1039/c7cp02255g	journal	January 2017
Probing Ultrafast Dynamics with Time-resolved Multi-dimensional Coincidence Imaging: Butadiene Hockett, Paul; Ripani, Enrico; Rytwinski, Andrew figshare https://doi.org/10.6084/m9.figshare.154687.v1	text	January 2013
Beyond Oil and Gas: The Methanol Economy Prakash, G. K. Surya; Olah, George; Goeppert, Alain ECS Transactions, Vol. 35, Issue 11 https://doi.org/10.1149/1.3645178	journal	April 2011
Femtosecond Time-Resolved Photoelectron Spectroscopy Stolow, Albert; Bragg, Arthur E.; Neumark, Daniel M. ChemInform, Vol. 35, Issue 24 https://doi.org/10.1002/chin.200424292	journal	June 2004
Beyond Oil and Gas: The Methanol Economy Olah, George A. ChemInform, Vol. 36, Issue 29 https://doi.org/10.1002/chin.200529289	journal	July 2005
Probing Ultrafast Dynamics with Time-resolved Multi-dimensional Coincidence Imaging: Butadiene Hockett, Paul; Ripani, Enrico; Rytwinski, Andrew figshare https://doi.org/10.6084/m9.figshare.106343.v1	dataset	January 2013
XUV-induced reactions in benzene on sub-10 fs timescale Galbraith, M. C. E.; Smeenk, C. T. L.; Reitsma, G. Freie Universität Berlin https://doi.org/10.17169/refubium-1366	text	January 2017
Focal overlap gating in velocity map imaging to achieve high signal-to-noise ratio in photo-ion pump-probe experiments Shivaram, Niranjan; Champenois, Elio G.; Cryan, James P. arXiv https://doi.org/10.48550/arxiv.1608.05107	text	January 2016
VUV and XUV reflectance of optically coated mirrors for selection of high harmonics Larsen, K. A.; Cryan, J. P.; Shivaram, N. Optics Express, Vol. 24, Issue 16 https://doi.org/10.1364/oe.24.018209	journal	January 2016
The four-transmembrane protein MAL2 and tumor protein D52 (TPD52) are highly expressed in colorectal cancer and correlated with poor prognosis Li, Jingwen; Li, Yongmin; Liu, He PLOS ONE, Vol. 12, Issue 5 https://doi.org/10.1371/journal.pone.0178515	journal	May 2017
Probing Ultrafast Dynamics with Time-resolved Multi-dimensional Coincidence Imaging: Butadiene Hockett, Paul; Ripani, Enrico; Rytwinski, Andrew figshare https://doi.org/10.6084/m9.figshare.106343	dataset	January 2013

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