Highly efficient and stable p-type ZnO nanowires with piezotronic effect for photoelectrochemical water splitting

Journal Article · Wed May 01 00:00:00 EDT 2019 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2019.04.098· OSTI ID:1526285

Cao, Chang ^[1]; Xie, Xinxin ^[1]; Zeng, Yamei ^[1]; Shi, Shaohua ^[1]; Wang, Guizhen ^[1]; Yang, Liang ^[1]; Wang, Cai-Zhuang ^[2]; Lin, Shiwei ^[1]

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1. Hainan Univ., Haikou (China)
2. Ames Lab. and Iowa State Univ., Ames, IA (United States)

Unremitting efforts have been made to develop high-performance photoelectrochemical (PEC) water-splitting system to produce clean hydrogen fuel using sunlight. In this research, a novel way, combining highly-ordered nanowires (NWs) structure and piezotronic effect of p-type ZnO has been demonstrated to dramatically enhance PEC hydrogen evolution performance. Systematic characterizations indicate that the Sb atoms uniformly dope into ZnO NWs and substitute Zn sites with the introduction of two zinc vacancies to form the shallow acceptor Sb_Zn–2V_Zn complex. Detailed synchrotron-based X-ray absorption near-edge structure (XANES) experiments in O K-edge and Zn L-edge further confirm the formation of the complex, and theoretical calculation verifies the Sb⁵⁺ state dominating the complex. The optimal photocurrent density of the 0.2Sb/ZnO-anneal NWs can reach –0.85 mA/cm² (0 V_RHE) which is 17.2 times larger than that of the n-ZnO NWs under sunlight illumination (100 mW/cm²). Furthermore, the piezotronic effect can be introduced to regulate the charge separation and transfer in the ZnO NWs through modulating the band structure near the interface. The photocurrent density can further increase to –1.08 mA/cm² (0 V_RHE) under a 0.6% tensile strain, which is 27.4% enhancement with respect to the ZnO sample without strain. These conclusions provide an efficient way to design and develop high-performance photoelectrodes toward PEC hydrogen evolution.

• Research Organization: Ames Lab., Ames, IA (United States)
• Sponsoring Organization: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; National Natural Science Foundation of China (NSFC)
• Grant/Contract Number: 51462008; 61764003; ZDYF2017166; AC02-07CH11358
• OSTI ID: 1526285
• Report Number(s): IS-J-9947
• Journal Information: Nano Energy, Vol. 61, Issue C; ISSN 2211-2855
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

08 HYDROGEN
77 NANOSCIENCE AND NANOTECHNOLOGY
P-type ZnO
Nanowires
Piezotronic effect
Photoelectrochemical
Hydrogen evolution