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Title: KE Basin Sludge Flocculant Testing

Technical Report ·
DOI:https://doi.org/10.2172/15007925· OSTI ID:15007925

In the revised path forward and schedule for the K Basins Sludge Retrieval and Disposal Project, the sludge in K East (KE) Basin will be moved from the floor and pits and transferred to large, free-standing containers located in the pits (so as to isolate the sludge from the basin). When the sludge is pumped into the containers, it must settle fast enough and clarify sufficiently that the overflow water returned to the basin pool will not cloud the water or significantly increase the radiological dose rate to the operations staff as a result of increased suspended radioactive material. The approach being evaluated to enhance sludge settling and speed the rate of clarification is to add a flocculant to the sludge while it is being transferred to the containers. In February 2004, seven commercial flocculants were tested with a specific K Basin sludge simulant to identify those agents that demonstrated good performance over a broad range of slurry solids concentrations. From this testing, a cationic polymer flocculant, Nalco Optimer 7194 Plus (7194+), was shown to exhibit superior performance. Related prior testing with K Basin sludge and simulant in 1994/1996 had also identified this agent as promising. In March 2004, four series of jar tests were conducted with 7194+ and actual KE Basin sludge (prepared by combining selected archived KE sludge samples). The results from these jar tests show that 7194+ greatly improves settling of the sludge slurries and clarification of the supernatant.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
15007925
Report Number(s):
PNNL-14730; 820101000; TRN: US0402583
Resource Relation:
Other Information: PBD: 23 Jun 2004
Country of Publication:
United States
Language:
English